Thermochromic dye compositions and method for preparing same

Patent metadata

Field	Value
Publication number	US-11524515-B2
Application number	US-201916376261-A
Country	US
Kind code	B2
Filing date	Apr 5, 2019
Priority date	Apr 5, 2019
Publication date	Dec 13, 2022
Grant date	Dec 13, 2022

Abstract

A thermochromic composition including a dye molecule; a matrix, wherein the matrix comprises a material having a defined melting point; and an optional developer. A process for preparing a thermochromic composition, including providing a dye; heating a matrix above its melting point; adding the heated matrix to the dye until the dye dissolves in the matrix; optionally, adding a developer; wherein the thermochromic composition exhibits a first color at a first temperature and a second color at a second temperature; wherein the first color and the second color are different; and wherein the first temperature and the second temperature are different.

First claim

The invention claimed is:

1. A thermochromic composition consisting of:
a dye molecule, where the dye molecule is selected from the group consisting of Gentian violet, Malachite green, Thymol blue, Methyl yellow, Bromophenol blue, Congo red, Methyl orange, Bromocresol green, Methyl red, Methyl purple, Azolitmin red, Bromocresol purple, Metacresol Purple, Bromothymol blue, Phenol red, Neutral red, Naphtholphthalein, Cresol red, Cresolphthalein, Phenolphthalein, Thymolphthalein, Alizarine Yellow, Indigo carmine, and combinations thereof;
a matrix, wherein the matrix comprises a material having a defined melting point; optionally, wherein the matrix is a wax; where the matrix is selected from the group consisting of tert-butanol, 1-decanol, 1-dodecanol, 1-tetradecanol, 1-hexadecanol, 1-octadecanol, 1,10-decanediol, 1,12-dodecanediol, glycerol, poly(ethylene glycol), and combinations thereof;
wherein the composition contains two components, the matrix and the dye, and is free of a developer; and
wherein the composition is encapsulated.

2. The composition of claim 1 , where the dye molecule is selected from the group consisting of a pH sensitive molecule, a pH indicator, and combinations thereof.

3. The composition of claim 1 , where the matrix is a wax.

4. The composition of claim 1 , wherein the composition exhibits a first color at a first temperature and a second color at a second temperature;
wherein the first color and the second color are different; and
wherein the first temperature and the second temperature are different.

5. The composition of claim 1 , wherein the composition comprises a thermochromic composition having a color change activation temperature; and wherein the activation temperature of the color change is equal to the melting point of the matrix;
and wherein the matrix or a combination of matrices are selected to provide the thermochromic composition with a desired activation temperature.

6. The composition of claim 1 , wherein the composition exhibits the characteristic of multiple color transitions at multiple temperatures.

7. A process for preparing a thermochromic composition, consisting of:
providing a dye, where the dye is selected from the group consisting of Gentian violet, Malachite green, Thymol blue, Methyl yellow, Bromophenol blue, Congo red, Methyl orange, Bromocresol green, Methyl red, Methyl purple, Azolitmin red, Bromocresol purple, Metacresol Purple, Bromothymol blue, Phenol red, Neutral red, Naphtholphthalein, Cresol red, Cresolphthalein, Phenolphthalein, Thymolphthalein, Alizarine Yellow, Indigo carmine, and combinations thereof;
heating a matrix above its melting point, where the matrix is selected from the group consisting of tert-butanol, 1-decanol, 1-dodecanol, 1-tetradecanol, 1-hexadecanol, 1-octadecanol, 1,10-decanediol, 1,12-dodecanediol, glycerol, poly(ethylene glycol), and combinations thereof;
adding the heated matrix to the dye until the dye dissolves in the matrix;
wherein the composition contains two components, the matrix and the dye, and is free of a developer;
encapsulating the thermochromic composition to form an encapsulated thermochromic composition;
wherein the thermochromic composition exhibits a first color at a first temperature and a second color at a second temperature;
wherein the first color and the second color are different; and
wherein the first temperature and the second temperature are different.

8. The process of claim 7 , wherein the composition comprises a thermochromic composition having a color change activation temperature; and wherein the activation temperature of the color change is equal to the melting point of the matrix;
and wherein the matrix or a combination of matrices are selected to provide the thermochromic composition with a desired activation temperature.

9. The process of claim 7 , where the dye molecule is selected from the group consisting of a pH sensitive molecule, a pH indicator, and combinations thereof.

10. A process consisting of:
providing a thermochromic composition comprising a dye molecule; a matrix, wherein the matrix comprises a material having a defined melting point;
where the dye molecule is selected from the group consisting of Gentian violet, Malachite green, Thymol blue, Methyl yellow, Bromophenol blue, Congo red, Methyl orange, Bromocresol green, Methyl red, Methyl purple, Azolitmin red, Bromocresol purple, Metacresol Purple, Bromothymol blue, Phenol red, Neutral red, Naphtholphthalein, Cresol red, Cresolphthalein, Phenolphthalein, Thymolphthalein, Alizarine Yellow, Indigo carmine, and combinations thereof;
where the matrix is selected from the group consisting of tert-butanol, 1-decanol, 1-dodecanol, 1-tetradecanol, 1-hexadecanol, 1-octadecanol, 1,10-decanediol, 1,12-dodecanediol, glycerol, poly(ethylene glycol), and combinations thereof;
wherein the composition contains two components, the matrix and the dye, and is free of a developer;
wherein the composition is encapsulated;
disposing the thermochromic composition onto a substrate, wherein disposing the thermochromic composition optionally comprises ink jet printing the composition;
wherein the thermochromic composition exhibits a first color at a first temperature and a second color at a second temperature;
wherein the first color and the second color are different; and
wherein the first temperature and the second temperature are different.

Assignees

• Xerox Corp

Inventors

• Resetco Cristina
• Morimitsu Kentaro

Classifications

• B41M5/3375

  Non-macromolecular compounds · CPC title

• B41M5/323

  Organic colour formers, e.g. leuco dyes · CPC title

• C09B67/0092

  Dyes in solid form · CPC title

• B41M5/3372

  Macromolecular compounds · CPC title

• B41M5/284 Primary

  Organic thermochromic compounds · CPC title