Molded articles having a swirl-like or marble-like appearance and compositions for producing same

Patent metadata

Field	Value
Publication number	US-9745469-B2
Application number	US-201514808404-A
Country	US
Kind code	B2
Filing date	Jul 24, 2015
Priority date	Apr 5, 2011
Publication date	Aug 29, 2017
Grant date	Aug 29, 2017

Abstract

Polymer compositions are described that contain at least two different immiscible phases for producing molded articles having a swirl-like or marble-like appearance. The first phase, for instance, may contain one or more polyoxymethylene polymers. The second phase, on the other hand, contains one or more polymers that together have a melting point that is from about 5° to about 30° different than the melting point of the polyoxymethylene polymer. In one embodiment, the second phase may contain a thermoplastic elastomer, a glycol-modified polyethylene terephthalate, or a polyimide and may have a melting point that is higher than the melting point of the polyoxymethylene polymer. The second phase is present in the polymer composition in relatively low amounts, such as in amounts less than about 5% by weight. The second phase can contain a high concentration of colorants that creates a contrast of colors when the molded article is produced.

First claim

What is claimed:

1. A polymer composition comprising:
a first phase comprising a polyoxymethylene polymer having a melting point; and
a second phase that is immiscible with the first phase,
wherein the second phase comprises a colorant and a thermoplastic, semi-crystalline polymer having a melting point that is at least 5° C. higher than the melting point of the polyoxymethylene polymer, and
wherein the colorant is present in an amount greater than 30% by weight based upon the weight of the second phase.

2. The polymer composition of claim 1 , wherein the colorant comprises an inorganic pigment.

3. The polymer composition of claim 1 , wherein the colorant is present in an amount greater than 40% by weight based upon the weight of the second phase.

4. The polymer composition of claim 1 , wherein the colorant is present in an amount from about 30% by weight to about 60% by weight based upon the weight of the second phase.

5. The polymer composition of claim 1 , wherein the colorant is present in an amount from about 40% by weight to about 60% by weight based upon the weight of the second phase.

6. The polymer composition of claim 1 , wherein the second phase is present in the polymer composition in an amount of from about 1% to about 5% by weight.

7. The polymer composition of claim 1 , wherein the thermoplastic, semi-crystalline polymer contained in the second phase comprises a thermoplastic elastomer.

8. The polymer composition of claim 1 , wherein the thermoplastic, semi-crystalline polymer contained in the second phase comprises a polyamide or a glycol-modified polyethylene terephthalate.

9. The polymer composition of claim 1 , wherein the melting point of the thermoplastic, semi-crystalline polymer is at least 10° C. higher than the melting point of the polyoxymethylene polymer.

10. The polymer composition of claim 1 , wherein the polyoxymethylene polymer is present in the composition in an amount of at least about 70% by weight.

11. The polymer composition of claim 1 , wherein the polyoxymethylene polymer has a melting point of from about 150° C. to about 200° C.

12. The polymer composition of claim 1 , wherein the polyoxymethylene polymer has a melting point of from about 160° C. to about 180° C. and the thermoplastic, semi-crystalline polymer has a melting point of from about 190° C. to about 200° C.

13. The polymer composition of claim 1 , wherein the immiscible phases create a swirl-like or marble-like appearance.

14. The polymer composition of claim 1 , wherein the second phase comprises discrete domains within a matrix formed by the first phase.

15. A polymer composition comprising:
a first phase comprising a polyoxymethylene polymer having a melting point; and
a second phase that is immiscible with the first phase,
wherein the second phase comprises a colorant and a thermoplastic, semi-crystalline polymer having a melting point from about 170° C. to about 210° C.,
wherein the melting point of the thermoplastic, semi-crystalline polymer is at least 5° C. higher or lower than the melting point of the polyoxymethylene polymer, and
wherein the colorant is present in an amount greater than 30% by weight based upon the weight of the second phase.

16. The polymer composition of claim 15 , wherein the melting point of the thermoplastic, semi-crystalline polymer is from about 10° C. to about 30° C. higher or lower than the melting point of the polyoxymethylene polymer.

17. The polymer composition of claim 15 , wherein the second phase is present in the polymer composition in an amount of from about 1% to about 5% by weight and wherein the colorant is present in the second phase in an amount from about 30% by weight to about 60% by weight.

18. A polymer composition comprising:
a first phase comprising a polyoxymethylene polymer having a melting point of from about 150° C. to about 200° C. wherein the polyoxymethylene polymer is present in the composition in an amount of at least about 70% by weight; and
a second phase that is immiscible with the first phase,
wherein the second phase comprises a colorant and a thermoplastic, semi-crystalline polymer having a melting point from about 170° C. to about 210° C.,
wherein the melting point of the polyoxymethylene polymer is lower than the melting point of the thermoplastic, semi-crystalline polymer, and
wherein the colorant comprises an inorganic pigment in an amount greater than 30% by weight based upon the weight of the second phase.

19. The polymer composition of claim 18 , wherein the thermoplastic, semi-crystalline polymer contained in the second phase comprises a thermoplastic elastomer, a polyamide, or a glycol-modified polyethylene terephthalate.

20. The polymer composition of claim 18 , wherein the polyoxymethylene polymer has a melting point of from about 160° C. to about 180° C. and the thermoplastic, semi-crystalline polymer has a melting point of from about 190° C. to about 200° C.

Assignees

• Ticona Llc

Inventors

• Mulholland Bruce M

Classifications

• C08L59/00

  Compositions of polyacetals; Compositions of derivatives of polyacetals (of polyvinyl acetals C08L29/14) · CPC title

• C08L67/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C08L67/06 takes precedence) · CPC title

• C08L67/025 Primary

  containing polyether sequences · CPC title

• C08L59/02

  Polyacetals containing polyoxymethylene sequences only · CPC title

• C08L77/06 Primary

  Polyamides derived from polyamines and polycarboxylic acids (C08L77/10 takes precedence) · CPC title