Non-line of sight deposition of erbium based plasma resistant ceramic coating

Patent metadata

Field	Value
Publication number	US-9850573-B1
Application number	US-201615191269-A
Country	US
Kind code	B1
Filing date	Jun 23, 2016
Priority date	Jun 23, 2016
Publication date	Dec 26, 2017
Grant date	Dec 26, 2017

Abstract

Described herein is a method of depositing a plasma resistant ceramic coating onto a surface of a chamber component using a non-line-of-sight (NLOS) deposition process, such as atomic layer deposition (ALD) and chemical vapor deposition (CVD). The plasma resistant ceramic coating consists of an erbium containing oxide, an erbium containing oxy-fluoride, or an erbium containing fluoride. Also described are chamber components having a plasma resistant ceramic coating of an erbium containing oxide, an erbium containing oxy-fluoride, or an erbium containing fluoride.

First claim

What is claimed is:

1. A method comprising:
depositing a multi-layer stack onto a surface of a chamber component using a chemical vapor deposition (CVD) process or an atomic layer deposition (ALD) process; and
annealing the chamber component comprising the multi-layer stack to convert the multi-layer stack into a plasma resistant ceramic coating, wherein the plasma resistant ceramic coating is selected from a group consisting of:
an erbium containing fluoride of Y x Er y F z , where x, y and z are selected such that the erbium containing fluoride of Y x Er y F z contains over 0 mol % to under 100 mol % YF 3 and over 0 mol % to under 100 mol % ErF 3 , and
an erbium containing oxy-fluoride Y w Er x O x F z , where w, x, y and z are selected such that the erbium containing oxy-fluoride of Y w Er x O x F z contains over 0 mol % to under 100 mol % of three or more of Y 2 O 3 , YF 3 , Er 2 O 3 and ErF 3 .

2. The method of claim 1 , wherein the chamber component comprises a conduit, and wherein the surface of the chamber component onto which the plasma resistant ceramic coating is deposited comprises an internal surface of the conduit that has an aspect ratio between 50:1 and 200:1.

3. The method of claim 1 , wherein the plasma resistant ceramic coating has a zero porosity.

4. The method of claim 1 , further comprising:
prior to depositing the multi-layer stack, cleaning the surface of the chamber component using an acid solution, the acid solution comprising 0.1-20 vol % hydrochloric acid to improve an adhesion of the plasma resistant ceramic coating to the chamber component.

5. The method of claim 1 , wherein the annealing is performed at a temperature of 300-1000° C.

6. The method of claim 1 , wherein each layer in the multi-layer stack has a thickness of about 0.1-100 nm.

7. A method comprising:
depositing a multi-layer stack onto a surface of a chamber component using an atomic layer deposition (ALD) process, wherein the multi-layer stack comprises at least one of an erbium containing oxide, an erbium containing oxy-fluoride, or an erbium containing fluoride, and wherein depositing the multi-layer stack comprises:
depositing a first layer using the ALD process, the first layer consisting essentially of Er 2 O 3 or ErF 3 ;
depositing a second layer using the ALD process, the second layer consisting of a different material than the first layer, wherein the second layer consists essentially of Er 2 O 3 , Al 2 O 3 , ErF 3 , Y 2 O 3 or YF 3 ; and
depositing one or more additional layers using the ALD process, each of the one or more additional layers consisting essentially of one of Er 2 O 3 , Al 2 O 3 , ErF 3 , Y 2 O 3 or YF 3 ; and

annealing the chamber component comprising the multi-layer stack, wherein the annealing causes the first layer, the second layer and the one or more additional layers to interdiffuse and transform into a single layer of a plasma resistant ceramic coating, the single layer comprising a solid state phase.

8. The method of claim 7 , wherein the plasma resistant ceramic coating consists essentially of Er 3 Al 5 O 12 .

9. The method of claim 7 , wherein the plasma resistant ceramic coating consists essentially of Y x Er y O z , where x, y and z are selected such that the erbium containing oxide of Y x Er y O z contains over 0 mol % to under 100 mol % Y 2 O 3 and over 0 mol % to under 100 mol % Er 2 O 3 .

10. The method of claim 7 , wherein the plasma resistant ceramic coating consists essentially of Er x O y F z , where x, y and z are selected such that the erbium containing oxy-fluoride of Er x O y F z contains over 0.1 at. % to under 100 at. % Er, over 0.1 at. % to under 100 at. % 0 and over 0.1 at. % to under 100 at. % F.

11. The method of claim 7 , wherein the plasma resistant ceramic coating consists essentially of Y x Er y F z , where x, y and z are selected such that the erbium containing fluoride of Y x Er y F z contains over 0 mol % to under 100 mol % YF 3 and over 0 mol % to under 100 mol % ErF 3 .

12. The method of claim 7 , wherein the plasma resistant ceramic coating consists essentially of Y w Er x O y F z , where w, x, y and z are selected such that the erbium containing oxy-fluoride of Y w Er x O y F z contains over 0 mol % to under 100 mol % of three or more of Y 2 O 3 , YF 3 , Er 2 O 3 and ErF 3 .

13. The method of claim 7 , wherein the annealing is performed at a temperature of 300-1000° C.

14. The method of claim 7 , wherein the first layer, the second layer and the one or more additional layers each have a thickness of about 0.1-100 nm.

15. The method of claim 7 , wherein the single layer is an approximately homogenous layer.

16. A method comprising:
depositing a multi-layer stack onto a surface of a chamber component using an atomic layer deposition (ALD) process, wherein the multi-layer stack comprises at least one of an erbium containing oxide, an erbium containing oxy-fluoride, or an erbium containing fluoride, and wherein depositing the multi-layer stack comprises:
depositing a first layer using the ALD process, the first layer consisting essentially of ErF 3 ;
depositing a second layer using the ALD process, the second layer consisting essentially of Er 2 O 3 , Al 2 O 3 , ZrO 2 , Y 2 O 3 or YF 3 ; and
depositing one or more additional layers using the ALD process, each of the one or more additional layers consisting essentially of one of Er 2 O 3 , ZrO 2 , Al 2 O 3 , ErF 3 , Y 2 O 3 or YF 3 ; and

annealing the chamber component comprising the multi-layer stack, wherein the annealing causes the first layer, the second layer and the one or more additional layers to interdiffuse and transform into a single layer of a plasma resistant coating, the single layer comprising a solid state phase.

17. The method of claim 16 , wherein the annealing is performed at a temperature of 300-1000° C.

18. The method of claim 16 , wherein the first layer, the second layer and the one or more additional layers each have a thickness of about 0.1-100 nm.

19. The method of claim 16 , wherein the single layer is an approximately homogenous layer.

Assignees

• Applied Materials Inc

Inventors

• Sun Jennifer Y

Classifications

• C23C16/0227

  by cleaning or etching · CPC title

• H01J37/32467

  Material · CPC title

• C23C16/40 Primary

  Oxides · CPC title

• C23C16/405

  of refractory metals or yttrium · CPC title

• C23C16/403

  of aluminium, magnesium or beryllium · CPC title