Method for producing high-purity calcium

Patent metadata

Field	Value
Publication number	US-10138533-B2
Application number	US-201615293381-A
Country	US
Kind code	B2
Filing date	Oct 14, 2016
Priority date	Dec 7, 2011
Publication date	Nov 27, 2018
Grant date	Nov 27, 2018

Abstract

A high-purity calcium and method of producing same are provided. The method includes performing first sublimation purification by introducing calcium starting material having a purity, excluding gas components, of 4N or less into a crucible of a sublimation vessel, subjecting the starting material to sublimation by heating at 750° C. to 800° C., and causing the product to deposit or evaporate onto the inside walls of the sublimation vessel; and then, once the calcium that has been subjected to first sublimation purification is recovered, performing second sublimation purification by introducing the recovered calcium again to the crucible to the sublimation vessel, heating the recovered calcium at 750° C. to 800° C., and causing the product to similarly deposit or evaporate on the inside walls of the sublimation vessel thereby recovering calcium having a purity of 4N5 or higher.

First claim

The invention claimed is:

1. High-purity calcium having a purity, excluding gas components, Sr, and Ba, of 4N5 or higher and containing silicon as an impurity in an amount of: less than 0.05 ppm, produced by a process comprising the steps of:
charging calcium starting material having a purity, excluding the gas components, of 4N or less into a crucible of a sublimation vessel;
performing first sublimation purification by heating at 750° C. to 800° C. so that calcium is sublimated and deposits (evaporates) onto the inner side wall of the sublimation vessel;
recovering the calcium purified by the first sublimation purification;
charging the calcium into a crucible of a sublimation vessel again;
performing second sublimation purification by heating at 750° C. to 800° C. so that the calcium is sublimated and deposits (evaporates) onto the inner side wall of the sublimation vessel; and
recovering the calcium having a purity, excluding gas components, Sr, and Ba, of 4N5 or higher and containing silicon as an impurity in an amount of less than 0.05 ppm.

2. The high-purity calcium according to claim 1 , wherein the high-purity calcium contains less than 5 ppm of each transition metal element.

3. The high-purity calcium according to claim 1 , wherein the high-purity calcium contains less than 1 ppm of each transition metal element.

Assignees

• Jx Nippon Mining & Metals Corp

Inventors

• Takahata Masahiro

Classifications

• C22B9/14

  Refining in the solid state · CPC title

• C22B9/02

  Refining by liquating, filtering, centrifuging, distilling, or supersonic wave action {including acoustic waves; (C22B9/003, C22B9/006, C22B9/05, C22B9/22 take precedence)} · CPC title

• Y02P10/234

  Cross-Sectional Technologies · mapped topic

• C22B9/04

  Refining by applying a vacuum · CPC title

• C22C24/00

  Alloys based on an alkali or an alkaline earth metal · CPC title