Negative electrode active material and method of preparing the same
US-2017346085-A1 · Nov 30, 2017 · US
US9975158B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9975158-B2 |
| Application number | US-201214352441-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 15, 2012 |
| Priority date | Oct 19, 2011 |
| Publication date | May 22, 2018 |
| Grant date | May 22, 2018 |
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There is provided a roll surface layer material including a roll surface layer with excellent fatigue resistance. The roll surface layer material has a composition including, on a mass % basis, C: 2.3% to 2.9%, Si: 0.2% to 0.8%, Mn: 0.2% to 1.0%, Cr: 5.0% to 7.5%, Mo: 4.4% to 6.5%, V: 5.3% to 7.0%, Nb: 0.6% to 1.5%, and Co: 0.1% to 4.0% so as to satisfy 14.0≤(Mo+1.7V)≤17.0 (where Mo represents a content (mass %) of Mo and V represents a content (mass %) of V) and further including Al: 0.001% to 0.03% and/or REM: 0.001% to 0.03%, wherein a carbide is contained at an area fraction of 13% to 40%. A composite roll obtained by integrally welding a shaft member to the roll surface layer member is treated as a centrifugal cast roll that includes a surface layer with excellent fatigue resistance.
Opening claim text (preview).
The invention claimed is: 1. A roll surface layer material produced by centrifugal casting for a hot rolling mill, the roll surface layer material having excellent fatigue resistance and a compression 0.2% proof strength of 2000 MPa or more, and being used for a centrifugal cast roll for a hot rolling mill composite roll having a hardness of 79 to 88 HS, a composition of the roll surface layer material consisting of, on a mass % basis: Carbon (C): 2.3% to 2.9%; Silicon (Si): 0.2% to 0.8%; Manganese (Mn): 0.2% to 1.0%; Chromium (Cr): 5.0% to 7.5%; Molybdenum (Mo): 4.4% to 6.5%; Vanadium (V): 5.3% to 7.0%; Niobium (Nb): 0.6% to 1.5%; Cobalt (Co): 0.1% to 4.0%, and at least one of aluminum (Al) or rare earth metals (REM) in an amount of 0.001% to 0.03%, so as to satisfy formula (1) below, with the balance being iron (Fe) and incidental impurities including phosphor (P): 0.05% or less, sulfur (S): 0.05% or less and nitrogen (N): 0.06% or less, and wherein an area fraction of carbides in the roll surface layer material is in the range of 13% to 20%, 14.0≤(Mo+1.7V)≤17.0 (1) wherein Mo represents a content (mass%) of molybdenum and V represents a content (mass%) of vanadium. 2. A centrifugal cast roll for a hot rolling mill composite roll having a hardness of 79 to 88 HS, the centrifugal cast roil having excellent fatigue resistance and a compression 0.2% proof strength of 2000 MPa or more, and including a surface layer and an internal layer integrally welded to the surface layer, a composition of the roll surface layer material consisting of, on a mass % basis: Carbon (C): 2.3% to 2.9%; Silicon (Si): 0.2% to 0.8%; Manganese (Mn): 0.2% to 1.0%; Chromium (Cr): 5.0% to 7.5%; Molybdenum (Mo): 4.4% to 6.5%; Vanadium (V): 5.3% to 7.0%; Niobium (Nb): 0.6% to 1.5%; Cobalt (Co): 0.1% to 4.0%, and at least one of aluminum (Al) or rare earth metals (REM) in an amount of 0.001% to 0.03%, so as to satisfy formula (1) below, with the balance being iron (Fe) and incidental impurities including phosphor (P): 0.05% or less, sulfur (S): 0.05% or less and nitrogen (N): 0.06% or less, and wherein an area fraction of carbides in the roll surface layer material is in the range of 13% to 20%, 14.0≤(Mo+1.7V)≤17.0 (1) wherein Mo represents a content (mass%) of molybdenum and V represents a content (mass%) of vanadium.
containing chromium · CPC title
containing aluminium or silicon · CPC title
Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten") · CPC title
of elongated solid or hollow bodies, e.g. pipes, in moulds rotating around their longitudinal axis · CPC title
Shape or construction of rolls (for rolling metal of indefinite length in repetitive shapes specially designed for the manufacture of particular objects B21H8/02 {; B21B27/005 takes precedence}) · CPC title
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