Heat exchange process for adsorber regeneration

Patent metadata

Field	Value
Publication number	US-9943828-B2
Application number	US-201415517857-A
Country	US
Kind code	B2
Filing date	Oct 9, 2014
Priority date	Oct 9, 2014
Publication date	Apr 17, 2018
Grant date	Apr 17, 2018

Abstract

The invention relates to a process for regeneration of an adsorber (A) by contact with a stream (S 1 ), wherein the stream (S 1 ) is heated in advance by at least two heat exchange units (HEU 1 ) and (HEU 2 ). As outflow of the adsorber (A) a stream (S 2 ) is obtained, which is passed through at least two heat exchange units (HEU 1 ) and (HEU 2 ) traversed by stream (S 1 ), wherein the temperature of stream (S 2 ) fed into each heat exchange unit is higher than the temperature of stream (S 1 ) fed into the heat exchange units (HEU 1 ) and (HEU 2 ), in order to directly transfer heat from stream (S 2 ) to stream (S 1 ).

First claim

The invention claimed is:

1. A process for regenerating an adsorber (A) comprising:
a) heating a stream (S 1 ) in at least two heat exchange units (HEU 1 ) and (HEU 2 );
b) regenerating an adsorber (A) by contacting the adsorber (A) with the stream (S 1 ) such that a stream (S 2 ) is obtained as an outflow of the adsorber;
c) passing the stream (S 2 ) through the heat exchange unit (HEU 2 ), wherein the temperature of stream (S 2 ) fed into the heat exchange unit (HEU 2 ) is higher than the temperature of stream (S 1 ) fed into the heat exchange unit (HEU 2 ) such that heat is transferred from the stream (S 2 ) to the stream (S 1 ) in the heat exchange unit (HEU 2 );
d) passing the stream (S 2 ) through the heat exchange unit (HEU 1 ), wherein the temperature of stream (S 2 ) fed into the heat exchange unit (HEU 1 ) is higher than the temperature of the stream (S 1 ) fed into the heat exchange unit (HEU 1 ) such that heat is transferred from the stream (S 2 ) to the stream (S 1 ) in the heat exchange unit (HEU 1 ),
wherein
i) the passing in c) and d) are optionally carried out in parallel by splitting the stream (S 2 ) into two parts,
ii) the passing in c) is followed by the passing in d) and the temperature of stream (S 2 ) fed into the heat exchange unit (HEU 2 ) is higher than or equal to the temperature of stream (S 2 ) when being fed into the heat exchange unit (HEU 1 ), or
iii) temporarily only one of the passings in c) and d) is carried out,
and wherein the regenerating in b) comprises at least one of:
b1) heating the adsorber (A) by contacting the adsorber (A) with the gaseous stream (S 1 ), wherein the gaseous stream (S 1 ) is condensed within the adsorber,
b2) heating the adsorber (A) by contacting the adsorber (A) with the gaseous stream (S 1 ) up to a temperature in the range of from 230 to 270° C. without any condensation of the gaseous stream (S 1 ) within the adsorber (A),
b3) regenerating the absorber (A) at a temperature in the range of from 230 to 270° C. by contacting the adsorber (A) with the gaseous stream (S 1 ),
b4) cooling of the absorber by contacting the adsorber (A) with the gaseous stream (S 1 ), or
b5) cooling of the absorber (A) by contacting the adsorber (A) with the liquid stream (S 1 ) to a temperature below 80° C.,
and the heating in b1) is followed by the heating in b2), followed by the regenerating in b3), followed by the cooling in b4) and followed by the cooling in b5), and the heating of the adsorber (A) does not exceed 60° C./h and the temperature of the gaseous stream (S 1 ) is not more than 100° C. and higher than the adsorber (A), and the temperature of the gaseous or liquid stream (S 1 ) is not more than 100° C. and lower than the adsorber.

2. The process according to claim 1 , wherein at least one of the heat exchange units (HEU 1 ) and (HEU 2 ) or any further heat exchange unit employed in the process is an evaporator based on heat recovery or a superheater based on heat recovery.

3. The process according to claim 1 , wherein
i) in the passing in d), the heat exchange unit (HEU 1 ) is an evaporator configured to convert the stream (S 1 ) from liquid into gaseous phase, or in the passing in c), the heat exchange unit (HEU 2 ) is a superheater configured to superheat the stream (S 1 ), or
ii) the stream (S 1 ) is passed in the heating in a) through the heat exchange unit (HEU 1 ) prior to being passed through the heat exchange unit (HEU 2 ).

