Polyacetal resin composition for molding plate-shaped molded article, plate-shaped molded article, and carrier plate of window regulator

Patent metadata

Field	Value
Publication number	US-10717864-B2
Application number	US-201716301565-A
Country	US
Kind code	B2
Filing date	Apr 12, 2017
Priority date	Jun 30, 2016
Publication date	Jul 21, 2020
Grant date	Jul 21, 2020

Abstract

A polyacetal resin composition suitable for providing a plate-shaped resin molded article that satisfies all of the following: high flatness, low shrinkage ratio anisotropy (high dimensional stability), high creep resistance, high impact strength, and excellent color stability during residence in the molding machine. The polyacetal resin composition for molding a plate-shaped molded article includes 100 mass parts of a polyacetal resin having a melt index (according to ASTM D1238, 190° C., 2.16 kgf) of 2.0 g/10 min to 4.0 g/10 min; 0.1 mass parts to 2 mass parts of a polyacetal copolymer that is a copolymer of (b1) trioxane, (b2) a compound having two to four cyclic ether units per one molecule, and (b3) a compound having one cyclic ether unit per one molecule, the polyacetal copolymer having a branched or crosslinked structure; and 0.1 mass parts to 1 mass part of a hindered phenol antioxidant.

First claim

The invention claimed is:

1. A polyacetal resin composition for molding a plate-shaped molded article, comprising:
(A) 100 parts by mass of a polyacetal resin having a melt index (in conformity with ASTM-D1238, 190° C., 2.16 kgf) of 2.0 g/10 min to 4.0 g/10 min;
(B) 0.1 parts by mass to 2 parts by mass of a polyacetal copolymer having a branched or crosslinked structure, which is a copolymer of (b1) trioxane, (b2) a compound having 2 cyclic ether units per one molecule, and (b3) a compound having one cyclic ether unit per one molecule; and
(C) 0.1 parts by mass to 1 part by mass of a hindered phenol-based antioxidant.

2. The polyacetal resin composition according to claim 1 , wherein the (C) hindered phenol-based antioxidant comprises triethylene glycol bis[3-(3-t-butyl-5-methyl-4-hydroxyphenyl)propionate].

3. The polyacetal resin composition according to claim 1 , wherein a flatness measured according to the measurement method below is 1.5 mm or less:
(I) a plate-shaped molded article is obtained by injection molding of the polyacetal resin composition under conditions of a cylinder temperature of 200° C., mold temperature of 80° C., holding pressure 50 MPa, injection rate 30 mm/s, one point center pin gate, having a flat plate portion and a rib portion, a length of the long side of the flat plate portion is 98 mm, a length of the short side of the flat plate portion is 48 mm, a thickness of the flat plate portion is 2 mm, a rib thickness of the rib portion is 4 mm, and the rib height of the rib portion is 6 mm;
(II) for the plate-shaped molded article obtained in (I), 4 locations each 5 mm away in the long side direction and the short side direction from the four corners of the flat plate portion towards the inner side of the flat plate portion are taken as end points;
(III) from the end points of the 4 locations, a total of 35 locations are set as measurement positions, by selecting 7 locations in the long side direction of the flat plate portion and 5 locations in the short side direction of the flat plate portion such that the distances between each point are evenly spaced;
(IV) for each of the 35 locations of the measurement positions, the degree of deviation from the base surface of the flat plate portion was measured using an image measuring device, and the magnitude of the difference between the greatest positive deviation point and the greatest negative deviation point was taken as the flatness.

4. A plate-shaped molded article consisting of the polyacetal resin composition according to claim 1 .

5. A carrier plate of a window regulator, comprising the plate-shaped molded article according to claim 4 .

6. The polyacetal resin composition according to claim 2 , wherein a flatness measured according to the measurement method below is 1.5 mm or less:
(I) a plate-shaped molded article is obtained by injection molding of the polyacetal resin composition under conditions of a cylinder temperature of 200° C., mold temperature of 80° C., holding pressure 50 MPa, injection rate 30 mm/s, one point center pin gate, having a flat plate portion and a rib portion, a length of the long side of the flat plate portion is 98 mm, a length of the short side of the flat plate portion is 48 mm, a thickness of the flat plate portion is 2 mm, a rib thickness of the rib portion is 4 mm, and the rib height of the rib portion is 6 mm;
(II) for the plate-shaped molded article obtained in (I), 4 locations each 5 mm away in the long side direction and the short side direction from the four corners of the flat plate portion towards the inner side of the flat plate portion are taken as end points;
(III) from the end points of the 4 locations, a total of 35 locations are set as measurement positions, by selecting 7 locations in the long side direction of the flat plate portion and 5 locations in the short side direction of the flat plate portion such that the distances between each point are evenly spaced;
(IV) for each of the 35 locations of the measurement positions, the degree of deviation from the base surface of the flat plate portion was measured using an image measuring device, and the magnitude of the difference between the greatest positive deviation point and the greatest negative deviation point was taken as the flatness.

7. A plate-shaped molded article consisting of the polyacetal resin composition according to claim 2 .

8. A plate-shaped molded article consisting of the polyacetal resin composition according to claim 3 .

9. A carrier plate of a window regulator, comprising the plate-shaped molded article according to claim 7 .

10. A carrier plate of a window regulator, comprising the plate-shaped molded article according to claim 8 .

Assignees

• Polyplastics Co

Inventors

• Horiguchi Tadahiro
• Kotani Sonae
• Ohi Kazuki

Classifications

• B29C45/00

  Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor (injection blow-moulding B29C49/06) · CPC title

• B60J1/17

  vertically · CPC title

• C08J5/00

  Manufacture of articles or shaped materials containing macromolecular substances (manufacture of semi-permeable membranes B01D67/00 - B01D71/00) · CPC title

• C08K5/13

  Phenols; Phenolates · CPC title

• C08L59/00

  Compositions of polyacetals; Compositions of derivatives of polyacetals (of polyvinyl acetals C08L29/14) · CPC title