Process for melamine purification

Patent metadata

Field	Value
Publication number	US-11059793-B2
Application number	US-201716318736-A
Country	US
Kind code	B2
Filing date	Jun 21, 2017
Priority date	Jul 22, 2016
Publication date	Jul 13, 2021
Grant date	Jul 13, 2021

Abstract

A process for the purification of a melamine melt ( 5 ) containing melamine and by-products, comprising the steps of: (a1) quenching of said melamine melt; (a2) decomposition of by-products with alkali, providing an alkaline aqueous solution of melamine ( 26 ); (b) stripping of said alkaline aqueous solution of melamine ( 26 ); (c) crystallization of melamine with a first alkali-containing solution ( 6 b ) and separation of solid melamine ( 7 ) from a mother liquor ( 8 ); (d) treatment of said mother liquor, providing a waste water stream ( 11 ) containing carbonates; (e) decomposition of at least part of the carbonates contained in said waste water stream ( 11 ) into carbon dioxide and alkali, providing a second alkali-containing aqueous solution ( 30 ); (f) recycle of at least part of said alkali-containing aqueous solution ( 30 ) to at least one of said steps (a1), (a2) and (c).

First claim

What is claimed is:

1. A process for the purification of a melamine melt containing melamine and by-products and obtained from a high pressure non-catalytic synthesis process, said process comprising the steps of:
(a1) quenching of said melamine melt;
(a2) decomposition with alkali of at least part of said by-products, providing an alkaline aqueous solution of melamine;
(b) stripping of said alkaline aqueous solution of melamine, resulting in a stripped melamine solution;
(c) crystallization of melamine from said stripped melamine solution with a first alkali-containing aqueous solution and separation of melamine from a mother liquor;
(d) treatment of at least part of said mother liquor, providing an aqueous solution containing carbonates;
(e) decomposition of at least part of the carbonates contained in said aqueous solution into carbon dioxide and alkali, providing a second alkali-containing aqueous solution separated from a water stream;
(f) recycle of at least part of said second alkali-containing aqueous solution to at least one of said steps (a1), (a2) and (c).

2. The process according to claim 1 , wherein said decomposition step (e) is performed by means of an electrolysis process of said aqueous solution containing carbonates.

3. The process according to claim 2 , wherein said aqueous solution containing carbonates is subjected to an ultrafiltration step before being sent to said electrolysis process.

4. The process according to claim 1 , wherein the second alkali-containing aqueous solution provided by said decomposition step (e) is at least partially subjected to a concentration step before being recycled to at least one of said steps (a1), (a2) and (c).

5. The process according to claim 1 , at least a portion of said second alkali-containing aqueous solution being recycled to said step (c), wherein said first alkali-containing aqueous solution ( 6 b ) is entirely or substantially entirely formed by said at least a portion of the second alkali-containing aqueous solution.

6. The process according to claim 1 , wherein said step (a1) of quenching is carried out in the presence of alkali and a third alkali-containing aqueous solution is fed to said step (a1) as a quenching medium.

7. The process according to claim 6 , wherein said third alkali-containing aqueous solution comprises a portion of said mother liquor provided from said step (c) of crystallization.

8. The process according to claim 7 , wherein said portion of the mother liquor and at least a portion of said second alkali-containing aqueous solution are mixed to form said third alkali-containing aqueous solution or a portion thereof.

9. The process according to claim 1 , wherein said alkali-containing solutions are sodium or potassium hydroxide solutions.

10. The process according to claim 1 , wherein said water stream is at least partially recycled back to a melamine plant.

Assignees

• Casale Sa

Inventors

• Scotto Andrea
• Gamba Simone

Classifications

• C07D251/62 Primary

  Purification of melamine · CPC title

• C07D251/60 Primary

  from urea or from carbon dioxide and ammonia · CPC title