Method for producing resin composition comprising modified microfibrillated plant fibers, and same resin composition

Patent metadata

Field	Value
Publication number	US-9512304-B2
Application number	US-201314383230-A
Country	US
Kind code	B2
Filing date	Feb 26, 2013
Priority date	Mar 9, 2012
Publication date	Dec 6, 2016
Grant date	Dec 6, 2016

Abstract

The present invention provides a method for producing a resin composition, which, by means of simple steps, can uniformly disperse microfibrillated plant fiber in a highly hydrophobic resin and can impart enhanced mechanical strength to a molding material obtained by molding the resin composition. The present invention further provides a resin composition having excellent heat resistance and low linear thermal expansion. The present invention relates to a method for producing a resin composition, the method including a step of mixing a thermoplastic resin or thermosetting resin (A), and modified plant fiber (b) or modified microfibrillated plant fiber (B), in the presence of an organic liquid (C), the modified plant fiber (b) or modified microfibrillated plant fiber (B) being obtained by modification with an alkyl or alkenyl succinic anhydride in a liquid capable of swelling microfibrillated plant fiber (B′) or plant fiber (b).

First claim

The invention claimed is:

1. A method for producing a resin composition comprising the step of:
(1) mixing a thermoplastic resin or thermosetting resin (A) with modified microfibrillated plant fiber (B) or modified plant fiber (b) in the presence of an organic liquid (C),
the modified microfibrillated plant fiber (B) or modified plant fiber (b) being obtained by modification with an alkyl or alkenyl succinic anhydride in a liquid capable of swelling microfibrillated plant fiber (B′) or plant fiber (b′),
the thermoplastic resin in the resin composition being in the form of lamellae that are layered in a direction different from the fiber length direction of the modified microfibrillated plant fiber (B),
the composition comprising resin fibrous cores that are uniaxially oriented in the fiber length direction of the modified microfibrillated plant fiber (B),
the resin lamellae being layered between the modified microfibrillated plant fiber (B), and
the fibrous cores in a direction different from the fiber length direction of the modified microfibrillated plant fiber (B).

2. The method according to claim 1 , further comprising the step of (2) kneading the mixture obtained in step (1).

3. The method according to claim 2 , wherein the modified microfibrillated plant fiber (B) or modified plant fiber (b) in step (1) is modified plant fiber (b), and during the kneading in step (2), the modified plant fiber (b) is defibrated in the thermoplastic resin or thermosetting resin (A) and the modified microfibrillated plant fiber (B) is dispersed in the thermoplastic resin or thermosetting resin (A).

4. The method for producing a resin composition according to claim 2 , wherein step (2) is a step in which the mixture obtained in step (1) is further kneaded in the presence of an antioxidant.

5. The method for producing a resin composition according to claim 1 , wherein the liquid capable of swelling microfibrillated plant fiber (B′) or plant fiber (b′) is at least one member selected from the group consisting of amide solvents and sulfoxide solvents.

6. The method for producing a resin composition according to claim 1 , wherein the organic liquid (C) is at least one member selected from the group consisting of lower alcohols, esters, hydrocarbons, ketones, and ethers.

7. The method for producing a resin composition according to claim 1 , wherein carboxyl group in the modified microfibrillated plant fiber (B) or modified plant fiber (b) is unmodified or modified into a carboxylate, carboxyamide, or alkoxycarbonyl group.

8. The method for producing a resin composition according to claim 7 , wherein the carboxylate is an alkaline earth metal salt.

9. The method for producing a resin composition according to claim 1 , wherein the amount of the modified microfibrillated plant fiber (B) or modified plant fiber (b) is 0.1 to 1,000 parts by mass per 100 parts by mass of the thermoplastic resin or thermosetting resin (A).

10. The method for producing a resin composition according to claim 1 , wherein the modified microfibrillated plant fiber (B) or modified plant fiber (b) in step (1) is obtained by subjecting the microfibrillated plant fiber (B′) or plant fiber (b′) to modification with the alkyl or alkenyl succinic anhydride and to acylation.

