Anion exchange membranes and process for making

Patent metadata

Field	Value
Publication number	US-9944546-B2
Application number	US-201514603098-A
Country	US
Kind code	B2
Filing date	Jan 22, 2015
Priority date	Oct 15, 2010
Publication date	Apr 17, 2018
Grant date	Apr 17, 2018

Abstract

Embodiments of the present invention provide for anion exchange membranes and processes for their manufacture. The anion exchange membranes described herein are made the polymerization product of at least one functional monomer comprising a tertiary amine which is reacted with a quaternizing agent in the polymerization process.

First claim

The invention claimed is:

1. An anion exchange membrane, comprising:
a microporous membrane support having a porous first side, a porous second side, and a continuous porous structure comprising pores having a size of about 0.05 microns to about 10 microns extending from said first side to said second side; and
a crosslinked ion transferring polymer filling said continuous porous structure, said polymer formed in the porous structure from a polymer solution comprising a vinyl compound having nitrogen containing rings, the anion exchange membrane having a permselectivity of greater than about 92%.

2. The anion exchange membrane of claim 1 , wherein the vinyl compound is selected from the group consisting of vinylimidazole and vinylcarbazole.

3. The anion exchange membrane of claim 1 , wherein the polymer solution further comprises at least one crosslinking monomer, at least one quaternizing agent, and at least one polymerization initiator.

4. The anion exchange membrane of claim 2 , wherein the at least one crosslinking monomer is selected from the group consisting of: divinylbenzene, ethylene glycol dimethacrylate, vinylbenzyl chloride, dichloroethane, propylene glycol dimethacrylate, isobutylene glycol dimethacrylate, C 16 H 24 O 12 Si 8 , C 32 H 72 O 20 Si 16 , (CH 2 CH) n (SiO 1.5 ) n wherein n=8, 10, or 12, C 14 H 38 O 12 Si 7 , C 28 H 66 O 12 Si 7 , C 56 H 122 O 12 Si 7 , C 16 H 56 O 20 Si 16 , H 8 O 12 Si 8 , (C 8 H 13 O) n (SiO 1.5 ) n wherein n=8, 10, 12, (C 6 H 11 O 2 ) n (SiO 1.5 ) n wherein n=8, 10, or 12, (C 7 H 11 O 2 ) n (SiO 1.5 ) n wherein n=8, 10, or 12, and (C 6 H 9 O 2 ) n wherein n=8, 10, or 12.

5. The anion exchange membrane of claim 3 , wherein the at least one quaternizing agent is selected from the group consisting of benzyl chloride, benzyl bromide, vinyl benzyl chloride, dichloroethane, or methyl iodide.

6. The anion exchange membrane of claim 3 , wherein the at least one polymerization initiator is selected from the group consisting of organic peroxides, 2,2′ azobis[2,[2-imidazolin-2-yl]-propane] dihydrochloride, a,a′-azoisobutyronitrile, 2,2′-azobis[2-methylpropioaminidine]dihydrochloride, 2,2′ azobis[2, [2-imidazolin-2-yl]propane], or dimethyl2,2′azobis[2-methylpropionate.

7. The anion exchange membrane of claim 6 , wherein the organic peroxide is benzoyl peroxide.

8. The anion exchange membrane of claim 3 , wherein the polymer solution further comprises at least one polymerization inhibitor.

9. The anion exchange membrane of claim 8 , wherein the at least one polymerization inhibitor is selected from the group consisting of 4-methoxyphenol and 4-tert-butyl catechol.

10. The anion exchange membrane of claim 1 , wherein the microporous membrane support comprises polypropylene, high molecular weight polyethylene, ultrahigh molecular weight polyethylene or polyvinylidene fluoride.

11. The anion exchange membrane of claim 1 , wherein the thickness of the microporous membrane support is greater than about 55 microns and less than about 155 microns.

12. The anion exchange membrane of claim 1 , wherein the thickness of the microporous membrane support is greater than about approximately 20 microns and less than about 55 microns.

13. The anion exchange membrane of claim 1 , wherein the microporous membrane support has a pore size of from about 0.1 microns to about 1.0 microns.

14. The anion exchange membrane of claim 13 , wherein the microporous membrane support has a pore size of from about 0.1 microns to about 0.2 microns.

15. A process for producing an ion exchange membrane, comprising:
choosing a porous substrate having a porous first side, a porous second side, and a continuous porous structure extending from the first side to the second side, the continuous porous structure comprising pores having a size of about 0.05 microns to about 10 microns;
saturating the porous regions of the substrate with a monomeric solution comprising a vinyl compound having nitrogen containing rings;
removing excess solution from the substrate while leaving the continuous porous structure filled with solution; and
initiating polymerization to form a crosslinked anion exchange polymer in the continuous porous structure of the substrate, the ion exchange membrane having a permselectivity of greater than about 92%.

16. The process of claim 15 , wherein the vinyl compound is selected from the group consisting of vinylimidazole and vinylcarbazole.

17. The process of claim 15 , wherein the monomeric solution further comprises at least one crosslinking monomer, at least one quaternizing agent, and at least one polymerization initiator.

18. The process of claim 17 , wherein the at least one crosslinking monomer is selected from the group consisting of: divinylbenzene, vinylbenzyl chloride, dichloroethane, an octaglycidyl-polyhedral oligomeric silsequioxane or ethylene glycol dimethacrylate.

19. The process of claim 17 , wherein the at least one quaternizing agent is selected from the group consisting of benzyl chloride, vinyl benzyl chloride, dichloroethane, or methyl iodide.

20. The process of claim 17 , wherein the at least one polymerization initiator is selected from the group consisting of organic peroxides, 2,2′-azobis[2,(2-imidazolin-2-yl)-propane] dihydrochloride, a,a′azoisobutyronitrile, 2,2′-azobis(2-methylpropioaminidine) dihydrochloride, 2,2′-azobis[2,(2-imidazolin-2-yl)-propane], and dimethyl 2,2′-azo bis (2-methyl propionate).

21. The process of claim 20 , wherein the organic peroxide is benzoyl peroxide.

22. The process of claim 17 , wherein the monomeric solution further comprises at least one polymerization inhibitor.

23. The process of claim 22 , wherein the at least one polymerization inhibitor is selected from the group consisting of 4-methoxyphenol and 4-tert-butyl catechol.

24. The process of claim 15 , wherein the porous substrate comprises polypropylene, high molecular weight polyethylene, ultrahigh molecular weight polyethylene or polyvinylidene fluoride.

25. The process of claim 15 , wherein the thickness of the porous support is greater than about 55 microns and less than about 155 microns.

26. The process of claim 15 , wherein the thickness of the porous support is greater than about 20 microns and less than about 55 microns.

27. The process of claim 15 , wherein the porous substrate has a pore size of from about 0.1 microns to about 1.0 microns.

28. The process of claim 27 , wherein the porous substrate has a pore size of from about 0.1 microns to about 0.2 microns.

Assignees

• Evoqua Water Tech Llc

Inventors

• Lin Juchui Ray

Classifications

• C08F212/18 Primary

  Chlorine · CPC title

• H03K2005/00286

  Phase shifter, i.e. the delay between the output and input pulse is dependent on the frequency, and such that a phase difference is obtained independent of the frequency · CPC title

• H01Q3/36

  with variable phase-shifters · CPC title

• B01D67/0002

  Organic membrane manufacture · CPC title

• C08J2379/06

  Polyhydrazides; Polytriazoles; Polyamino-triazoles; Polyoxadiazoles · CPC title