Method for producing composition containing purified chlorogenic acids

Patent metadata

Field	Value
Publication number	US-9950985-B2
Application number	US-201515506579-A
Country	US
Kind code	B2
Filing date	Aug 18, 2015
Priority date	Aug 26, 2014
Publication date	Apr 24, 2018
Grant date	Apr 24, 2018

Abstract

Provided is a method of producing a purified chlorogenic acid-containing composition, including: a first step of dispersing or dissolving a raw material chlorogenic acid-containing composition in an aqueous solution of organic solvent; a second step of removing a precipitate from a dispersion or a solution obtained in the first step; and a third step of bringing a solution obtained in the second step into contact with activated carbon including activated carbon (A) having a pore volume of from 0.3 mL/g to 1.0 mL/g and activated carbon (B) having a pore volume larger than that of the activated carbon (A), in which a difference [(B)−(A)] in pore volume between the activated carbon (A) and the activated carbon (B) is from 0.1 mL/g to 1.5 mL/g.

First claim

The invention claimed is:

1. A method of producing a purified chlorogenic acid-containing composition, comprising:
a first step of adding together a raw material chlorogenic acid-containing composition and an aqueous solution of organic solvent to form a dispersion or solution;
a second step of removing a precipitate from the dispersion or the solution obtained in the first step to form a solution; and
a third step of bringing the solution obtained in the second step into contact with activated carbon comprising activated carbon (A) having a pore volume of from 0.3 mL/g to 1.0 mL/g and activated carbon (B) having a pore volume larger than that of the activated carbon (A) to form said purified chlorogenic acid-containing composition,
wherein a difference [(B)−(A)] in pore volume between the activated carbon (A) and the activated carbon (B) is from 0.1 mL/g to 1.5 mL/g.

2. The method of producing a purified chlorogenic acid-containing composition according to claim 1 , wherein the difference [(B)−(A)] in pore volume between the activated carbon (A) and the activated carbon (B) is from 0.5 mL/g to 1.5 mL/g.

3. The method of producing a purified chlorogenic acid-containing composition according to claim 1 , wherein a ratio of the pore volume of the activated carbon (B) to the pore volume of the activated carbon (A), [(B)/(A)], is from 1.5 to 4.0.

4. The method of producing a purified chlorogenic acid-containing composition according to claim 1 , wherein a mass ratio of the activated carbon (B) to the activated carbon (A), [(B)/(A)], is from 0.1 to 1.0.

5. The method of producing a purified chlorogenic acid-containing composition according to claim 1 , wherein a mass ratio of the activated carbon (B) to the activated carbon (A), [(B)/(A)], is from 0.1 to 0.7.

6. The method of producing a purified chlorogenic acid-containing composition according to claim 1 , wherein the activated carbon (A) has a pore volume of from 0.33 mL/g to 0.94 mL/g.

7. The method of producing a purified chlorogenic acid-containing composition according to claim 1 , wherein the activated carbon (A) has a pore volume of from 0.37 mL/g to 0.64 mL/g.

8. The method of producing a purified chlorogenic acid-containing composition according to claim 1 , wherein the activated carbon (B) has a pore volume of from 1.0 mL/g to 2.0 mL/g.

9. The method of producing a purified chlorogenic acid-containing composition according to claim 1 , wherein in the third step, the solution obtained in the second step is brought into contact with the activated carbon (A) and the activated carbon (B) separately.

10. The method of producing a purified chlorogenic acid-containing composition according to claim 1 , wherein in the third step, the solution obtained in the second step is brought into contact with the activated carbon (A) and then with the activated carbon (B).

11. The method of producing a purified chlorogenic acid-containing composition according to claim 1 , wherein a concentration of an organic solvent in the aqueous solution of organic solvent is from 10 mass % to 95 mass %.

12. The method of producing a purified chlorogenic acid-containing composition according to claim 1 , wherein an organic solvent in the aqueous solution of organic solvent is ethanol.

13. The method of producing a purified chlorogenic acid-containing composition according to claim 1 , wherein in the first step, one or more selected from the group consisting of acid clay, activated clay, and a filter aid is added to said dispersion or solution.

14. The method of producing a purified chlorogenic acid-containing composition according to claim 1 , further comprising, after the second step and before the third step, or after the third step, adjusting a pH of the solution before treatment with the activated carbon or after treatment with the activated carbon to from 0.2 to 3.8.

15. The method of producing a purified chlorogenic acid-containing composition according to claim 1 , wherein an amount of the activated carbon (A) in the third step is from 0.4 time by mass to 2.0 times by mass with respect to solids in the raw material chlorogenic acid-containing composition in the first step.

16. The method of producing a purified chlorogenic acid-containing composition according to claim 1 , wherein an amount of the activated carbon (B) in the third step is from 0.1 time by mass to 0.8 time by mass with respect to solids in the raw material chlorogenic acid-containing composition in the first step.

Assignees

• Kao Corp

Inventors

• Sugiyama Yukiteru
• Yamawaki Kenji

Classifications

• A23F5/02

  Treating green coffee; Preparations produced thereby (roasting A23F5/04; removing unwanted substances A23F5/16; reducing or removing alkaloid content A23F5/20; extraction A23F5/24) · CPC title

• A23L33/105

  Plant extracts, their artificial duplicates or their derivatives · CPC title

• B01J39/04

  Processes using organic exchangers · CPC title

• A23L2/52

  Adding ingredients (adding preservatives A23B70/10) · CPC title

• C07C67/56 Primary

  by solid-liquid treatment; by chemisorption · CPC title