Desalination of polyaryl ethers by means of melt extraction

Patent metadata

Field	Value
Publication number	US-9975994-B2
Application number	US-201615545546-A
Country	US
Kind code	B2
Filing date	Jan 22, 2016
Priority date	Jan 23, 2015
Publication date	May 22, 2018
Grant date	May 22, 2018

Abstract

A method for desalinating a salt-containing polymer (SP) comprising a polyaryl ether having a softening temperature T S and a salt (S), comprising the steps of
a) providing the salt-containing polymer (SP) at a first temperature T 1 above the softening temperature T S of the polyaryl ether, b) contacting the salt-containing polymer (SP) provided in step a) with an extractant (E) to obtain a desalinated polymer (DP) comprising the polyaryl ether, and a salt-containing extractant (SE) comprising the extractant (E) and the salt (S).

First claim

The invention claimed is:

1. A method for desalinating a salt-containing polymer (SP) comprising a polyaryl ether having a softening temperature T S and a salt (S), comprising the steps of
a) providing the salt-containing polymer (SP) at a first temperature T 1 above the softening temperature T S of the polyaryl ether,
b) contacting the salt-containing polymer (SP) provided in step a) with an extractant (E) to obtain a desalinated polymer (DP) comprising the polyaryl ether, and a salt-containing extractant (SE) comprising the extractant (E) and the salt (S),

wherein step a) comprises the following steps:
i) providing a first salt-containing polymer (SP1) comprising the polyaryl ether and the salt (S),
ii) pelletizing the first salt-containing polymer (SP1) provided in step i) to obtain a pelletized first salt-containing polymer (PSP1),
iii) contacting the pelletized first salt-containing polymer (PSP1) obtained in step ii) with the extractant (E) to obtain the salt-containing polymer (SP) comprising the polyaryl ether and residues of the salt (S), and a first salt-containing extractant (SE1) comprising the extractant (E) and a portion of the salt (S),
iv) heating the salt-containing polymer (SP) obtained in step iii) to a first temperature T 1 above the softening temperature T S of the polyaryl ether,

and wherein step b) comprises the following step:
v) contacting the salt-containing polymer (SP) heated in step iv) with the extractant (E) to obtain the desalinated polymer (DP) comprising the polyaryl ether, and a second salt-containing extractant (SE2) comprising the extractant (E) and the residues of the salt (S),

wherein the first salt-containing polymer (SP1) is provided in step i) by a melt polymerization method.

2. The method according to claim 1 , wherein the salt-containing polymer (SP) is contacted with the extractant (E) in step b) at a second temperature T 2 above the softening temperature T S of the polyaryl ether.

3. The method according to claim 2 , wherein the second temperature T2 at which the salt-containing polymer (SP) is contacted with the extractant (E) in step b) is in the range from 160 to 300° C.

4. The method according to claim 1 , wherein the first temperature T 1 in step a) is within a range from 160 to 300° C.

5. The method according to claim 1 , wherein the first temperature T 1 is in the range from 1 to 100° C. above the softening temperature T S of the polyaryl ether.

6. The method according to claim 1 , wherein the softening temperature T S of the polyaryl ether is in the range from 150 to 230° C.

7. The method according to claim 1 , wherein the extractant (E) in step b) comprises water.

8. The method according to claim 1 , wherein the desalinated polymer (DP) obtained in step b) comprises not more than 150 ppm by weight of the salt (S), based on the total weight of the desalinated polymer (DP).

9. The method according to claim 1 , wherein the first salt-containing polymer (SP1) is pelletized in step ii) to a particle size in the range from 0.3 to 10 mm.

10. The method according to claim 1 , wherein the polyaryl ether is a polyaryl ether sulfone.

11. The method according to claim 1 , wherein the salt (S) comprises potassium chloride and/or sodium chloride.

Assignees

• Basf Se

Inventors

• Gramlich Simon
• Stammer Achim
• Ulzhöfer Angela
• Niedermaier Frank

Classifications

• C08G65/46 Primary

  Post-polymerisation treatment, e.g. recovery, purification, drying · CPC title

• B29B9/12

  characterised by structure or composition · CPC title

• C07D207/267

  with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to the ring nitrogen atom · CPC title

• C07C233/05

  having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms · CPC title