Combined reactor for high-pressure synthesis of melamine

Patent metadata

Field	Value
Publication number	US-9938247-B2
Application number	US-201515118394-A
Country	US
Kind code	B2
Filing date	Jan 30, 2015
Priority date	Feb 18, 2014
Publication date	Apr 10, 2018
Grant date	Apr 10, 2018

Abstract

A reactor and associated process for the high-pressure synthesis of melamine from urea, comprising a primary step of conversion of the urea into crude melamine inside a first chamber delimited by a shell inside a reactor body and a secondary step of stripping said crude melamine melt inside a second reaction chamber, which is coaxial with and situated outside said first chamber, inside the same reactor body.

First claim

The invention claimed is:

1. A reactor for the synthesis of melamine from urea, using the high-pressure non-catalytic process, comprising:
a vertical reactor body having a urea melt inlet and a melamine outlet;
an inner reaction chamber and an outer reaction chamber, said outer reaction chamber being arranged coaxially around said inner chamber;
said at least one urea melt inlet arranged to introduce urea melt into said inner reaction chamber, wherein the urea melt contacts a circulating liquid mixture in the inner reaction chamber;
at least one path arranged to feed a raw melamine product effluent from said inner chamber into said outer chamber;
at least one ammonia inlet arranged to introduce gaseous ammonia into said outer reaction chamber, wherein said gaseous ammonia, in the outer chamber reaction chamber, has upward flow counter-current with a descending flow of said raw melamine product, so that the outer reaction chamber acts as a stripping chamber for said raw melamine product; and
at least one melamine header for collecting liquid melamine from said outer reaction chamber, said melamine header being connected to said melamine outlet, so that the melamine output of the reactor is withdrawn from the outer reaction chamber.

2. The reactor according to claim 1 , comprising a shell coaxial with said vertical body and situated inside said vertical body, wherein said shell delimits inside the reactor said inner reaction chamber and said outer reaction chamber.

3. The reactor according to claim 2 , said outer reaction chamber being delimited between said shell and said body of the reactor.

4. The reactor according to claim 3 , comprising a central duct coaxial with and situated inside said shell, which delimits an inner zone and a peripheral zone of said inner reaction chamber.

5. The reactor according to claim 4 , said urea melt inlet being designed to introduce urea melt into said inner zone of said inner reaction chamber.

6. The reactor according to claim 1 , said shell being cylindrical.

7. The reactor according to claim 4 , wherein said central duct communicates with the peripheral zone of the inner reaction chamber, said peripheral zone being delimited internally by the central duct and externally by said shell, and said peripheral zone communicating with said outer chamber.

8. The reactor according to claim 7 , wherein said shell extends up to a height greater than the height of said central duct and a top edge of said shell acts as an overflow distributor for feeding said outer reaction chamber.

9. The reactor according to claim 4 , comprising heating means which are housed inside said peripheral zone of the inner reaction chamber.

10. The reactor according to claim 1 , said inner chamber being cylindrical and said outer chamber being an annular chamber around said inner chamber.

11. The reactor according to claim 1 , comprising a distributor connected to said at least one gaseous ammonia inlet and configured to allow the introduction of ammonia in a distributed manner inside said outer chamber.

12. The reactor according to claim 11 , said distributor comprising a toroidal body housed substantially at the base of the outer chamber.

13. The reactor according to claim 1 , said header for the liquid melamine being housed at the bottom of said outer chamber.

14. The reactor according to claim 1 , comprising also a scrubber section situated in the top part of the said reactor above said inner chamber and outer chamber, and arranged to collect the gases coming from said chambers.

15. A plant for converting urea into melamine using the high-pressure process, comprising at least one reactor according to claim 1 .

16. A process for the high-pressure synthesis of melamine from urea, comprising:
a primary conversion step inside a first chamber delimited by a shell inside a reactor body, resulting in crude melamine melt,
a secondary step of stripping of said crude melamine melt inside a second reaction chamber, which is arranged coaxially around said first chamber, inside said reactor body,
wherein said stripping is performed with gaseous ammonia, flowing upward in the second reaction chamber, and in counter-current with a descendant crude melamine melt,
and melamine melt is withdrawn after stripping from said second reaction chamber.

17. The process according to claim 16 , said secondary stripping being carried out with gaseous ammonia.

18. The process according to claim 16 , also comprising the step of scrubbing of melamine off-gases produced during said primary and secondary steps, inside a scrubber section positioned above said coaxial reaction chambers and inside said reactor body.

19. The process according to claim 16 , said pressure being higher than 70 bar.

20. The process according to claim 16 , said pressure being between 70 and 250 bar.

Assignees

• Casale Sa

Inventors

• Rizzi Enrico

Classifications

• B01J3/04

  Pressure vessels, e.g. autoclaves · CPC title

• C07D251/60 Primary

  from urea or from carbon dioxide and ammonia · CPC title

• B01J4/02

  for feeding measured {, i.e. prescribed} quantities of reagents · CPC title

• B01J2219/00078

  Fingers · CPC title

• C07D251/62

  Purification of melamine · CPC title