Device for the synthesis of a polymer with extraction of a gaseous substance comprising a reaction chamber having at least one circular-cylindrical section

Patent metadata

Field	Value
Publication number	US-9631051-B2
Application number	US-201414896769-A
Country	US
Kind code	B2
Filing date	Jun 11, 2014
Priority date	Jun 12, 2013
Publication date	Apr 25, 2017
Grant date	Apr 25, 2017

Abstract

An apparatus for synthesis of a polymer with separation of a gaseous substance comprises a reaction space having an essentially circular cylindrical upper section which is bounded by two circular faces and one shell face and has a longitudinal cylinder axis, and a lower section, an inlet orifice disposed in a circular face or the shell face of the upper section, a first outlet orifice disposed in a wall of the lower section, a second outlet orifice disposed in the shell face of the upper section opposite the first outlet orifice, and a removal device which is disposed so as to be rotatable about the longitudinal cylinder axis and is in contact with both circular faces and the shell face. This apparatus can especially be used for performance of a process including the feeding of an oligomer melt into a reaction space through an inlet orifice, the polymerization of the oligomer melt to give a polymer melt, the removal of the polymer melt from the reaction space through a first outlet orifice of the reaction space, and the removal of a gaseous substance from the reaction space through a second outlet orifice of the reaction space, wherein deposits on at least one inner wall of the reaction space are removed by a removal device and transported into the oligomer melt.

First claim

The invention claimed is:

1. A process for synthesizing a polymer by polymerizing a prepolymer melt ( 6 ) to give a polymer melt ( 7 ) with separation of a gaseous substance ( 8 ) in an apparatus comprising
a reaction space ( 1 ) comprising an essentially circular cylindrical upper section ( 11 ) which is bounded by two circular faces ( 111 , 112 ) and one shell face ( 113 ) and has a longitudinal cylinder axis, and a lower section ( 12 ),
an inlet orifice ( 2 ) disposed in a circular face ( 111 , 112 ) or the shell face ( 113 ) of the upper section ( 11 ),
a first outlet orifice ( 3 ) disposed in a wall of the lower section ( 12 ),
a second outlet orifice ( 4 ) disposed in the shell face ( 113 ) of the upper section ( 11 ) opposite the first outlet orifice ( 3 ) and
a removal device ( 5 ) which is disposed so as to be rotatable about the longitudinal cylinder axis and is in contact with both circular faces ( 111 , 112 ) and the shell face ( 113 ), the removal device ( 5 ) taking the form of a rotor with several rotor blades ( 51 ), and which is immersed into the prepolymer melt ( 6 ), and wherein the cross section of the reaction space ( 1 ) which encloses at least one circular face ( 111 , 112 ) of the upper section ( 11 ) is essentially droplet-shaped,
having the following process steps:
a) feeding a prepolymer melt ( 6 ) into a reaction space ( 1 ) through an inlet orifice ( 2 ),
b) polymerizing the prepolymer melt ( 6 ) to give a polymer melt ( 7 ),
c) removing the polymer melt ( 7 ) from the reaction space ( 1 ) through a first outlet orifice ( 3 ) in the reaction space ( 1 ), and
d) removing a gaseous substance ( 8 ) from the reaction space ( 1 ) through a second outlet orifice ( 4 ) in the reaction space ( 1 ),
wherein deposits on at least one inner wall of the reaction space ( 1 ) are removed by a removal device ( 5 ) immersed into the prepolymer melt ( 6 ), and transported into the prepolymer melt ( 6 ).

2. The process according to claim 1 , wherein
the inlet orifice ( 2 ) is disposed in a shell face ( 113 ) of a cylindrical first section ( 11 ) of the reaction space ( 1 ),
the removal device ( 5 ) is rotated about the longitudinal cylinder axis of the first section ( 11 ) in the direction in which the prepolymer melt ( 6 ) runs out of the inlet orifice ( 2 ) into the reaction space ( 1 ).

3. The process according to claim 1 , wherein the speed with which the polymer melt ( 7 ) moves toward the first outlet orifice ( 3 ) increases with falling distance from the first outlet orifice ( 3 ).

4. The process according to claim 1 , wherein the polymer comprises a thermoplastic polymer.

5. The process according to claim 1 , wherein the polymer is a polyamide and the gaseous substance is steam.

6. The process according to claim 1 , wherein the polymer is a semiaromatic polyamide comprising at least one incorporated repeat unit having an aromatic group and at least one incorporated repeat unit having an aliphatic or cycloaliphatic group.

7. The process according to claim 1 , wherein the polymer is a polyamide selected from the group consisting of
PA 6.T, PA 9.T, PA8.T, PA 10.T, PA 12.T, PA 6.1, PA 8.1, PA 9.1, PA 10.1, PA 12.1, PA 6.T/6, PA 6.T/10, PA 6.T/12, PA 6.T/6.1, PA6.T/8.T, PA 6.T/9.T, PA 6.T/10T, PA 6.T/12.T, PA 12.T/6.T, PA 6.T/6.1/6, PA 6.T/6.1/12, PA 6.T/6.1/6.10, PA 6.T/6.1/6.12, PA 6.T/6.6, PA 6.T/6.10, PA 6.T/6.12, PA 10.T/6, PA 10.T/11, PA 10.T/12, PA 8.T/6.T, PA 8.T/66, PA 8.T/8.I, PA 8.T/8.6, PA 8.T/6.I, PA 10.T/6.T, PA 10.T/6.6, PA 10.T/10.1, PA 10T/10.1/6.T, PA 10.T/6.1, PA 4.T/4.1/46, PA 4.T/4.1/6.6, PA 5.T/5.I, PA 5.T/5.1/5.6, PA 5.T/5.1/6.6, PA 6.T/6.1/6.6, PA MXDA.6, PA IPDA.I, PA IPDA.T, PA MACM.I, PA MACM.T, PA PACM.I, PA PACM.T, PA MXDA.I, PA MXDA.T, PA 6.T/IPDA.T, PA 6.T/MACM.T, PA 6.T/PACM.T, PA 6.T/MXDA.T, PA 6.T/6.1/8.T/8.I, PA 6.T/6.1/10.T/10.1, PA 6.T/6.I/IPDA.T/IPDA.I, PA 6.T/6.1/MXDA.T/MXDA.I, PA 6.T/6.I/MACM.T/MACM.I, PA 6.T/6.1/PACM.T/PACM.I, PA 6.T/10.T/IPDA.T, PA 6.T/12.T/IPDA.T, PA 6.T/10.T/PACM.T, PA 6.T/12.T/PACM.T, PA 10.T/IPDA.T, PA 12.T/IPDA.T, and copolymers and mixtures thereof.

8. The process according to claim 4 , wherein the polymer is selected from the group consisting of polyamides, thermoplastic polyurethanes, polyolefins, vinylaromatic polymers, polyesters, polyacetals, polycarbonates, polysulfones, polyether sulfones, and mixtures thereof polymer.

Assignees

• Basf Se

Inventors

• Zhu Ning
• Stammer Achim
• Clauss Joachim
• Kory Gad

Classifications

• C08F2/002

  Scale prevention in a polymerisation reactor or its auxiliary parts · CPC title

• B01J2219/1948

  ovoid or egg-shaped · CPC title

• B01J19/1887

  forming a thin film · CPC title

• C08G69/28

  Preparatory processes · CPC title

• C08L77/06

  Polyamides derived from polyamines and polycarboxylic acids (C08L77/10 takes precedence) · CPC title