Process for making a NiO-doped aluminogallate nanocomposite

Patent metadata

Field	Value
Publication number	US-9821295-B2
Application number	US-201715634297-A
Country	US
Kind code	B2
Filing date	Jun 27, 2017
Priority date	Feb 19, 2016
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

The present disclosure relates to a process for producing a finely divided metal-doped aluminogallate nanocomposite comprising mixing a carrier solvent with a bulk metal-doped aluminogallate nanocomposite to form a bulk metal-doped aluminogallate slurry and atomizing the bulk metal-doped aluminogallate slurry using a low temperature collision to produce a finely divided metal-doped aluminogallate nanocomposite, the composition of a nickel-doped aluminogallate nanocomposite (GAN), and a method of NO decomposition using the nickel-doped aluminogallate nanocomposite.

First claim

The invention claimed is:

1. A process for producing a finely divided NiO-doped aluminogallate nanocomposite having a spinel structure comprising:
mixing a carrier solvent with a bulk metal-doped aluminogallate nanocomposite synthesized by a process selected from the group consisting of co-precipitation, sol-gel, and hydrothermal to form a bulk metal-doped aluminogallate slurry, wherein the bulk metal-doped aluminogallate nanocomposite comprises:
Ga 2 O 3 ;
Al 2 O 3 ; and
nickel oxide dopant; and

atomizing the bulk metal-doped aluminogallate slurry using a collision to produce the finely divided NiO-doped aluminogallate nanocomposite;
wherein the carrier solvent is at least one selected from the group consisting of deionized water, ethanol, butanol, isopropyl alcohol, diacetone alcohol, diglycol, triglycol, acetone, methyl ethyl ketone, ethyl acetate, butyl acetate, toluene, and xylene.

2. The process of claim 1 , wherein the bulk divided NiO-doped aluminogallate is synthesized by a hydrothermal process comprising:
adding a precipitating agent to an aqueous solution comprising a gallium salt, an aluminum salt, and a nickel dopant salt to form a nickel-doped aluminogallate suspension with a pH of 8-12; and
heating the nickel-doped aluminogallate suspension to a hydrothermal reaction temperature in a range of 100° C.-350° C., for a reaction time range of 24-100 hrs to form the bulk metal-doped aluminogallate nanocomposite.

3. The process of claim 2 , wherein the bulk metal-doped aluminogallate slurry, the finely divided NiO-doped aluminogallate nanocomposite or both are not calcined or milled.

4. The process of claim 1 , wherein the atomizing comprises:
injecting the bulk metal-doped aluminogallate slurry into a fluid carrier stream to produce a bulk metal-doped aluminogallate slurry stream;
colliding the bulk metal-doped aluminogallate slurry stream with a surface of at least one collision agent within an atomizing unit reaction zone at a flow rate and a sufficient pressure to atomize the bulk metal-doped aluminogallate slurry stream and form the finely divided NiO-doped aluminogallate nanocomposite without any heat induced phase transitions.

5. The process of claim 4 , wherein the atomizing unit is a wet jet atomizer.

6. The process of claim 4 , wherein the sufficient pressure is 50 MPa-400 MPa.

7. The process of claim 4 , wherein prior to the colliding the bulk metal-doped aluminogallate slurry stream passes through a nozzle having a nozzle diameter of 50 μm-300 μm.

8. The process of claim 4 , wherein the flow rate of the bulk metal-doped aluminogallate slurry is 2 L/hr to 840 L/hr.

9. The process of claim 4 , wherein the at least one collision agent is at least a portion of the bulk metal-doped aluminogallate slurry.

10. The process of claim 4 , wherein the at least one collision agent is a ceramic ball.

11. The process of claim 1 , wherein the bulk metal-doped aluminogallate slurry comprises:
20-45 mol % Ga 2 O 3 ;
35-60 mol % Al 2 O 3 ; and
2-30 mol % nickel oxide dopant relative to the total molar composition of the bulk metal-doped aluminogallate nanocomposite.

12. The process of claim 1 , wherein the finely divided NiO-doped aluminogallate nanocomposite having a spinel structure further has a diameter of 100-200 nm and a surface area range of 250-300 m 2 /g.

Assignees

• Univ King Fahd Pet & Minerals

Inventors

• Zahir Md Hasan
• Khalid Alhooshani

Classifications

• B01J23/14

  of germanium, tin or lead · CPC title

• B01J23/825 Primary

  with gallium, indium or thallium · CPC title

• B01J37/036

  to form a gel or a cogel · CPC title

• B01J37/10

  in the presence of water, e.g. steam · CPC title

• B01D2255/209

  Other metals · CPC title