Electroless metallization of dielectrics with alkaline stable pyrazine derivative containing catalysts

Patent metadata

Field	Value
Publication number	US-9918389-B2
Application number	US-201414477855-A
Country	US
Kind code	B2
Filing date	Sep 4, 2014
Priority date	Sep 4, 2013
Publication date	Mar 13, 2018
Grant date	Mar 13, 2018

Abstract

Pyrazine derivatives which contain one or more electron donating groups on the ring are used as catalytic metal complexing agents in aqueous alkaline environments to catalyze electroless metal plating on metal clad and un-clad substrates. The catalysts are monomers and free of tin and antioxidants.

First claim

What is claimed is:

1. A method comprising:
a) providing a substrate comprising a dielectric, wherein the dielectric is chosen from one or more of fiberglass, epoxy resin, acrylonitrile butadienestyrene, polyphenylene ethers, polyphenylene sulfides, polysulfones and polytetrafluoroethylene;
b) applying an aqueous alkaline catalyst solution to the substrate comprising the dielectric, the aqueous alkaline catalyst comprises a monomeric complex of palladium ions and one or more pyrazine derivatives having formula:

wherein R 1 , R 2 , R 3 and R 4 may be the same or different and are hydrogen, linear or branched (C 1 -C 5 )alky, —N(R) 2 , linear or branched amino(C 1 -C 5 )alkyl, acetyl, linear or branched hydroxy(C 1 -C 5 )alkyl, or linear or branched (C 1 -C 5 )alkoxy, and where R may be the same or different and is linear or branched (C 1 -C 5 )alkyl, and with the proviso that at least one of R 1 , R 2 , R 3 and R 4 is other than hydrogen, wherein the aqueous alkaline catalyst is free of tin;

c) applying a reducing agent to the substrate comprising the dielectric and the aqueous alkaline catalyst comprising the monomeric complex and the palladium ions to reduce the palladium ions to their metallic state prior to metallization of the substrate; and
d) immersing the substrate comprising the dielectric and palladium metal into an alkaline metal plating bath to electrolessly plate metal on the substrate comprising the dielectric.

2. The method of claim 1 , wherein the one or more pyrazine derivatives are chosen from 2,6-dimethylpyrazine, 2,3-dimethylpyrazine, 2,5-dimethylpyrazine, 2,3,5-trimethylpyraizine, 2-acetylpyrazine, ethylpyrazine, methoxypyrazine, 3,4-dimethylpyrazine and 2-(2′-hydroxyethyl)pyrazine.

3. The method of claim 1 , wherein a molar ratio of the one or more pyrazine derivatives to the metal ions is 1:1 to 4:1.

4. The method of claim 1 , wherein the electrolessly plated metal on the substrate is copper, copper alloy, nickel or nickel alloy.

5. The method of claim 1 , wherein the aqueous alkaline catalyst solution has a pH of 8.5 or greater.

6. The method of claim 5 , wherein the aqueous alkaline catalyst solution has pH of 9 or greater.

7. The method of claim 1 , wherein the substrate comprising the dielectric further comprises a plurality of through-holes.

8. The method of claim 7 , wherein the substrate comprising the dielectric further comprises metal cladding.

Assignees

• Rohm & Haas Elect Mat

Inventors

• Liu Feng
• Rzeznik Maria

Classifications

• C23C18/30 Primary

  Activating {or accelerating or sensitising with palladium or other noble metal} · CPC title

• C23C18/40

  using reducing agents · CPC title

• B01J2231/005

  General concepts, e.g. reviews, relating to methods of using catalyst systems, the concept being defined by a common method or theory, e.g. microwave heating or multiple stereoselectivity · CPC title

• C23C18/166

  with two steps starting with addition of reducing agent followed by metal deposition · CPC title

• C23C18/34

  using reducing agents · CPC title