11. A resin composition produced by using the method according to claim 1 .

12. A resin molding material comprising the resin composition according to claim claim 11 .

13. A resin molded article obtained by molding the resin molding material according to claim 12 .

14. A method for producing a resin composition comprising the steps of:
(1) mixing a thermoplastic resin or thermosetting resin (A) with modified plant fiber (b) in the presence of water (C′), the modified plant fiber (b) being obtained by modification with an alkyl or alkenyl succinic anhydride in a liquid capable of swelling plant fiber (b′); and
(2) further kneading the mixture obtained in step (1), wherein during the kneading in step (2), the modified plant fiber (b) is defibrated in the thermoplastic resin or thermosetting resin (A), and the modified microfibrillated plant fiber (B) is dispersed in the thermoplastic resin or thermosetting resin (A),
the thermoplastic resin in the resin composition being in the form of lamellae that are layered in a direction different from the fiber length direction of the modified microfibrillated plant fiber (B),
the composition comprising resin fibrous cores that are uniaxially oriented in the fiber length direction of the modified microfibrillated plant fiber (B),
the resin lamellae being layered between the modified microfibrillated plant fiber (B), and
the fibrous cores in a direction different from the fiber length direction of the modified microfibrillated plant fiber (B).

15. The method for producing a resin composition according to claim 14 , wherein the modified plant fiber (b) in step (1) is obtained by subjecting the plant fiber (b′) to modification with the alkyl or alkenyl succinic anhydride and to acylation.

16. A resin composition comprising a thermoplastic resin and modified microfibrillated plant fiber (B),
the modified microfibrillated plant fiber (B) being obtained by subjecting microfibrillated plant fiber (B′) to modification with an alkyl or alkenyl succinic anhydride,
the modified microfibrillated plant fiber (B) being obtained by modifying microfibrillated plant fiber (B′) with an alkyl or alkenyl succinic anhydride,
the thermoplastic resin in the resin composition being in the form of lamellae that are layered in a direction different from the fiber length direction of the modified microfibrillated plant fiber (B),
the composition comprising resin fibrous cores that are uniaxially oriented in the fiber length direction of the modified microfibrillated plant fiber (B),
the resin lamellae being layered between the modified microfibrillated plant fiber (B) and the fibrous cores in a direction different from the fiber length direction of the modified microfibrillated plant fiber (B).

17. The resin composition according to claim 16 , wherein the modified microfibrillated plant fiber (B) is obtained by subjecting the microfibrillated plant fiber (B′) to modification with the alkyl or alkenyl succinic anhydride and to acylation.

18. A resin composition comprising a thermoplastic resin, and modified microfibrillated plant fiber (B) and/or modified plant fiber (b) according to claim 16 , the modified microfibrillated plant fiber (B) and modified plant fiber (b) being obtained by subjecting microfibrillated plant fiber (B′) and/or plant fiber (b′) to modification with an alkyl or alkenyl succinic anhydride and to acylation.

19. The resin composition according to claim 16 , wherein the thermoplastic resin is at least one resin selected from the group consisting of polyolefin resins, polyamide resins, polyester resins, and polyacetal resins.

20. The resin composition according to claim 19 , wherein the polyolefin resins are polyethylenes.

21. The resin composition according to claim 16 , further comprising an antioxidant.

22. A resin molding material comprising the resin composition according to claim 16 .

23. A resin molded article obtained by molding the resin molding material according to claim 22 .

Assignees

• Dainippon Ink & Chemicals
• Seiko Pmc Corp
• Univ Kyoto
• Kyoto Municipal Inst Of Ind Tech And Culture

Inventors

• Yano Hiroyuki
• Sato Akihiro
• Yoshimura Tomoaki
• Igarashi Yuko
• Kabusaki Daisuke
• Nakatsubo Fumiaki
• Okumura Hiroaki
• Semba Takeshi
• Kitagawa Kazuo
• Kataoka Hiromasa
• Shintani Kazuhiro

Classifications

• C08L23/02

  not modified by chemical after-treatment · CPC title

• C08L77/02

  Polyamides derived from omega-amino carboxylic acids or from lactams thereof (C08L77/10 takes precedence) · CPC title

• C08L23/06

  Polyethylene · CPC title

• C08L51/06

  grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond · CPC title

• D06M13/192

  Polycarboxylic acids; Anhydrides, halides or salts thereof {(D06M13/1845 takes precedence)} · CPC title