Thermal interface materials with low secant modulus of elasticity and high thermal conductivity

Patent metadata

Field	Value
Publication number	US-9828539-B2
Application number	US-201615184865-A
Country	US
Kind code	B2
Filing date	Jun 16, 2016
Priority date	Jun 30, 2015
Publication date	Nov 28, 2017
Grant date	Nov 28, 2017

Abstract

Disclosed are exemplary embodiments of thermal interface materials with low secant modulus of elasticity and high thermal conductivity.

First claim

What is claimed is:

1. A thermal interface material comprising a matrix or base resin loaded with thermally-conductive filler, wherein the thermal interface material has a thermal conductivity of at least 6 Watts per meter per Kelvin and a secant modulus of elasticity of no more than 620 kilopascals (kPa) at 50% strain for 1.5 millimeter (mm) initial thickness material, and wherein:
the thermally-conductive filler comprises alumina and aluminum, and the matrix or base resin is loaded with the alumina and aluminum such that the thermal interface material includes at least 90 weight % of the alumina and aluminum; and
the matrix or base resin comprises: a polydimethylsiloxane (PDMS); or silicone polymer with platinum catalyst and silicone polymer with SiH crosslinking oligomer; or a process oil.

2. The thermal interface material of claim 1 , wherein the thermally-conductive filler further comprises one or more of zinc oxide, boron nitride, silicon nitride, aluminum nitride, iron, metallic oxides, graphite, silver, copper, and ceramic.

3. The thermal interface material of claim 1 , wherein the matrix or base resin comprises silicone polymer with platinum catalyst and silicone polymer with SiH crosslinking oligomer.

4. The thermal interface material of claim 1 , wherein the thermally-conductive filler comprises at least two different grades of alumina and at least two different grades of aluminum.

5. The thermal interface material of claim 1 , wherein the thermal interface material comprises a thermally-conductive gap filler, a dispensable material, or a bulk putty.

6. The thermal interface material of claim 1 , wherein: the thermal interface material has a secant modulus of elasticity of no more than 17 kPA at 50% strain for 1.5 mm initial thickness material and a thermal conductivity of at least 9 Watts per meter per Kelvin; the matrix or base resin comprises silicone polymer with platinum catalyst and silicone polymer with SiH crosslinking oligomer; and the thermal interface material further comprises pigment and coupling agent.

7. The thermal interface material of claim 6 , wherein:
the thermal interface material includes about 94.31 weight % of the alumina and aluminum; and/or
the thermal interface material includes about 51.22 weight % of alumina and about 43.09 weight % of aluminum.

8. The thermal interface material of claim 1 , wherein: the thermal interface material has a secant modulus of elasticity of no more than 3.8 kPa at 50% strain for 1.5 mm initial thickness material and/or a thermal conductivity of at least 8.3 Watts per meter per Kelvin; the matrix or base resin comprises a polydimethylsiloxane (PDMS); and the thermal interface material further comprises pigment and coupling agent.

9. The thermal interface material of claim 8 , wherein:
the thermal interface material includes about 92.83 weight % of the alumina and aluminum; and/or
the thermal interface material includes about 37.83 weight % of alumina and about 54.99 weight % of aluminum.

10. The thermal interface material of claim 1 , wherein: the thermal interface material has a secant modulus of elasticity of no more than 269 kPA at 50% strain for 1.5 mm initial thickness material and a thermal conductivity of at least 9 Watts per meter per Kelvin; the matrix or base resin comprises process oil; and the thermal interface material further comprises pigment and coupling agent.

11. The thermal interface material of claim 10 , wherein:
the thermal interface material includes about 92.95 weight % of the alumina and aluminum; and/or
the thermal interface material includes about 50.47 weight % of alumina and about 42.48 weight % of aluminum.

12. The thermal interface material of claim 1 , wherein the thermally-conductive filler includes:
a first grade of alumina comprising alumina particles that are spherical in shape and having a mean particle size of about 0.3 microns with particle sizes ranging from about 0.1 microns to about 0.6 microns;
a second grade of alumina comprising alumina particles that are spherical in shape and having a mean particle size of about 1.5 microns with particle sizes ranging from about 1.2 microns to about 2 microns;
a third grade of alumina comprising alumina particles that are spherical in shape and having a mean particle size of about 11 microns with particle sizes ranging from about 8 microns to about 16 microns;
a first grade of aluminum comprising aluminum particles that are spherical in shape and having a mean particle size of about 150 microns with particle sizes ranging from about 76 microns to about 260 microns;
a second grade of aluminum comprising aluminum particles that are spherical in shape and having a mean particle size of about 80 microns with particle sizes ranging from about 46 microns to about 135 microns;
a third grade of aluminum comprising aluminum particles that are spherical in shape and having a mean particle size of about 5 microns with particle sizes ranging from about 2.7 microns to about 9 microns; and
a fourth grade of aluminum comprising aluminum particles that are spherical in shape and having a mean particle size of about 50 microns with particle sizes ranging from about 23 microns to about 90 microns.

13. A thermal interface material comprising a matrix or base resin loaded with thermally-conductive filler, wherein the thermal interface material has a thermal conductivity of at least 6 Watts per meter per Kelvin and a secant modulus of elasticity of no more than 620 kilopascals (kPa) at 50% strain for 1.5 millimeter (mm) initial thickness material; wherein the thermally-conductive filler includes: a first grade of alumina comprising alumina particles that are spherical in shape and having a mean particle size of about 0.3 microns with particle sizes ranging from about 0.1 microns to about 0.6 microns; a second grade of alumina comprising alumina particles that are spherical in shape and having a mean particle size of about 1.5 microns with particle sizes ranging from about 1.2 microns to about 2 microns; a third grade of alumina comprising alumina particles that are spherical in shape and having a mean particle size of about 11 microns with particle sizes ranging from about 8 microns to about 16 microns; a first grade of aluminum comprising aluminum particles that are spherical in shape and having a mean particle size of about 150 microns with particle sizes ranging from about 76 microns to about 260 microns; a second grade of aluminum comprising aluminum particles that are spherical in shape and having a mean particle size of about 80 microns with particle sizes ranging from about 46 microns to about 135 microns; a third grade of aluminum comprising aluminum particles that are spherical in shape and having a mean particle size of about 5 microns with particle sizes ranging from about 2.7 microns to about 9 microns; and a fourth grade of aluminum comprising aluminum particles that are spherical in shape and having a mean particle size of about 50 microns with particle sizes ranging from about 23 microns to about 90 microns; wherein the thermal interface material includes: about 2.89 weight % of silicone polymer with platinum catalyst, about 2.37 weight % of the silicone with SiH crosslinking oligomer, about 0.06 weight % of pigment, about 0.36 weight % of coupling agent, about 0.71 weight % of the first grade of alumina, about 19.91 weight % of the second grade of alumina, about 30.6 weight % of the third grade of alumina, about 17.47 weight % of the first grade of aluminum, about 4.99 weight % of the second grade of aluminum, about 8.74 weight % of the third grade of aluminum, and about 11.89 weight % of the fourth grade of alumi

Assignees

• Laird Technologies Inc

Inventors

• Bruzda Karen
• Cancar Kathryn

Classifications

• H05K7/20481

  characterised by the material composition exhibiting specific thermal properties · CPC title

• C08L83/04 Primary

  Polysiloxanes · CPC title

• C08K2201/003

  Additives being defined by their diameter · CPC title

• C08K2003/0812

  Aluminium · CPC title

• C08K2201/014

  Additives containing two or more different additives of the same subgroup in C08K · CPC title