Thermally emissive sensing materials for chemical spectroscopy analysis

Patent metadata

Field	Value
Publication number	US-9964494-B1
Application number	US-201615160389-A
Country	US
Kind code	B1
Filing date	May 20, 2016
Priority date	Sep 28, 2015
Publication date	May 8, 2018
Grant date	May 8, 2018

Abstract

A sensor using thermally emissive materials for chemical spectroscopy analysis includes an emissive material, wherein the emissive material includes the thermally emissive materials which emit electromagnetic radiation, wherein the electromagnetic radiation is modified due to chemical composition in an environment; and a detector adapted to detect the electromagnetic radiation, wherein the electromagnetic radiation is indicative of the chemical interaction changes and hence chemical composition and/or chemical composition changes of the environment. The emissive material can be utilized with an optical fiber sensor, with the optical fiber sensor operating without the emissive material probed with a light source external to the material.

First claim

What is claimed is:

1. An optical fiber sensor utilizing thermally emissive materials for chemical spectroscopy analysis, the sensor comprising:
an emissive material, wherein the emissive material comprises the thermally emissive materials comprising one of TiO 2 , Pd—TiO 2 , and Au—TiO 2 nanocomposites, with varied properties comprising high conductivity, hydrogen absorptivity, and localized surface plasmon resonance (LSPR) based activity in nitrogen and in oxygen containing high-temperature environments, perovskite oxide, strontium titanate (SrTiO 3 ) or doped SrTiO 3 , one of which emit electromagnetic radiation, wherein the electromagnetic radiation is modified due to chemical composition in an environment;
the optical fiber sensor comprising a distributed optical fiber sensor with a plurality of emissive materials each operating at different wavelengths, the optical fiber operating without the emissive material probed with a light source external to the material; and
a detector adapted to detect the electromagnetic radiation, wherein the electromagnetic radiation is indicative of the chemical interaction changes and hence chemical composition and/or chemical composition changes of the environment.

2. The sensor of claim 1 , wherein the optical fiber sensor comprises an optical fiber sensor coupled to the detector, wherein the emissive material is one of deposited on a core or the end-face of the optical fiber, coated on the optical fiber, and integrated with the optical fiber to derive information about the chemical composition of the environment.

3. The sensor of claim 1 , wherein the optical fiber sensor comprises an optical fiber coupled to the detector, wherein the emissive material is integrated with one of a core, a cladding, and a combination of the core and the cladding of the optical fiber to derive information about the chemical composition of the environment.

4. The sensor of claim 1 , wherein the detector comprises two detectors each at opposite ends of an optical fiber of the optical fiber sensor which monitors an output from the emissive material to derive information about the chemical composition of the environment and spatial dependence of the chemical composition.

5. The sensor of claim 1 , wherein the emissive material interacts with environment chemistry to provide an altered emissivity observed via high isolation with respect to background interferences through tunneling to the optical fiber sensor by overlapping the emissive material near-field and optical fiber evanescent regions.

6. The sensor of claim 1 , wherein the emissive material is integrated with the optical fiber.

7. The sensor of claim 1 , wherein the emissive material comprises one of the thermally emissive materials directly disposed to a material, the thermally emissive materials on an underlayer, the thermally emissive materials embedded in a matrix phase, a monolithic film with the thermally emissive materials, and the thermally emissive materials embedded in a multi-layer stack and/or overcoated by another thin film layer.

8. A method for chemical spectroscopy analysis with a sensor using thermally emissive materials, the method comprising:
emitting radiation by the thermally emissive materials responsive to thermal energy which is altered based on chemical interaction changes in an environment, the thermally emissive materials comprising one of TiO 2 , Pd—TiO 2 , and Au—TiO 2 nanocomposites, with varied properties comprising high conductivity, hydrogen absorptivity, and localized surface plasmon resonance (LSPR) based activity in nitrogen and in oxygen containing high-temperature environments, perovskite oxide, strontium titanate (SrTiO 3 ) or doped SrTiO 3 ; and
operating an optical fiber without the emissive material probed with a light source external to the material, the optical fiber sensor comprising a distributed optical fiber sensor with a plurality of emissive materials each operating at different wavelengths; and
detecting the radiation using a detector, wherein the electromagnetic radiation is indicative of the chemical interaction changes and hence chemical composition and/or chemical composition changes of the environment.

9. The method of claim 8 , further comprising:
detecting the radiation by the detector coupled to an optical fiber of an optical fiber sensor, wherein the detector operates without the emissive material probed with a light source external to the material.

10. The method of claim 9 , wherein the emissive material is one of deposited on a core of the optical fiber, coated on the optical fiber, and integrated with the optical fiber.

11. The method of claim 9 , wherein the emissive material interacts with environment chemistry to provide an altered emissivity observed via high isolation through tunneling to the optical fiber by overlapping the emissive material near-field and optical fiber evanescent regions.

12. An optical fiber sensor using thermally emissive materials for chemical spectroscopy analysis, the sensor comprising:
an emissive material, wherein the emissive material comprises the thermally emissive materials comprising one of TiO 2 , Pd—TiO 2 , and Au—TiO 2 nanocomposites, with varied properties comprising high conductivity, hydrogen absorptivity, and localized surface plasmon resonance (LSPR) based activity in nitrogen and in oxygen containing high-temperature environments, perovskite oxide, strontium titanate (SrTiO 3 ) or doped SrTiO 3 , one of which emit electromagnetic radiation, wherein the electromagnetic radiation is modified due to chemical composition in an environment;
the optical fiber sensor comprises a bundled fiber with a plurality of optical fibers therein with the emissive material to provide distributed sensing,
the optical fiber operating without the emissive material probed with a light source external to the material; and
a detector adapted to detect the electromagnetic radiation, wherein the electromagnetic radiation is indicative of the chemical interaction changes and hence chemical composition and/or chemical composition changes of the environment.

13. The sensor of claim 12 , wherein the optical fiber sensor comprises an optical fiber coupled to the detector, wherein the emissive material is one of deposited on a core or the end-face of the optical fiber, coated on the optical fiber, and integrated with the optical fiber to derive information about the chemical composition of the environment.

14. The sensor of claim 12 , wherein the optical fiber sensor comprises an optical fiber coupled to the detector, wherein the emissive material is integrated with one of a core, a cladding, and a combination of the core and the cladding of the optical fiber to derive information about the chemical composition of the environment.

15. The sensor of claim 12 , wherein the detector comprises two detectors each at opposite ends of an optical fiber of the optical fiber sensor which monitors an output from the emissive material to derive information about the chemical composition of the environment and spatial dependence of the chemical composition.

16. The sensor of claim 12 , wherein the optical fiber sensor comprises a distributed optical fiber sensor with a plurality of emissive materials each operating at different wavelengths.

Assignees

• The United States Of America Dept Of Energy
• Us Dept Energy

Inventors

• Poole Zsolt
• Ohodnicki Paul R

Classifications

• G01N21/71 Primary

  thermally excited · CPC title

• G02B6/10

  of the optical waveguide type (G02B6/02, G02B6/24 take precedence; devices or arrangements for the control of light by electric, magnetic, electro-magnetic or acoustic means G02F1/00; transferring the modulation of modulated light G02F2/00; optical logic elements G02F3/00; optical analogue/digital converters G02F7/00) · CPC title

• G02B6/04

  formed by bundles of fibres (G02B6/24 takes precedence) · CPC title

• F28F21/089

  Coatings, claddings or bonding layers made from metals or metal alloys (F28F19/06 takes precedence) · CPC title

• F28F21/086

  from titanium or titanium alloys · CPC title