Performance high vinyl block copolymer compositions and uses thereof

Patent metadata

Field	Value
Publication number	US-10385156-B2
Application number	US-201715638110-A
Country	US
Kind code	B2
Filing date	Jun 29, 2017
Priority date	Jun 30, 2016
Publication date	Aug 20, 2019
Grant date	Aug 20, 2019

Abstract

Provided herein are improved performance high vinyl block copolymer compositions. The compositions may include a block copolymer and a polyolefin. The block copolymer may have a microstructure characterized by a vinyl content of equal to or greater than about 60%. The block copolymer may be a styrenic block copolymer. The polyolefin may include a polypropylene. Additional additives may be optionally added to the composition depending on the end-use application. The compositions may find utility in the preparation of various articles such as medical products including sterilized tubing, bags, and the like, films and injection molded articles.

First claim

The invention claimed is:

1. A composition comprising i) a selectively hydrogenated styrenic block copolymer present in an amount of from about 5 wt. % to about 95 wt. % based on the total weight of the composition and ii) a polyolefin present in an amount of from about 2 wt. % to about 98 wt. % based on the total weight of the composition, wherein the composition has an Isotropic Ratio of less than about 1.4 as measured on extruded film with process temperature of less than about 250° C.;
wherein prior to hydrogenation, the styrenic block copolymer has a configuration (AB) n X or (A 1 BA 2 ) n X;
wherein A, A 1 , and A 2 are polymer blocks of at least one monoalkenyl arene having a molecular weight from 5-6 kg/mol;
B is a polymer block of at least one conjugated diene, having a molecular weight from 65 kg/mol to 92 kg/mol; and a vinyl content from 60 mol percent to 85 mol percent;
n is 2-6; and X is a residue of a coupling agent;
and wherein the styrenic block copolymer has a styrene content of 10-15 weight percent.

2. The composition of claim 1 , wherein the monoalkenyl arene is selected from the group consisting of styrene, alpha-methylstyrene, para-methylstyrene, vinyl toluene, vinylnaphthalene, diphenyl ethylene, para-butyl styrene, and mixtures thereof.

3. The composition of claim 1 , wherein the coupling agent is an alkoxysilane.

4. The composition of claim 1 wherein the A block is a polystyrene block.

5. The composition of claim 1 , wherein the B block comprises a polybutadiene.

6. The composition of claim 1 , wherein when n is equal to 3, the styrenic block copolymer, prior to hydrogenation, has a molecular weight from 170 kg/mol to 230 kg/mol.

7. The composition of claim 1 , wherein the selectively hydrogenated styrenic block copolymer has a 100% modulus at elongation ranging from about 0.4 MPa to about 1.6 MPa as determined in accordance with ASTM D412.

8. The composition of claim 1 , wherein the polyolefin has a melt index of from about 1 g/10 min. to about 200 g/10 min, measured in accordance with ASTM D 1238.

9. The composition of claim 1 , wherein an extruded film of the selectively hydrogenated styrenic block copolymer has an elongation at break ranging from about 500% to about 1600% as determined in accordance with ASTM D412.

10. The composition of claim 1 , wherein the selectively hydrogenated styrenic block copolymer has an order-disorder transition temperature (ODT) of from about 180° C. to about 260° C.

11. The composition of claim 1 , wherein the polyolefin comprises polypropylene.

12. The composition of claim 1 , further comprising one or more of lubricants, slip additives, tackifiers, dusting agents, blue agents, colorants, and antioxidants.

13. The composition of claim 1 , having a melt index of from about 1 g/10 min. to about 200 g/10 min. as determined in accordance with ASTM D1238 at 230° C. and 2.16 kg weight.

14. The composition of claim 1 , wherein an extruded film of the composition has a tensile strength of from about 5 MPa to about 80 MPa as determined in accordance with ASTM D412 or ASTM D638.

15. The composition of claim 1 , having a clarity in the range of from about 80% to about 90%, measured in accordance with ASTM D1003.

16. A film formed from the composition of claim 1 .

17. A tube prepared from the composition of claim 1 .

18. An injection molded article prepared from the composition of claim 1 .

Assignees

• Kraton Polymers Us Llc

Inventors

• Zhou Yonghua
• Ding Ruidong
• Ma Liqiang

Classifications

• C08L53/00

  Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers · CPC title

• C08L23/12

  Polypropene · CPC title

• C08J2353/02

  of vinyl aromatic monomers and conjugated dienes · CPC title

• C09J153/025

  modified · CPC title

• C08L53/025

  modified · CPC title