High flow, hydrogenated styrene-butadiene-styrene block copolymers and applications

Patent metadata

Field	Value
Publication number	US-9243163-B2
Application number	US-201414469695-A
Country	US
Kind code	B2
Filing date	Aug 27, 2014
Priority date	Feb 24, 2012
Publication date	Jan 26, 2016
Grant date	Jan 26, 2016

Abstract

The invention relates to unique applications for the novel high melt flow, low viscosity, selectively hydrogenated styrene-butadiene-styrene (hSBS) or selectively hydrogenated controlled distribution styrene-butadiene/styrene-styrene (hSBSS) block copolymers, wherein the melt flow rate of said block copolymer is at least 100 g/10 min at 230° C. under 2.16 kg mass according to ASTM D1238. These block copolymers are novel and have the highest melt flow rate of any styrenic block copolymer also possessing high strength and elasticity. It has applications that prior to the present invention were not normally possible due to the normal low melt flow rate of styrenic block copolymers. The present invention also encompasses various fields of use such as a fiberglass hSBS or hSBSS reinforced mat, low viscosity hSBS or hSBSS coatings for industrial uses, hot melt adhesives prepared from hSBS or hSBSS blended with polyalpha-olefins, and elastic film, fiber, and nonwoven constructions using hSBS or hSBSS.

First claim

What is claimed is:

1. An aqueous based emulsion of styrenic block copolymer having a melt flow rate greater than 100 to 220 g/10 min at 230° C., and 2.16 kg mass, said styrenic block copolymer being hydrogenated styrene-butadiene-styrene or selectively hydrogenated controlled distribution styrene-butadiene/styrene-styrene.

2. The aqueous based emulsion of claim 1 , wherein said styrenic block copolymer includes grafted maleic anhydride.

3. The aqueous based emulsion of claim 1 , containing less than 20 wt. % organic solvent.

4. The aqueous based emulsion of claim 1 , wherein said emulsion includes a tackifier and is employed as a coating.

5. The aqueous based emulsion of claim 4 , wherein said tackifier is compatible with polystyrene.

6. The aqueous based emulsion of claim 4 , wherein said tackifier is compatible with polybutadiene.

7. The aqueous based emulsion of claim 4 , wherein said tackifier is present from 5 to 100 parts by wt. based on 100 parts by wt. styrenic block copolymer.

8. The aqueous based emulsion of claim 1 , wherein said styrenic block copolymer has a minimum peak mol. wt. of 45,000, a polystyrene content of 18-45%, a vinyl content of 65-80%, and a coupling efficiency of 60-97%.

9. The aqueous based emulsion of claim 1 , wherein said butadiene in said styrenic block copolymer is hydrogenated at least 90%.

10. The aqueous based emulsion of claim 1 , wherein said melt flow rate is greater than or equal to 160 g/10 min at 230° C., and 2.16 kg mass.

11. An aqueous based emulsion of styrenic block copolymer having a melt flow rate of about 160 to 220 g/10 min at 230° C., and 2.16 kg mass, said styrenic block copolymer being hydrogenated styrene-butadiene-styrene or selectively hydrogenated controlled distribution styrene-butadiene/styrene-styrene, wherein said styrenic block copolymer has a minimum peak mol. wt. of 45,000, a polystyrene content of 18-45%, a vinyl content of 65-80%, and a coupling efficiency of 60-97%.

Assignees

• Kraton Polymers Us Llc
• Kraton Polymers Us Llc

Inventors

• Salazar Lydia Ann

Classifications

• D04H1/4209

  Inorganic fibres · CPC title

• Y10T442/56

  From synthetic organic fiber · CPC title

• C08L67/00

  Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain (of polyester-amides C08L77/12; of polyester-imides C08L79/08); Compositions of derivatives of such polymers · CPC title

• C08K3/26

  Carbonates; Bicarbonates · CPC title

• C08F293/00

  Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule (on to polymers modified by introduction of unsaturated end groups C08F290/02) · CPC title