Method and apparatus for preparing isopropyl alcohol

Patent metadata

Field	Value
Publication number	US-9895625-B2
Application number	US-201414559632-A
Country	US
Kind code	B2
Filing date	Dec 3, 2014
Priority date	Sep 6, 2012
Publication date	Feb 20, 2018
Grant date	Feb 20, 2018

Abstract

The present application relates to an apparatus for purifying isopropyl alcohol. The present application enables isopropyl alcohol to be obtained in a high purity from a feed comprising water and isopropyl alcohol with a minimum amount of energy consumption.

First claim

The invention claimed is:

1. A method for preparing isopropyl alcohol, comprising:
supplying a feed including isopropyl alcohol and water and having a water content of 1,000 ppm to 10,000 ppm to a dehydration column including molecular sieves;
removing the water with the dehydration column to adjust the water content of the feed to 300 ppm or less; and
supplying the feed of which the water content is adjusted to 300 ppm or less to a divided wall column to carry out purification,
wherein the divided wall column comprises a top region, a supply region, a discharge region, a bottom region and a dividing wall, wherein the dividing wall divides the divided wall column between the top region and the bottom region into the supply region and the discharge region,
wherein the supply region is bisected along a longitudinal direction of the divided wall column to form an upper supply region and a lower supply region, and the discharge region is bisected along a longitudinal direction of the divided wall column to form an upper discharge region and a lower discharge region,
wherein the purification includes supplying the feed of which the water content is adjusted to 300 ppm or less into the upper supply region of the divided wall column, carrying out purification in the divided wall column, and obtaining a discharge including the purified isopropyl alcohol from the lower discharge region of the divided wall column,
wherein upper and lower driving temperatures of the divided wall column are adjusted to 40° C. to 140° C. and 90° C. to 170° C., respectively,
wherein a driving pressure of the upper portion of the divided wall column is adjusted to 0.1 Kg/cm 2 to 10.0 Kg/cm 2 ,
wherein heat is exchanged between the discharge from the lower discharge region of the divided wall column and the feed supplied to the upper supply region of the divided wall column, and
wherein a reflux ratio of the discharge from the lower discharge region of the divided wall column is 1,000 to 3,000.

2. The method of claim 1 , wherein an average pore size of the molecular sieves is 1.0 Å to 5.0 Å.

3. The method of claim 1 , wherein the molecular sieves have a specific surface area of 10 m 2 /g to 3,000 m 2 /g.

4. The method of claim 1 , wherein the dehydration column includes a column in which the molecular sieves are filled.

5. The method of claim 1 , further comprising:
using nitrogen gas to regenerate the molecular sieves that have been used to adjust the water content of the feed.

6. The method of claim 5 , wherein the regeneration is carried out at 180° C. to 300° C.

7. An apparatus for preparing isopropyl alcohol, comprising:
a dehydration column including molecular sieves and installed to adjust a water content of a feed to 300 ppm or less and to discharge the feed when the feed including isopropyl alcohol and water and having the water content of 1,000 ppm to 10,000 ppm is supplied to the dehydration column;
a divided wall column installed to allow the feed passed through the dehydration column to be introduced and purification process to be carried out, wherein the divided wall column comprises a top region, a supply region, a discharge region, a bottom region and a divided wall, the divided wall dividing the divided wall column between the top region and the bottom region into the supply region and the discharge region, the supply region being bisected along a longitudinal direction of the divided wall column to form an upper supply region and a lower supply region, and the discharge region being bisected along a longitudinal direction of the divided wall column to form an upper discharge region and a lower discharge region; and
a heat exchanger installed to exchange heat between a discharge from the lower discharge region of the divided wall column and the feed supplied into the upper supply region of the divided wall column,
wherein the divided wall column is installed to supply the feed of which the water content is adjusted to 300 ppm or less into the upper supply region and to discharge the purified isopropyl alcohol from the supplied feed to the lower discharge region,
wherein upper and lower driving temperatures of the divided wall column are 40° C. to 140° C. and 90° C. to 170° C., respectively,
wherein driving pressure of the upper portion of the divided wall column is 0.1 Kg/cm 2 to 10.0 Kg/cm 2 , and
wherein a reflux ratio of the discharge from the lower discharge region of the divided wall column is 1,000 to 3,000.

8. The apparatus of claim 7 , wherein an average pore size of the molecular sieves is 1.0 Å to 5.0 Å.

9. The apparatus of claim 7 , wherein the molecular sieves have a specific surface area of 10 m 2 /g to 3,000 m 2 /g.

10. The apparatus of claim 7 , further comprising:
a regenerator including a nitrogen gas as a desorbing agent for the molecular sieves.

Assignees

• Lg Chemical Ltd

Inventors

• Lee Sung Kyu
• Lee Jong Ku
• Shin Joon Ho

Classifications

• B01D3/141 Primary

  where at least one distillation column contains at least one dividing wall · CPC title

• B01D3/007

  Energy recuperation; Heat pumps · CPC title

• B01D3/32 Primary

  Other features of fractionating columns {; Constructional details of fractionating columns not provided for in groups B01D3/16 - B01D3/30} · CPC title

• C07C29/76 Primary

  by physical treatment · CPC title

• B01D71/028

  Molecular sieves (carbon B01D71/021) · CPC title