Alpha + beta titanium alloy cold-rolled and annealed sheet having high strength and high young's modulus and method for producing the same
US-2016326620-A1 · Nov 10, 2016 · US
US9757779B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9757779-B2 |
| Application number | US-201214344734-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 3, 2012 |
| Priority date | Sep 21, 2011 |
| Publication date | Sep 12, 2017 |
| Grant date | Sep 12, 2017 |
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A centrifugally cast composite roll for hot rolling comprising an outer layer having a composition comprising by mass 0.8-3.5% of C, 0.1-2.5% of Si, 0.1-2.5% of Mn, 1.2-15% of Cr, 1-5% of Ni, and 1-10% of Mo+0.5×W, the balance being substantially Fe and inevitable impurities, and an inner layer made of an iron-based alloy and integrally fused to the outer layer; the outer layer having Shore hardness of 67-82 at the initial diameter of the composite roll; and the maximum Shore hardness of the outer layer in a range 30 mm or more deep from the initial diameter being higher by 1 or more than the Shore hardness of the outer layer at the initial diameter.
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What is claimed is: 1. A centrifugally cast composite roll for hot rolling comprising an outer layer having a composition comprising by mass 0.8-3.5% of C, 0.1-2.5% of Si, 0.1-2.5% of Mn, 1.2-15% of Cr, 1-5% of Ni, and 2.53-10% of Mo+0.5×W, the balance being substantially Fe and inevitable impurities, and an inner layer made of an iron-based alloy and integrally fused to said outer layer; said outer layer having Shore hardness of 67-82 at an initial diameter of said composite roll, the initial diameter being an outer diameter of the composite roll before the composite roll is used for rolling; and the maximum Shore hardness of said outer layer in a range 30 mm or more deep from said initial diameter being higher by 1 or more than the Shore hardness of said outer layer at said initial diameter. 2. The centrifugally cast composite roll for hot rolling according to claim 1 , wherein a regression line of the depth-direction distribution of the Shore hardness of said outer layer in a range up to the depth of 30 mm from said initial diameter has positive inclination A (Hs/mm). 3. The centrifugally cast composite roll for hot rolling according to claim 1 , wherein said outer layer further comprises 2-15% by mass of V+Nb. 4. The centrifugally cast composite roll for hot rolling according to claim 1 , wherein said outer layer further comprises at least one of 1-10% of Co, 0.01-2% of Ti, 0.01-2% of Zr, and 0.001-0.15% of N by mass. 5. The centrifugally cast composite roll for hot rolling according to claim 1 , wherein said outer layer has a W content of 0.1-20% by mass. 6. The centrifugally cast composite roll for hot rolling according to claim 1 , wherein said inner layer is made of ductile cast iron. 7. The centrifugally cast composite roll for hot rolling according to claim 1 , which comprises an intermediate layer between said outer layer and said inner layer. 8. The centrifugally cast composite roll for hot rolling according to claim 3 , wherein an area ratio of undecomposed M 2 C carbides is more than an area ratio of MC carbides and M 6 C carbides formed by the decomposition of M 2 C carbides at said initial diameter of said outer layer, and the area ratio of undecomposed M 2 C carbides is less than the area ratio of MC carbides and M 6 C carbides formed by the decomposition of M 2 C carbides at the discard diameter of said outer layer. 9. The centrifugally cast composite roll for hot rolling according to claim 8 , wherein a ratio of (area ratio of undecomposed M 2 C carbides)/[(area ratio of undecomposed M 2 C carbides)+(area ratio of MC carbides and M 6 C carbides formed by the decomposition of M 2 C carbides)] is 60% or more at the initial diameter. 10. The centrifugally cast composite roll for hot rolling according to claim 8 , wherein a ratio of (area ratio of MC carbides and M 6 C carbides formed by the decomposition of M 2 C carbides)/[(area ratio of undecomposed M 2 C carbides)+(area ratio of MC carbides and M 6 C carbides formed by the decomposition of M 2 C carbides)] is 60% or more at the discard diameter. 11. The centrifugally cast composite roll for hot rolling according to claim 1 , wherein a cross section area ratio of the outer layer to the inner layer is 0.25-0.8 at the initial diameter. 12. A method for producing the centrifugally cast composite roll for hot rolling recited in claim 1 , comprising the steps of casting a melt for the outer layer into a rotating centrifugal casting mold; casting an iron-based alloy melt for the inner layer into the resultant hollow outer layer during or after the solidification of said outer layer, such that said inner layer is integrally fused to an inner surface of the outer layer by re-melting; cooling the resultant composite roll until the surface temperature of said outer layer becomes 600° C. or lower; and then conducting a tempering treatment at 600° C. or lower one or more times without a heating step to a temperature equal to or higher than the transformation point of the outer layer. 13. The method for producing a centrifugally cast composite roll for hot rolling according to claim 12 , wherein said centrifugal casting mold has a wall as thick as 100-600 mm.
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