Resin composition, prepreg and laminate board

Patent metadata

Field	Value
Publication number	US-10017601-B2
Application number	US-201414901996-A
Country	US
Kind code	B2
Filing date	Jun 24, 2014
Priority date	Jul 4, 2013
Publication date	Jul 10, 2018
Grant date	Jul 10, 2018

Abstract

A resin composition contains a preliminary reaction product obtained through mixing an epoxy resin and a monofunctional acid anhydride as a first curing agent in an equivalence ratio of the epoxy resin to the monofunctional acid anhydride in a range of 1:0.1 to 1:0.6, and reacting the epoxy resin and the monofunctional acid anhydride such that a percentage of ring opening of the monofunctional acid anhydride is 80% or more, and a second curing agent being a different compound from the monofunctional acid anhydride.

First claim

The invention claimed is:

1. A resin composition comprising:
a preliminary reaction product obtained through mixing an epoxy resin and a monofunctional acid anhydride as a first curing agent in an equivalence ratio of the epoxy resin to the monofunctional acid anhydride in a range of 1:0.1 to 1:0.6, and reacting the epoxy resin and the monofunctional acid anhydride such that a percentage of ring opening of the monofunctional acid anhydride is 80% or more;
a second curing agent being a different compound from the monofunctional acid anhydride;
phosphorus-containing flame retardant; and
an inorganic filler,
wherein the second curing agent is at least one selected from the group consisting of a polyfunctional acid anhydride, a styrene-maleic anhydride resin, a thiol-based curing agent, and an active ester-based curing agent,
wherein the phosphorus-containing flame retardant includes a dispersion-type phosphorus-containing flame retardant that does not dissolve in the resin composition and is not reactive with the monofunctional acid anhydride, and
wherein a phosphorus content is 1.0 mass % or more and 2.0 mass % or less based on a total amount of the phosphorus-containing flame retardant and organic components in the resin composition,
wherein the inorganic filler is an inorganic filler surface-treated with a silane coupling agent,
wherein the silane coupling agent is at least one selected from the group consisting of isocyanate silane, vinylsilane, methacrylic silane, acrylic silane, ureidosilane, mercaptosilane, sulfide silane, and styrylsilane.

2. The resin composition according to claim 1 ,
wherein the phosphorus-containing flame retardant further includes a reaction-type phosphorus-containing flame retardant having a functional group reactive with an acid anhydride group or a carboxy group.

3. The resin composition according to claim 2 , wherein the functional group reactive with an acid anhydride group or a carboxy group is a hydroxy group or an amino group.

4. The resin composition according to claim 1 ,
wherein a content of the inorganic filler is 5 to 50 parts by mass with respect to 100 parts by mass of a remaining portion of the resin composition that excludes the inorganic filler.

5. The resin composition according to claim 4 , wherein a content of the silane coupling agent is 1 to 10 parts by mass with respect to 100 parts by mass of the inorganic filler.

6. A prepreg formed through impregnating a base material with the resin composition according to claim 1 , and semi-curing the resin composition.

7. A laminate board formed through laminating the prepreg according to claim 6 with a metal foil, and hot-press molding the laminated prepreg.

8. The resin composition according to claim 1 , wherein the second curing agent is at least one selected from the group consisting of a styrene-maleic anhydride resin, a thiol-based curing agent, and an active ester-based curing agent.

9. The resin composition according to claim 1 , further comprising:
a melting-type phosphorus-containing flame retardant that dissolves in the resin composition and is not reactive with the monofunctional acid anhydride.

10. The resin composition according to claim 1 , wherein the silane coupling agent is isocyanate silane.

Assignees

• Panasonic Ip Man Co Ltd

Inventors

• Nii Daisuke
• Nishino Mitsuyoshi
• Sato Fuminori
• Nakamura Yoshihiko

Classifications

• B32B2307/714

  Inert, i.e. inert to chemical degradation, corrosion · CPC title

• C08J2363/00

  Characterised by the use of epoxy resins; Derivatives of epoxy resins · CPC title

• C08K5/0066

  Flame-proofing or flame-retarding additives · CPC title

• C08K5/5399

  Phosphorus bound to nitrogen · CPC title

• C08J5/24

  Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs · CPC title