Thermosensitive recording material

Patent metadata

Field	Value
Publication number	US-9962980-B2
Application number	US-201415026065-A
Country	US
Kind code	B2
Filing date	Sep 30, 2014
Priority date	Oct 4, 2013
Publication date	May 8, 2018
Grant date	May 8, 2018

Abstract

A main object of the present invention is to provide a thermosensitive recording material having excellent recording color developability and recording image quality, having no inhibition of a color-developing reaction due to the adhesive component after being processed into a thermosensitive recording label (glue desensitization), and being able to withstand long-term storage while retaining excellent recording performance. The present invention is a thermosensitive recording material (1) having at least an anchor layer (1) containing a sizing agent on a support, an undercoat layer containing at least one member selected from the group consisting of plastic hollow particles and sizing agents on the anchor layer (1), and a thermosensitive recording layer containing a leuco dye and a coloring agent on the undercoat layer; and is a thermosensitive recording material (2a) having an anchor layer (2) containing specific amounts of a pigment and a specific sizing agent on a support, and a thermosensitive recording layer containing a leuco dye and a coloring agent on the anchor layer (2); a thermosensitive recording material (2b) having an anchor layer (2) containing a pigment and a specific sizing agent on a support, and a thermosensitive recording layer containing a leuco dye and a specific coloring agent on the anchor layer (2); or a thermosensitive recording material (2c) having an anchor layer (2) containing a sizing agent and a water resistance-imparting agent on a support, and a thermosensitive recording layer containing a leuco dye and a coloring agent on the anchor layer.

First claim

The invention claimed is:

1. A thermosensitive recording material comprising:
at least an anchor layer (1) containing a sizing agent and plastic hollow particles on a support;
an undercoat layer containing at least one member selected from the group consisting of plastic hollow particles and sizing agents on the anchor layer (1); and
a thermosensitive recording layer containing a leuco dye and a coloring agent on the undercoat layer.

2. The thermosensitive recording material according to claim 1 , wherein the undercoat layer contains the plastic hollow particles and the sizing agent.

3. The thermosensitive recording material according to claim 1 , wherein the undercoat layer contains the sizing agent in an amount of 0.5 to 7 mass % in terms of solids content, based on the total solids content of the undercoat layer.

4. The thermosensitive recording material according to claim 1 , wherein the undercoat layer contains the plastic hollow particles in an amount of 40 to 95 mass %, based on the total solids content of the undercoat layer.

5. The thermosensitive recording material according to claim 1 , wherein the anchor layer (1) contains at least one member selected from the group consisting of oil-absorptive pigments and plastic hollow particles as a pigment, and the mass ratio of the plastic hollow particles in the anchor layer (1) to the plastic hollow particles in the undercoat layer is from 0/100 to 60/40.

6. The thermosensitive recording material according to claim 1 comprising at least one member selected from the group consisting of 4,4′-dihydroxydiphenylsulfone, 2,4′-dihydroxydiphenylsulfone, and sulfonylurea compounds as the coloring agent.

7. The thermosensitive recording material according to claim 1 , wherein at least one layer formed on the support is formed by a curtain coating method.

8. The thermosensitive recording material according to claim 1 , wherein the support further contains a basic pigment.

9. The thermosensitive recording material according to claim 1 , wherein the support has an air permeability of 80 seconds or less.

10. The thermosensitive recording material according to claim 1 , wherein the support is a paper support.

11. The thermosensitive recording material according to claim 1 , wherein the support has a surface roughness measured with a microtopograph under a pressure of 20 kg/cm2 of at least 6 μm.

12. The thermosensitive recording material according to claim 1 , wherein the support has a Stockigt sizing degree of at most 15 seconds.

13. The thermosensitive recording material according to claim 1 comprising an adhesive layer on a side of the support opposite to the thermosensitive recording layer side.

14. The thermosensitive recording material according to claim 1 , wherein the anchor layer (1) is a pigment-coated layer.

15. The thermosensitive recording material according to claim 1 , wherein the sizing agent contained in the anchor layer (1) is at least one member selected from the group consisting of styrene-acrylic-based sizing agents and styrene-maleic acid-based sizing agents.

16. The thermosensitive recording material according to claim 1 , wherein the anchor layer (1) further contains a pigment and contains at least one member selected from the group consisting of oil-absorptive pigments and plastic hollow particles as the pigment, and the mass ratio of the oil-absorptive pigment to the plastic hollow particles in the anchor layer (1) is from 100/0 to 40/60.

17. The thermosensitive recording material according to claim 1 , wherein the anchor layer (1) contains the sizing agent in an amount of 1 to 9 mass % in terms of solids content, based on the total solids content of the anchor layer.

18. The thermosensitive recording material according to claim 1 , wherein at least the thermosensitive recording layer is a layer formed by a curtain coating method.

19. The thermosensitive recording material according to claim 1 , wherein the sizing agent in the anchor layer (1) contains a styrene-acrylic-based emulsion-type sizing agent.

20. The thermosensitive recording material according to claim 1 , wherein the undercoat layer contains a butyl ester of a styrene-maleic anhydride copolymer as the sizing agent.

Assignees

• Oji Holdings Corp

Inventors

• Morie Masahiro
• Minami Takehiro
• Yamane Kazuo
• Yamamoto Toshizo
• Sakamoto Kazuyuki
• Nojima Masaharu

Classifications

• B41M5/323

  Organic colour formers, e.g. leuco dyes · CPC title

• B41M5/423

  characterised by non-macromolecular compounds, e.g. waxes · CPC title

• B41M5/3336

  Sulfur compounds, e.g. sulfones, sulfides, sulfonamides · CPC title

• B41M2205/40

  Cover layers; Layers separated from substrate by imaging layer; Protective layers; Layers applied before imaging · CPC title

• B41M2205/38

  Intermediate layers; Layers between substrate and imaging layer · CPC title