Cathode for thin film microbattery

Patent metadata

Field	Value
Publication number	US-10069116-B2
Application number	US-201715789584-A
Country	US
Kind code	B2
Filing date	Oct 20, 2017
Priority date	Apr 8, 2014
Publication date	Sep 4, 2018
Grant date	Sep 4, 2018

Abstract

A battery comprising an anode comprising anode material in contact with a metal anode current collector. The battery further comprises a cathode comprising cathode material in contact with a cathode current collector comprising a transparent conducting oxide (TCO). The battery further comprises an electrolyte with a pH in a range of 3 to 7.

First claim

What is claimed is:

1. A method for forming a battery, the method comprising:
fabricating a cathode side including a cathode material located in a cathode cavity formed in a first dielectric element;
fabricating an anode side including an anode material located in an anode cavity formed in a second dielectric element; and
joining the cathode side and the anode side in a complanate manner, wherein the fabricating the cathode side uses no more than two lithographic masks and comprises:
forming an adhesion metal layer in the cathode cavity and on a topmost surface of the first dielectric element;
forming a transparent conductive oxide layer on the adhesion metal layer; and
removing end portions of the transparent conductive oxide and the adhesion metal layer that are present on the topmost surface of the first dielectric element.

2. The method of claim 1 , wherein the fabricating the anode side comprises using no more than three lithographic masks.

3. The method of claim 1 , wherein the removing the end portions of the transparent conductive oxide and the adhesion metal layer comprises a subtractive photolithographic technique.

4. The method of claim 1 , further comprising:
forming polymer bondable seal material portions on portions of the transparent conductive oxide layer, while maintaining a surface of the transparent conductive oxide layer that is located within the cathode cavity physically exposed.

5. The method of claim 4 , further comprising:
forming the cathode material in the cathode cavity and directly contacting the physically exposed surface of the transparent conductive oxide.

6. The method of claim 2 , wherein the fabricating the anode side comprises:
forming an adhesion metal layer in the anode cavity and on a topmost surface of the second dielectric element;
forming a seed metal layer on the adhesion metal layer;
forming the anode material on a portion of the seed metal layer that is located in the anode cavity; and
removing end portions of the seed metal layer and adhesion metal layer that are present on the topmost surface of the second dielectric element.

7. The method of claim 6 , wherein the end portions of the seed metal layer and adhesion metal layer comprises a subtractive photolithographic technique.

8. The method of claim 6 , further comprising:
forming polymer bondable seal material portions on portions of the seed metal layer, while maintaining a surface of the seed metal layer that is located within the anode cavity physically exposed.

9. The method of claim 8 , further comprising:
forming electrolyte in the anode cavity and directly contacting the physically exposed surface of the anode material.

10. The method of claim 1 , wherein the joining the cathode side and the anode side in a complanate manner comprises
bonding polymer bondable seal material portions located in the anode side to bonding polymer bondable seal material portions located in the cathode side.

11. The method of claim 1 , wherein the first and second dielectric elements comprise a flexible polymer.

12. The method of claim 1 , wherein each of the first and second dielectric elements is present on a handle substrate and each handle substrate is removed after the joining.

13. The method of claim 6 , wherein the anode material is a homogeneous solid metallic alloy.

14. The method of claim 13 , wherein the homogeneous solid metallic alloy is composed of 100 ppm to 1000 ppm Bi, 100 ppm to 1000 ppm In and the remainder is Zn.

15. A method for forming a battery, the method comprising:
fabricating a cathode side including a cathode material located in a cathode cavity formed in a first dielectric element;
fabricating an anode side including an anode material located in an anode cavity formed in a second dielectric element; and
joining the cathode side and the anode side in a complanate manner, wherein the fabricating the anode side uses no more than three lithographic masks and comprises forming an adhesion metal layer in the anode cavity and on a topmost surface of the second dielectric element;
forming a seed metal layer on the adhesion metal layer;
forming the anode material on a portion of the seed metal layer that is located in the anode cavity; and
removing end portions of the seed metal layer and adhesion metal layer that are present on the topmost surface of the second dielectric element.

Assignees

• IBM

Inventors

• Andry Paul S
• Lewandowski Eric P
• Luo Yu
• Narasgond Adinath S

Classifications

• Y10T29/49115

  including coating or impregnating · CPC title

• Y10T29/49108

  Electric battery cell making · CPC title

• H01M10/0436

  Small-sized flat cells or batteries for portable equipment · CPC title

• H01M4/139

  Processes of manufacture · CPC title

• C25D5/50

  by heat-treatment · CPC title