Method for purifying isopropyl alcohol

Patent metadata

Field	Value
Publication number	US-2016200649-A1
Application number	US-201414912545-A
Country	US
Kind code	A1
Filing date	Aug 20, 2014
Priority date	Aug 20, 2013
Publication date	Jul 14, 2016
Grant date	—

Abstract

Provided are a method of and a device for purifying isopropyl alcohol. Water may be effectively removed from a feed including water and isopropyl alcohol while consuming a minimum amount of energy, and therefore high-purity isopropyl alcohol may be obtained.

First claim

1 . A method for purifying isopropyl alcohol, comprising:
removing water by providing a feed including isopropyl alcohol and water to a column charged with an adsorbent; and performing purification by providing the feed having a water content adjusted by removing water from the column to a divided wall column.

2 . The method according to claim 1 , wherein the adsorbent includes a molecular sieve, a silica gel, activated alumina, activated carbon or an ion exchange resin.

3 . The method according to claim 2 , further comprising regenerating a molecular sieve in which dehydration is performed using a nitrogen gas.

4 . The method according to claim 3 , wherein the regeneration is performed at 175 to 320° C.

5 . The method according to claim 1 , wherein the removal of water includes providing a feed having a water content of 1,200 to 5,000 ppm to a column charged with an adsorbent, and adjusting a water content of the feed to 500 ppm or less in the column.

6 . The method according to claim 1 , wherein the performing of purification includes providing the feed in which a water content is adjusted to 500 ppm or less to the divided wall column by removing water from the column and, adjusting a water content of the feed to 150 ppm or less.

7 . The method according to claim 1 , wherein the divided wall column is divided into a feed inflow region, a top region, a bottom region and a product outflow region, and the product outflow region is divided into an upper product outflow region and a lower product outflow region, and
performing the purification includes providing the feed in which a water content is adjusted to 500 ppm or less by removing water from the column to the feed inflow region of the divided wall column, performing purification in the divided wall column, and obtaining a discharged product including isopropyl alcohol and having a water content of 150 ppm or less from a lower product outflow region of the divided wall column.

8 . The method according to claim 7 , wherein the discharged product including purified isopropyl alcohol and having a water content of 150 ppm or less is obtained from 50 to 90% of plates of the number of theoretical plates calculated based on a top of the divided wall column.

9 . The method according to claim 7 , wherein a temperature of the top region of the divided wall column is adjusted to 40 to 120° C.

10 . The method according to claim 7 , wherein a pressure of the top region of the divided wall column is adjusted to 0.1 to 10.0 kg/cm 2 .

11 . The method according to claim 9 , wherein a temperature of a flow discharged from the lower product region of the divided wall column is 60 to 130° C.

12 . The method according to claim 10 , wherein a pressure of the lower product outflow region of the divided wall column is 0.3 to 6.0 kg/cm 2 .

13 . The method according to claim 9 , wherein a temperature of the bottom region of the divided wall column is 80 to 160° C.

14 . The method according to claim 10 , wherein a pressure of the bottom region of the divided wall column is 0.3 to 6.0 kg/cm 2 .

15 . A device for purifying isopropyl alcohol, comprising:
a column charged with an adsorbent into which a feed including isopropyl alcohol and water is introduced, and discharging the feed by adjusting a water content of the feed; and a divided wall column including a divided wall column into which the feed passing

16 . The device according to claim 15 , wherein the adsorbent includes a molecular sieve, a silica gel, activated alumina, activated carbon, or an ion exchange resin.

17 . The device according to claim 16 , wherein the molecular sieve includes a zeolite, silica-alumina or silicate alumina.

18 . The device according to claim 16 , wherein the molecular sieve has an average micropore size of 1.0 to 5.0 Å.

19 . The device according to claim 16 , wherein the molecular sieve has a specific surface area of 100 to 1,500 m 3 /g.

20 . The device according to claim 15 , wherein the divided wall column is divided into a feed inflow region, a top region, a bottom region and a product outflow region, and the product outflow region is divided into an upper product outflow region and a lower product outflow region, and
wherein the feed in which a water content is adjusted to 500 ppm or less by removing water from the column is provided to the feed inflow region of the divided wall column, and a discharged product including purified isopropyl alcohol and having a water content of 150 ppm or less is discharged from the lower product outflow region of the divided wall column.

Assignees

• Lg Chemical Ltd

Inventors

• Park Jong Suh
• Lee Sung Kyu
• Shin Joon Ho
• Lee Jong Ku

Classifications

• C07C29/82 Primary

  by azeotropic distillation · CPC title

• C07C29/80

  by distillation · CPC title

• C07C29/76 Primary

  by physical treatment · CPC title

• B01D15/08

  Selective adsorption, e.g. chromatography · CPC title