4. The process according to claim 1 , wherein
i) at least one evaporator is a Kettle-evaporator or a shell-and-tube evaporator, or
ii) at least one super-heater is a tube bundle heat exchanger,
iii) the stream (S 1 ) is passed in the heating in a) through at least one superheater (SH 1 ), prior to being passed through the heat exchange unit (HEU 2 ), or
iv) the stream (S 1 ) is passed in the heating in a) through at least one evaporator, prior to being passed through the heat exchange unit (HEU 2 ), or
v) the stream (S 1 ) is passed in the heating in a) through at least one further super-heater, after passing the heat exchange unit (HEU 2 ).

5. The process according to claim 1 , wherein the stream (S 2 ) is passed countercurrently to the stream (S 1 ) through the heat exchange unit in the passing in c) or the passing in d).

6. The process according to claim 1 , wherein the stream (S 1 )
comprises at least 99 wt % of at least one alkane, or
comprises not more than 1000 wt ppm olefin.

7. The process according to claim 1 , further comprising, prior to the heating in a):
e) hydrogenating a stream (S 0 ) such that the stream (S 1 ) is obtained,
wherein the stream (S 0 ) comprises at least one alkane and at least one olefin in a total of at least 96 wt %, or
the stream (S 0 ) comprises butane and butene.

8. The process according to claim 1 , wherein the stream (S 2 )
i) comprises at least one alkane and not more than 1000 wt ppm olefin,
ii) optionally comprises at least one compound containing oxygen or sulphur or
iii) is cooled, condensed, or cooled and condensed with at least one condenser or cooler after the passing in c) or the passing in d).

9. The process according to claim 1 , wherein the heating in a) comprises at least one of:
a1) feeding a liquid stream (S 1 ) into a flash vessel (FV) to obtain gaseous stream (S 1 ) and liquid stream (S 1 );
a2) superheating gaseous stream (S 1 ), optionally obtained in any one or a combination of a1), a3), a4), a5) and a6), in a super-heater (SH 1 );
a3) super-heating gaseous stream (S 1 ), optionally obtained in any one or a combination of a1), a2), a4), a5) and a6), in a heat exchange unit (HEU 2 ), which is a super-heater, wherein heat is recovered from the stream (S 2 );
a4) super-heating gaseous stream (S 1 ), optionally obtained in any one or a combination of a1), a2), a3), a5) and a6), in a further super-heater (H);
a5) converting liquid stream (S 1 ), optionally obtained in a1), in a heat exchange unit (HEU 1 ), which is an evaporator, wherein heat is recovered from the stream (S 2 ), into gaseous stream (S 1 ) used in any one or a combination of a2), a3) and a4);
a6) converting liquid stream (S 1 ), optionally remained from a5), in an evaporator (E), into gaseous stream (S 1 ) and the gaseous stream (S 1 ) obtained is used in any one or a combination of a2), a3), and a4).

10. The process according to claim 1 , wherein the flow direction of the gaseous stream (S 1 ) through the adsorber (A) in b1), b2) or b3) is opposite to the flow direction of any organic composition through the adsorber (A) during its operation mode, or the gaseous stream (S 1 ) in b4) or the liquid stream (S 1 ) in b5) have the same flow direction through the adsorber (A) as the flow direction of any organic composition through the adsorber (A) during its operation mode.

11. The process according to claim 1 , wherein the stream (S 1 ) originates from an organic composition which has been earlier purified by the adsorber (A) or by a similar further adsorber during the operation mode of the respective adsorber.

12. The process according to claim 7 , wherein an oligomerization of olefins, or a distillation process to separate butane from butene is carried out prior to the hydrogenating in e) and after the purification of the organic composition employing at least one adsorber in its operation mode.

13. The process according to claim 1 , wherein the adsorber (A) to be regenerated in a) is part of an assembly which contains at least one further adsorber.

14. The process according to claim 13 , wherein the at least one further adsorber is under its operation mode during the regeneration of the adso

Assignees

• Basf Se

Inventors

• Wagner Hans-Guenter
• Bayer Christoph
• Karrer Lothar
• Crone Sven
• Eggersmann Markus
• Kirchner Guenther
• Zimmer Gabriele
• Wong Kam Wing
• Pietz Patrik
• Ruetter Heinz

Classifications

• B01J20/3433

  of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425 · CPC title

• F28D7/10

  the conduits being arranged one within the other, e.g. concentrically {(multiple wall tubes for leak detection F28F1/003)} · CPC title

• B01J20/3483 Primary

  by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling · CPC title

• B01J20/3458

  in the gas phase · CPC title

• B01J20/3408

  of aluminosilicate molecular sieves · CPC title