System for producing carbon nanotubes from combustion engine exhausts

Patent metadata

Field	Value
Publication number	US-9932236-B2
Application number	US-201414166448-A
Country	US
Kind code	B2
Filing date	Jan 28, 2014
Priority date	Jul 2, 2009
Publication date	Apr 3, 2018
Grant date	Apr 3, 2018

Abstract

A filtration system that uses a filter to convert wastes in automotive exhausts into carbon nanotubes is disclosed. Metallic salts, such as iron salts, may be mixed with diesel fuel by way of using algal biodiesel to ensure homogenous suspension of the metallic salts in the diesel fuel. The metallic salts form a suitable catalyst to grow carbon nanotubes on a filter placed in the pathway of the diesel combustion exhaust. The filter surface may be composed of iron of similar catalyst. The filter may be placed along the pathway of exhaust streamlines preferably at an angle of more than 5 degrees and less than 15 degrees. The filter is heated to temperatures in the range of 200-1000 degrees Celsius. The filter described in this invention can work in its own or supplement existing filtration systems. The filtration system may produce a material that is commercially valuable, synthesized carbon nanotubes.

First claim

We claim:

1. A method of converting exhaust waste of combustion engines to carbon nanotubes within an exhaust system in fluid communication with the combustion engine, comprising:
generating combustion engine exhaust through combustion of a fuel including an iron salt;
heating at least one filter to at least 200 degrees Celsius;
passing combustion engine exhaust past the at least one filter positioned within the exhaust system of the combustion engine, wherein carbon nanotubes form on an exposed surface of the at least one filter; and
wherein generating combustion engine exhaust through combustion of a fuel including an iron salt comprises generating combustion engine exhaust through combustion of a diesel fuel including the iron salt having a concentration of between one mg of metal salt/ml of fuel and four mg of metal salt/ml of fuel.

2. The method of claim 1 , wherein generating combustion engine exhaust through combustion of a fuel including an iron salt comprises generating combustion engine exhaust through combustion of a diesel fuel including the iron salt.

3. The method of claim 1 , wherein generating combustion engine exhaust through combustion of a fuel including an iron salt comprises generating combustion engine exhaust through combustion of a diesel fuel including the iron salt, wherein the diesel fuel is formed from a mixture of algal biodiesel fuel and fossil diesel fuel.

4. The method of claim 1 , wherein generating combustion engine exhaust through combustion of a fuel including an iron salt comprises generating combustion engine exhaust through combustion of a diesel fuel including the iron salt, wherein the diesel fuel is formed from a mixture of algal biodiesel fuel, ethanol and fossil diesel fuel.

5. The method of claim 1 , wherein generating combustion engine exhaust through combustion of a fuel including an iron comprises generating combustion engine exhaust through combustion of a diesel fuel including the iron salt, wherein the diesel fuel is formed from a mixture of between one percent and ten percent algal biodiesel fuel, between one percent and ten percent ethanol and remainder fossil diesel fuel.

6. The method of claim 1 , wherein generating combustion engine exhaust through combustion of a fuel including an iron salt comprises generating combustion engine exhaust through combustion of a diesel fuel including the iron salt, wherein the diesel fuel is formed from a mixture of about five percent algal biodiesel fuel, about five percent ethanol and about 90 percent fossil diesel fuel.

7. The method of claim 1 , wherein generating combustion engine exhaust through combustion of a fuel including an iron salt comprises generating combustion engine exhaust through combustion of a diesel fuel including the iron salt, wherein the diesel fuel is formed from a mixture of algal biodiesel fuel and fossil diesel fuel.

8. The method of claim 1 , wherein generating combustion engine exhaust through combustion of a fuel including an iron salt comprises generating combustion engine exhaust through combustion of a diesel fuel including the iron salt, wherein the diesel fuel is formed from a mixture of algal biodiesel fuel, ethanol and fossil diesel fuel.

9. The method of claim 1 , wherein generating combustion engine exhaust through combustion of a fuel including an iron salt comprises generating combustion engine exhaust through combustion of a diesel fuel including the iron salt, wherein the diesel fuel is formed from a mixture of between one percent and ten percent algal biodiesel fuel, between one percent and ten percent ethanol and remainder fossil diesel fuel.

10. The method of claim 1 , wherein generating combustion engine exhaust through combustion of a fuel including an iron salt comprises generating combustion engine exhaust through combustion of a diesel fuel including the iron salt, wherein the diesel fuel is formed from a mixture of about five percent algal biodiesel fuel, about five percent ethanol and about 90 percent fossil diesel fuel.

11. The method of claim 1 , wherein passing combustion engine exhaust past the at least one filter comprises passing combustion exhaust past a surface formed of iron.

12. The method of claim 1 , wherein passing combustion engine exhaust past the at least one filter comprises passing combustion exhaust past a surface formed of carbonated steel.

13. The method of claim 1 , wherein passing combustion engine exhaust past the at least one filter comprises passing combustion exhaust past a surface formed of a layer formed from a material selected from a group consisting of iron, nickel and aluminum deposited on a surface.

14. The method of claim 1 , wherein passing combustion engine exhaust past the at least one filter comprises passing combustion exhaust past the at least one filter having a surface skewed relative to exhaust flow at an angle less than 45 degrees.

15. The method of claim 1 , wherein heating the at least one filter to at least 200 degrees Celsius comprises heating the at least one filter to a temperature between 200-700 degrees C.

16. The method of claim 1 , wherein passing combustion engine exhaust past the at least one filter positioned within the exhaust system of the combustion engine, comprises passing combustion engine exhaust past the at least one filter positioned within the exhaust system of the combustion engine such that carbon nanotubes having a diameter of 20-50 nm and a length of 1-10 micrometers form on an exposed surface of the at least one filter.

Assignees

• Univ United Arab Emirates

Inventors

• Haik Yousef
• Aldajah Saud

Classifications

• B01D69/10

  Supported membranes; Membrane supports · CPC title

• B01D2277/20

  Inclined, i.e. forming an angle of between 0° and 90° · CPC title

• B01D46/0063

  Operations & Transport · mapped topic

• C01B2202/36

  Diameter · CPC title

• C01B2202/30

  Purity · CPC title