Recovery method of useful resources in seawater and brine

Patent metadata

Field	Value
Publication number	US-10273560-B2
Application number	US-201615097332-A
Country	US
Kind code	B2
Filing date	Apr 13, 2016
Priority date	Jul 31, 2015
Publication date	Apr 30, 2019
Grant date	Apr 30, 2019

Abstract

Provided is a recovery method of useful resources in seawater and brine, and more particularly, a recovery method of useful resources in seawater and brine capable of improving adsorption efficiency and recovery efficiency of trace amounts of useful resources such as strontium, lithium, boron, or the like, present in brine at low cost by using a magnetic adsorbent composite and a solid-liquid separation process which uses magnetic force.

First claim

What is claimed is:

1. A method for recovering a target element from seawater and brine, the method comprising:
(a) exposing the seawater and brine to unbound particles of a magnetic adsorbent composite;
(b) absorbing a first portion of the target element from the seawater and brine onto the magnetic absorbent composite to form loaded magnetic adsorbent composite particles;
(c) treating the loaded magnetic adsorbent composite particles with a desorption solution to release a second portion of the target element from the loaded composite to form a mixture of a loaded desorption solution and desorbed magnetic adsorbent composite particles;
(d) recovering a third portion of the target element from the loaded desorption solution.

2. The method of claim 1 , wherein:
the magnetic adsorbent composite has a comprising
a core comprising a magnetic particle,
a binder layer coating the core; and
an adsorbent material layer coating the binder layer.

3. The method of claim 1 , wherein:
the target element is selected from a group consisting of lithium, strontium, boron, and mixtures thereof.

4. The method of claim 2 , wherein:
the magnetic particle comprises at least one material selected from a group consisting of iron, nickel, cobalt, manganese, gadolinium, and oxides thereof, magnetite, maghemite, iron monoxide, iron nitride, cobalt platinum chromium alloy, barium ferrite alloy, aluminum manganese alloy, iron platinum alloy, iron palladium alloy, cobalt platinum alloy, and samarium cobalt alloy;
the binder layer contains carbon; and
the adsorbent material comprises at least one material selected from a group consisting of manganese and manganese oxides.

5. The method of claim 1 , wherein the magnetic adsorbent composite is prepared by a preparation method including:
(1) mixing magnetic particles and a carbon precursor to prepare a treatment mixture;
(2) heating the treatment mixture to a treatment temperature of from 150 to 250° C.; and thereby form a carbon-containing binder layer on the magnetic particles to form treated magnetic particles;
(3) mixing the treated magnetic particles with an adsorbent material precursor solution to form a reaction mixture; and
(4) maintaining the reaction mixture within a reaction temperature range and under a reaction pressure for a reaction period sufficient to form an absorbent material layer on the treated magnetic particles and obtain magnetic adsorbent composite particles.

6. The method of claim 5 , wherein:
the treatment mixture comprises 50 to 300 parts by weight of the carbon precursor to every 100 parts by weight of the magnetic particles;
the carbon precursor is selected from a group consisting of glucose, citric acid, and polyethylene glycol (PEG), and mixtures thereof; and wherein
the preparation method further comprises includes
separating the magnetic absorbent composite particles using magnetic force,
washing the separated magnetic absorbent composite particles, and
drying the washed magnetic absorbent composite particles.

7. The method of claim 5 , wherein:
the adsorbent material precursor solution has an adsorbent material concentration of 0.01 to 1M;
the reaction temperature range is from 20 to 25° C.;
the reaction pressure is approximately 1 atm (10.1 N/cm 2 ); and
the reaction period is at least 120 hours.

8. The method of claim 1 , further comprising:
(e) separating the desorbed magnetic adsorbent composite particles from the resource desorption solution;
(f) washing the separated desorbed magnetic absorbent composite particles; and
(g) drying the washed magnetic absorbent composite particles.

9. The method of claim 1 , further comprising:
removing dissolved magnesium and calcium from the seawater and brine before the seawater and brine are exposed to the magnetic absorbent composite.

10. A magnetic adsorbent composite comprising:
a core comprising a magnetic particle having an exterior surface;
a binder layer containing carbon coating the exterior surface of the core layer; and
an adsorbent material layer coating the binder layer;
wherein the binder layer has an average thickness of 5 to 20 nm and comprises between 5 and 15 wt % of a total weight of the magnetic adsorbent composite, and
the absorbent material layer comprises between 10 and 35 wt % of the total weight of the magnetic adsorbent composite.

11. A method for recovering a target element from an aqueous saline solution, the method comprising:
(a) exposing the aqueous saline solution to a plurality of unbound magnetic adsorbent composite particles;
(b) absorbing a first portion of the target element from the aqueous saline solution onto the magnetic absorbent composite particles to form a loaded magnetic adsorbent composite particles;
(c) treating the loaded magnetic adsorbent composite particles with a desorption solution to release a second portion of the target element from the loaded magnetic adsorbent composite particles to form a mixture of a loaded desorption solution and desorbed magnetic adsorbent composite particles; and
(d) recovering a third portion of the target element from the loaded desorption solution.

Assignees

• Korea Inst Geoscience & Mineral Resources

Inventors

• Ryu Jungho
• Hong Hye-Jin
• Kim Byoung-Gyu
• Park In-Su
• Ryu Taegong
• Chung Kang-Sup

Classifications

• C02F1/28

  by sorption (using ion-exchange C02F1/42; sorbent compositions B01J) · CPC title

• B01J20/20

  comprising free carbon; comprising carbon obtained by carbonising processes · CPC title

• Y02P10/212

  Cross-Sectional Technologies · mapped topic

• B01J20/06

  comprising oxides or hydroxides of metals not provided for in group B01J20/04 · CPC title

• C22B26/20

  Obtaining alkaline earth metals or magnesium · CPC title