High flow, hydrogenated styrene-butadiene-styrene block copolymers and applications

Patent metadata

Field	Value
Publication number	US-9249335-B2
Application number	US-201414469732-A
Country	US
Kind code	B2
Filing date	Aug 27, 2014
Priority date	Feb 24, 2012
Publication date	Feb 2, 2016
Grant date	Feb 2, 2016

Abstract

The invention relates to unique applications for the novel high melt flow, low viscosity, selectively hydrogenated styrene-butadiene-styrene (hSBS) or selectively hydrogenated controlled distribution styrene-butadiene/styrene-styrene (hSBSS) block copolymers, wherein the melt flow rate of said block copolymer is at least 100 g/10 min at 230° C. under 2.16 kg mass according to ASTM D1238. These block copolymers are novel and have the highest melt flow rate of any styrenic block copolymer also possessing high strength and elasticity. It has applications that prior to the present invention were not normally possible due to the normal low melt flow rate of styrenic block copolymers. The present invention also encompasses various fields of use such as a fiberglass hSBS or hSBSS reinforced mat, low viscosity hSBS or hSBSS coatings for industrial uses, hot melt adhesives prepared from hSBS or hSBSS blended with polyalpha-olefins, and elastic film, fiber, and nonwoven constructions using hSBS or hSBSS.

First claim

What is claimed is:

1. A slush or rotational molding composition comprising: a styrenic block copolymer, poly-1-butene, polypropylene and mineral oil, wherein said styrenic block copolymer having a melt flow rate greater than 100g/10 min to 220g/10min. at 230° C., and 2.16 kg mass, said styrenic block copolymer being hydrogenated styrene-butadiene-styrene or selectively hydrogenated controlled distribution styrene-butadiene/styrene- styrene.

2. The molding composition of claim 1 , wherein said styrenic block copolymer is present in a range from 50 to 70 wt. %; said poly-1-butene is present in a range of 10-15 wt. %; said polypropylene is present in a range of 8 to 11 wt. %; and said mineral oil is present in a range of 7-10 wt. %, all percentages based on 100 wt. % of the composition.

3. The molding composition of claim 1 , wherein said styrenic block copolymer has a minimum peak molecular weight of 45,000; a polystyrene content of between about 18 to about 33%, a vinyl content of about 65 to 80%, a coupling efficiency of about 60 to about 97%, and said butadiene is hydrogenated at least 90%.

4. A slush or rotational molding composition comprising: a styrenic block copolymer, poly-1-butene, polypropylene and mineral oil, wherein said styrenic block copolymer having a melt flow rate greater than or equal to 160g/10 min. to 220g/10min. at 230° C., and 2.16 kg mass, said styrenic block copolymer being selectively hydrogenated controlled distribution styrene-butadiene/styrene-styrene, wherein said styrenic block copolymer has a minimum peak molecular weight of 45,000; a polystyrene content of between about 18 to about 33%, a vinyl content of about 65 to 80%, a coupling efficiency of about 60 to about 97%, and said polybutadiene is hydrogenated at least 90%.

Assignees

• Kraton Polymers Us Llc
• Kraton Polymers Us Llc

Inventors

• Wiegand Troy E
• Wright Kathryn Janelle

Classifications

• C08K3/26

  Carbonates; Bicarbonates · CPC title

• C08K7/14

  Glass · CPC title

• C08K5/101

  of monocarboxylic acids · CPC title

• C08L23/20

  having four to nine carbon atoms · CPC title

• C08F293/00

  Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule (on to polymers modified by introduction of unsaturated end groups C08F290/02) · CPC title