Catalyst system and use in heavy aromatics conversion processes

Patent metadata

Field	Value
Publication number	US-9802181-B2
Application number	US-201615004662-A
Country	US
Kind code	B2
Filing date	Jan 22, 2016
Priority date	Feb 4, 2015
Publication date	Oct 31, 2017
Grant date	Oct 31, 2017

Abstract

Disclosed are a catalyst system and its use in a process for the conversion of a feedstock containing C 8 + aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst system comprises (a) a first catalyst bed comprising a first catalyst composition, said first catalyst composition comprising a zeolite having a constraint index of 3 to 12 combined (i) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (ii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table; and (b) a second catalyst bed comprising a second catalyst composition, said second catalyst composition comprising (i) a meso-mordenite zeolite, combined (ii) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (iii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said meso-mordenite zeolite is synthesized from TEA or MTEA and having a mesopore surface area of greater than 30 m 2 /g and said meso-mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.

First claim

The invention claimed is:

1. A process for conversion of C 8+ aromatic hydrocarbons to lighter aromatic products, the process comprising the steps of:
a) contacting a first feedstock comprising said C 8+ aromatic hydrocarbons and optionally hydrogen in the presence of a first catalyst composition, under conversion conditions including at least a temperature of 340° C. to 515° C., a pressure from 380 kPa (55 psia) to 4240 kPa (615 psia) and a weight hourly space velocity (WHSV) in the range of 1 to 100 hr −1 based on the weight of said feedstock, to produce a second feedstock, said first catalyst composition comprising a ZSM-5 zeolite combined with (i) at least one first metal of Group 10 of the IUPAC Periodic Table, and/or (ii) at least one second metal of Group 11 to 15 of the IUPAC Periodic Table; and
b) contacting said second feedstock with a second catalyst composition to produce said lighter aromatic products comprising xylenes, benzene, toluene and mixtures of two or more thereof, said second catalyst composition comprising:
(i) a meso-mordenite zeolite synthesized from TEA or MTEA and having a mesopore surface area of greater than 30 m 2 /g and comprising agglomerates of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2, combined with
(ii) at least one first metal of Group 10 of the IUPAC Periodic Table, and/or
(iii) at least one second metal of Group 11 to 15 of the IUPAC Periodic Table.

2. The process of claim 1 , wherein said at least first metal of Group 10 is selected from the group consisting of nickel, platinum, palladium and mixtures thereof.

3. The process of claim 1 , wherein said C 8+ aromatic hydrocarbons comprises aromatic compounds having nine or more carbon atoms.

4. The process of claim 1 , wherein said feedstock further comprises benzene, toluene or a mixture thereof.

5. The process of claim 1 , wherein said C 8+ aromatic hydrocarbons comprises aromatic compounds having a boiling point in the range of 135° C. to 260° C. at atmospheric pressure.

6. The process of claim 1 , further comprising step a) and b) are carried out in a reactor, said reactor comprising at least one first catalyst bed in fluid communication with a second catalyst bed, said first catalyst bed having said first catalyst composition and said second catalyst bed having said second catalyst composition.

7. The process of claim 1 , wherein said at least one second metal of Group 11 to 15 is selected from the group consisting of copper, zinc, silver, gallium, indium, tin, bismuth and a mixture of two or more thereof.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Elia Christine N
• Luo Shifang L
• Nair Hari
• Lai Wenyih F
• Tinger Robert G

Classifications

• B01J29/67

  Noble metals · CPC title

• C07C2521/04

  Alumina · CPC title

• B01J37/0201

  Impregnation · CPC title

• B01J29/7476

  MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25 · CPC title

• C01B39/265

  using at least one organic template directing agent · CPC title