Alkali metal and/or alkali earth metal extraction method

Patent metadata

Field	Value
Publication number	US-10113214-B2
Application number	US-201314412267-A
Country	US
Kind code	B2
Filing date	Jul 4, 2013
Priority date	Jul 5, 2012
Publication date	Oct 30, 2018
Grant date	Oct 30, 2018

Abstract

The present invention provides an alkali metal and/or alkali earth metal extraction method that has excellent extraction efficiency and allows repeated use of an aqueous solution that extracts an alkali metal and/or alkali earth metal from a solid. The alkali metal and/or alkali earth metal extraction method is a method for extracting an alkali metal and/or alkali earth metal from a solid containing the alkali metal and/or alkali earth metal, the method including an elution step in which the solid is added to a neutral amino acid-containing aqueous solution or an amino acid-containing mixed aqueous solution produced by mixing a pH adjusting agent with an aqueous solution containing at least one of a neutral amino acid, an acidic amino acid and a basic amino acid so as to elute the alkali metal and/or alkali earth metal in the neutral amino acid-containing aqueous solution or the amino acid-containing mixed aqueous solution.

First claim

The invention claimed is:

1. A method for extracting at least one of an alkali metal and an alkali earth metal from a solid containing at least one of the alkali metal and the alkali earth metal, the method comprising
adding the solid to a neutral amino acid-containing aqueous solution so as to elute at least one of the alkali metal and the alkali earth metal in the neutral amino acid-containing aqueous solution,
contacting an acidic gas with the eluted at least one of the alkali metal and the alkali earth metal in the neutral amino acid-containing aqueous solution to precipitate the at least one of the alkali metal and the alkali earth metal as a salt,
recovering the salt,
adding another solid containing at least one of an alkali metal and an alkali earth metal to the neutral amino acid-containing aqueous solution from which the salt was recovered to elute at least one of the alkali metal and the alkali earth metal in the neutral amino acid-containing aqueous solution, and
determining a mixing ratio of water, the neutral amino acid and the solid so that peak values of a rate of elution and an amount of the salt precipitated are matched, the rate of elution being obtained by dividing an amount of the at least one of the alkali metal and the alkali earth metal eluted in the neutral amino acid-containing aqueous solution by an amount of the at least one of the alkali metal and the alkali earth metal contained in the solid, or an integrated value of the rate of elution and the amount of the salt precipitated is maximized,
wherein the neutral amino acid-containing aqueous solution has an isoelectric point within a range of ±1.5 with respect to a first acid dissociation constant of the acidic gas, and the neutral amino acid is DL-alanine and is a chelating agent that reacts with at least one of the alkali metal and the alkali earth metal to form a chelated complex.

2. The method according to claim 1 , wherein the acidic gas is carbonic acid gas.

3. The method according to claim 1 , wherein the acidic gas is carbonic acid gas.

4. The method according to claim 1 , wherein the at least one of an alkali metal and the alkali earth metal is calcium.

5. A method for extracting at least one of an alkali metal and an alkali earth metal from a solid containing at least one of the alkali metal and the alkali earth metal, the method comprising
adding the solid to an amino acid-containing mixed aqueous solution produced by mixing a pH adjusting agent with an aqueous solution containing at least one of a neutral amino acid, an acidic amino acid and a basic amino acid so as to elute at least one of the alkali metal and the alkali earth metal in the amino acid-containing mixed aqueous solution,
contacting an acidic gas with the eluted at least one of the alkali metal and the alkali earth metal in the amino acid-containing mixed aqueous solution to precipitate the at least one of the alkali metal and the alkali earth metal as a salt,
recovering the salt,
adding another solid containing at least one of an alkali metal and an alkali earth metal to the amino acid-containing mixed aqueous solution from which the salt was recovered to elute at least one of the alkali metal and the alkali earth metal in the amino acid-containing mixed aqueous solution, and
determining a mixing ratio of water, the at least one of the neutral amino acid, the acidic amino acid and the basic amino acid, and the solid, so that peak values of a rate of elution and an amount of the salt precipitated are matched, the rate of elution being obtained by dividing an amount of the at least one of the alkali metal and the alkali earth metal eluted in the amino acid-containing mixed aqueous solution by an amount of the at least one of the alkali metal and the alkali earth metal contained in the solid, or an integrated value of the rate of elution and the amount of the salt precipitated is maximized,
wherein the amino acid-containing mixed aqueous solution has an isoelectric point within a range of ±1.5 with respect to a first acid dissociation constant of the acidic gas, and the amino acid is an organic compound which has both an amino group and a hydroxyl group and is a chelating agent that reacts with at least one of the alkali metal and the alkali earth metal to form a chelated complex, and the amino acid comprises DL-alanine.

6. The method according to claim 5 , wherein the acidic gas is carbonic acid gas.

Assignees

• Aisin Seiki
• Univ Tokyo

Inventors

• Wakimoto Yoshiki
• Fujii Satoshi
• RYONAGA Yukinori
• AMANO Kiichiro
• Kojima Toshiya
• Yamaguchi Shu
• Miyoshi Shogo

Classifications

• C01F5/24

  Magnesium carbonates · CPC title

• C22B26/00

  Obtaining alkali, alkaline earth metals or magnesium · CPC title

• C22B26/20

  Obtaining alkaline earth metals or magnesium · CPC title

• B01D11/0257

  using mixing mechanisms, e.g. stirrers, jets (B01D11/0242 takes precedence) · CPC title

• C22B26/10

  Obtaining alkali metals · CPC title