Dye-sensitized solar cell element for low illuminance

Patent metadata

Field	Value
Publication number	US-10096431-B2
Application number	US-201314424733-A
Country	US
Kind code	B2
Filing date	Aug 31, 2013
Priority date	Sep 1, 2012
Publication date	Oct 9, 2018
Grant date	Oct 9, 2018

Abstract

The dye-sensitized solar cell element includes at least one dye-sensitized solar cell (DSC), a first current extracting portion and a second current extracting portion for extracting current from the at least one DSC. The DSC comprises a first electrode having a transparent substrate and a transparent conductive layer provided on the surface of the substrate, a second electrode facing the first electrode and having a metal substrate, an oxide semiconductor layer provided on the first electrode, and an annular sealing portion bonding the first electrode with the second electrode. The first current extracting portion is included in the conductive film of one DSC of the at least one DSC, the second current extracting portion is connected with the metal substrate of the second electrode of one DSC of the at least one DSC, and the first and second current extracting portions are disposed next to each other.

First claim

The invention claimed is:

1. A dye-sensitized solar cell element for low illuminance comprising:
at least one dye-sensitized solar cell;
a first current extracting portion for extracting current from the at least one dye-sensitized solar cell; and
a second current extracting portion for extracting current from the at least one dye-sensitized solar cell,
wherein the dye-sensitized solar cell includes
a first electrode having a transparent substrate and a transparent conductive layer provided on one surface of the transparent substrate,
a second electrode facing the first electrode and having a metal substrate,
an oxide semiconductor layer provided on the first electrode or the second electrode, and
an annular sealing portion bonding the first electrode and the second electrode,
the first current extracting portion is included in the transparent conductive layer of one dye-sensitized solar cell of the at least one dye-sensitized solar cell,
the second current extracting portion is provided on the one surface of the transparent substrate of the at least one dye-sensitized solar cell and is electrically connected with the metal substrate of the second electrode of one dye-sensitized solar cell of the at least one dye-sensitized solar cell, the first current extracting portion and the second current extracting portion are disposed radially outside of the annular sealing portion so as to be adjacent to each other, and the oxide semiconductor layer is provided radially inside of the annular sealing portion;
wherein the second current extracting portion is provided directly on the one surface of the transparent substrate of the at least one dye-sensitized solar cell.

2. The dye-sensitized solar cell element for low illuminance according to claim 1 , further comprising a back sheet covering the at least one dye-sensitized solar cell on the one surface side of the transparent substrate.

3. The dye-sensitized solar cell element for low illuminance according to claim 2 ,
wherein an insulating coupling portion is provided on the entire circumference of a peripheral portion of the back sheet,
a separating portion connecting the transparent substrate and the coupling portion being provided so as to surround the transparent conductive layer of the at least one dye-sensitized solar cell and to form a gap with the transparent conductive layer is further included,
the separating portion is provided so as to form a cyclic structure together with the first current extracting portion and the second current extracting portion, and
a part of the gap is disposed on an inner side of the coupling portion.

4. The dye-sensitized solar cell element for low illuminance according to claim 2 ,
wherein the first current extracting portion and the second current extracting portion are disposed in the vicinity of one dye-sensitized solar cell of the at least one dye-sensitized solar cell, and
the metal substrate of the second electrode of one dye-sensitized solar cell of the at least one dye-sensitized solar cell is connected with the second current extracting portion by a second connecting portion.

5. The dye-sensitized solar cell element for low illuminance according to claim 4 , further comprising a second current collecting wiring provided on the second connecting portion and having a lower resistance than the second connecting portion.

6. The dye-sensitized solar cell element for low illuminance according to claim 5 , wherein the second collecting wiring is disposed so as not to intersect with the peripheral portion of the back sheet.

7. The dye-sensitized solar cell element for low illuminance according to claim 4 , wherein the second connecting portion is disposed on an inner side than the peripheral portion of the back sheet.

8. The dye-sensitized solar cell element for low illuminance according to claim 2 ,
wherein the first current extracting portion and the second current extracting portion are disposed in the vicinity of one dye-sensitized solar cell of the at least one dye-sensitized solar cell, and
the transparent conductive layer of one dye-sensitized solar cell of the at least one dye-sensitized solar cell further has

a main body portion provided on an inner side of the annular sealing portion and
a first connecting portion connecting the main body portion and the first current extracting portion.

9. The dye-sensitized solar cell element for low illuminance according to claim 8 , further comprising a first current collecting wiring provided at least on the first connecting portion of one dye-sensitized solar cell of the at least one dye-sensitized solar cell along the first connecting portion and having a lower resistance than the first connecting portion.

10. The dye-sensitized solar cell element for low illuminance according to claim 9 , wherein the first current collecting wiring is disposed so as not to intersect with the peripheral portion of the back sheet.

11. The dye-sensitized solar cell element for low illuminance according to claim 1 , comprising a plurality of the dye-sensitized solar cells,
wherein the transparent substrate is constituted by a common transparent substrate of the plurality of dye-sensitized solar cell,
the second electrodes of two adjacent dye-sensitized solar cells are spaced apart from each other,
the sealing portion has an annular first sealing portion provided between the first electrode and the second electrode,
the first sealing portions of two adjacent dye-sensitized solar cells are integrated to constitute a first integrated sealing portion,
the first integrated sealing portion has an annular portion and a partitioning portion partitioning an opening in the annular portion, and
a width of an adhesive portion of the partitioning portion of the first integrated sealing portion with a surface on the first electrode side of the second electrode is narrower than a width of an adhesive portion of the annular portion of the first integrated sealing portion with a surface on the first electrode side of the second electrode.

12. The dye-sensitized solar cell element for low illuminance according to claim 11 , wherein a width of the partitioning portion is 100% or more and less than 200% of a width of the annular portion in the first integrated sealing portion.

13. The dye-sensitized solar cell element for low illuminance according to claim 11 ,
wherein the sealing portion of the plurality of dye-sensitized solar cells further has an annular second sealing portion which is provided so as to be superimposed on the first sealing portion and which sandwiches an edge portion of the second electrode together with the first sealing portion, and
the second sealing portion is integrated to constitute a second integrated sealing portion.

14. The dye-sensitized solar cell element for low illuminance according to claim 1 , comprising a plurality of the dye-sensitized solar cells, the plurality of dye-sensitized solar cells being connected in series and electrically,
wherein the dye-sensitized solar cell connected with an adjacent dye-sensitized solar cell among the plurality of dye-sensitized solar cells further includes a connecting terminal provided on the transparent conductive layer,
the transparent conductive layer has
a main body portion provided on an inner side of the annular sealing portion and
a protruding portion which protrudes from the main body portion to an outer side of the sealing portion and on which the connecting terminal is provided,
the connecting terminal of one dye-sensitized solar cell of two adjacent dye-sensitized solar cells is connected with the metal substrate of the s

Assignees

• Fujikura Ltd

Inventors

• Okada Kenichi
• Yamada Naoshi
• Endoh Katsuyoshi
• Usui Hiroki

Classifications

• Y02E10/542

  Dye sensitized solar cells · CPC title

• H01G9/2081 Primary

  Serial interconnection of cells · CPC title

• H01G9/2031

  comprising titanium oxide, e.g. TiO2 (H01G9/2036 takes precedence) · CPC title

• H01G9/2077 Primary

  Sealing arrangements, e.g. to prevent the leakage of the electrolyte · CPC title

• H01G9/2059

  comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution · CPC title