Method for isomerizing an aromatic C8 fraction in the presence of a catalyst containing an EUO zeolite and a specific binder

Patent metadata

Field	Value
Publication number	US-9828311-B2
Application number	US-201214366006-A
Country	US
Kind code	B2
Filing date	Nov 20, 2012
Priority date	Dec 20, 2011
Publication date	Nov 28, 2017
Grant date	Nov 28, 2017

Abstract

A process for isomerizing an aromatic cut containing at least one aromatic compound containing eight carbon atoms per molecule is described, comprising bringing said cut into contact with at least one catalyst comprising at least one metal from group VIII of the periodic classification of the elements, at least one zeolitic support comprising a zeolite selected from zeolites with structure type EUO and MOR, used alone or as a mixture, and at least one matrix, such that the specific surface area of the matrix in the zeolitic support of said catalyst is in the range 5 to 200 m 2 /g.

First claim

The invention claimed is:

1. A process for isomerizing an aromatic cut containing at least one aromatic compound containing eight carbon atoms per molecule, comprising bringing said aromatic cut into contact with at least one catalyst comprising at least one metal from group VIII of the periodic classification of the elements and at least one zeolitic support,
wherein the at least one zeolitic support comprises a zeolite selected from zeolites with structure type EUO and MOR, used alone or as a mixture, and an alumina matrix, and
wherein the alumina matrix in the at least one zeolitic support of said at least one catalyst has a specific surface area in a range of 20 to less than 150 m 2 /g.

2. The process according to claim 1 , in which the alumina matrix in the at least one zeolitic support of said at least one catalyst has a specific surface area in a range of 50 to less than 150 m 2 /g.

3. The process according to claim 1 , in which said at least one catalyst comprises 1% to 90% by weight of zeolite with structure type EUO and/or MOR with respect to a total catalyst weight.

4. The process according to claim 1 , in which the zeolite with structure type EUO is selected from the group consisting of EU-1, TPZ-3, ZSM-50,and a mixture thereof.

5. A process according to claim 4 , in which the zeolite with structure type EUO is EU-1 zeolite.

6. A process according to claim 1 , in which the zeolite with structure type MOR is mordenite.

7. The process according to claim 1 , in which the zeolite used in the at least one zeolitic support of the at least one catalyst is a mixture of EU-1 zeolite and mordenite.

8. The process according to claim 1 , in which said at least one catalyst comprises a quantity of metal(s) from group VIII in the range 0.01% to 4% by weight with respect to a total catalyst weight.

9. The process according to claim 1 , in which said at least one catalyst further comprises at least one metal selected from metals from groups DIA, IVA and VIIB, said metal(s) being in a quantity of 2% by weight or less with respect to a total catalyst weight.

10. The process according to claim 1 , in which the process is carried out at a temperature of 300° C. to 500° C., a partial pressure of hydrogen of 0.3 to 1.5 MPa, a total pressure of 0.45 to 1.9 MPa, and an hourly space velocity, expressed in kilograms of feed introduced per kilogram of catalyst per hour, of 0.25 to 30 h −1 .

Assignees

• Ifp Energies Now

Inventors

• Guillon Emmanuelle
• Sanchez Eric

Classifications

• C07C2523/44

  Palladium · CPC title

• C07C2521/06

  Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof · CPC title

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• B01J2229/42

  Addition of matrix or binder particles · CPC title

• C07C15/08

  Xylenes · CPC title