Preparation of polyamides by hydrolytic polymerization, postpolymerization and subsequent extraction

Patent metadata

Field	Value
Publication number	US-2016009869-A1
Application number	US-201414771578-A
Country	US
Kind code	A1
Filing date	Mar 6, 2014
Priority date	Mar 7, 2013
Publication date	Jan 14, 2016
Grant date	—

Abstract

The present invention relates to a process for preparing polyamides, comprising a hydrolytic polymerization, a postpolymerization and an extraction.

First claim

1 . A process for preparing a polyamide, comprising:
a) converting a monomer composition comprising a lactam or an aminocarbonitrile and/or an oligomer of these monomers in a hydrolytic polymerization at elevated temperature in the presence of water to obtain a reaction product comprising polyamide, water, one or more unconverted monomers and oligomers, b) shaping the reaction product obtained in a) to obtain polyamide particles, c) feeding the polyamide particles obtained in b) into a reaction zone for postpolymerization, and d) treating the polyamide obtained in c) with at least one extractant, wherein the extractant is in the liquid state during the treating.

2 . The process according to claim 1 , further comprising drying the extracted polyamide obtained in d).

3 . The process according to claim 1 , wherein the monomer composition comprises ε-caprolactam or 6-aminocapronitrile and/or an oligomer of these monomers.

4 . The process according to claim 1 , wherein the conversion in a) is effected in one or more stages.

5 . The process according to claim 1 , wherein the conversion in a) is effected in two stages and an essentially vertical tubular reactor is used at least in the second stage.

6 . The process according to claim 1 , wherein the shaping in b) comprises a pelletization.

7 . The process according to claim 1 , wherein the polyamide particles obtained in b) are fed into the reaction zone for postpolymerization without being subjected to an extraction beforehand.

8 . The process according to claim 1 , wherein the polyamide particles obtained in b) are subjected to a solid phase polymerization for postpolymerization.

9 . The process according to claim 8 , wherein the reaction zone used for postpolymerization in c) comprises a tubular reactor or a tower drier.

10 . The process according to claim 8 , wherein the temperature during the postpolymerization in c) is within a range from 120 to 185° C.

11 . The process according to claim 1 , wherein the extractant employed in d) comprises water.

12 . The process according to claim 1 , wherein the temperature of the extractant during the treatment of the polyamide in d) is in a range of from 50 to less than 120° C.

13 . The process according to claim 1 , wherein the polyamide is in the solid state during the treatment in d).

14 . The process according to claim 1 , wherein the components present in the laden extractant obtained in d), selected from monomers and/or any dimers and/or oligomers, are isolated and recycled into a).

15 . The process according to claim 1 , wherein the process is performed continuously.

16 . A polyamide obtained by the process of claim 1 .

17 . The polyamide according to claim 16 , having a residual lactam content of not more than 0.055% by weight and a residual cyclic dimer content of not more than 0.05% by weight.

18 . A pellet, film, fiber or molding comprising the polyamide according to claim 16 .

Assignees

• Basf Se

Inventors

• Biedasek Silke
• Stammer Achim
• Kory Gad
• Grant William E

Classifications

• D01F6/60

  from polyamides (from polyamino acids or polypeptides D01F6/68) · CPC title

• C08G69/16

  Preparatory processes · CPC title

• C08J2377/02

  Polyamides derived from omega-amino carboxylic acids or from lactams thereof (C08J2377/10 takes precedence) · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title

• C08J3/00 Primary

  Processes of treating or compounding macromolecular substances · CPC title