Metal compound, method for preparing the same, selective metallization of surface of substrate with the metal compound

Patent metadata

Field	Value
Publication number	US-10059852-B2
Application number	US-201414242763-A
Country	US
Kind code	B2
Filing date	Apr 1, 2014
Priority date	Apr 2, 2013
Publication date	Aug 28, 2018
Grant date	Aug 28, 2018

Abstract

The present disclosure provides a metal compound. The metal compound is represented by a formula (I): Cu 2 A α B 2-α O 4-β (I). A contains at least one element selected from the groups 6 and 8 of the periodic table. B contains at least one element selected from the group 13 of the periodic table, 0<α<2, and 0<β<1.5. Polymer article containing the metal compound and method for preparing the polymer article as well as selective metallization of a surface of the polymer article are also provided. In addition, the present disclosure provides an ink composition and the selective metallization for a surface of the insulative substrate using the ink composition.

First claim

What is claimed is:

1. A polymer article comprising:
a polymer matrix, and
particles dispersed in the polymer matrix, the particles comprising a metal compound having a formula (I)
Cu 2 A α B 2-α O 4-β   (I),

wherein
A comprises at least one element selected from the groups 6 and 8 of the periodic table,
B comprises at least one element selected from the group 13 of the periodic table,
0.5≤α<2,
0<β<1.5, and
if A is Fe, B is not Al.

2. The polymer article according to claim 1 , wherein A comprises at least one element selected from a group consisting of Cr, Mo and Fe.

3. The polymer article according to claim 1 , wherein B comprises at least one element selected from a group consisting of Al, Ga and In.

4. The polymer article according to claim 1 , wherein the metal compound further comprises CuO, and based on the total weight of the metal compound, the content of the CuO is less than about 0.01 mol %.

5. The polymer article according to claim 1 , wherein the particles have an average particle diameter of about 0.01 μm to about 5 μm.

6. The polymer article according to claim 1 , wherein based on the total weight of the polymer article, the content of the metal compound is about 1 wt % to about 30 wt %.

7. The polymer article according to claim 1 , wherein B comprises Al.

8. The polymer article according to claim 1 , wherein B comprises In.

9. The polymer article according to claim 1 , wherein A comprises Cr and/or Mo.

10. The polymer article according to claim 1 , wherein the metal compound comprises at least one selected from a group consisting of Cu 2 Cr 0.6 Al 1.4 O 3.3 , Cu 2 FeGaO 3.9 , Cu 2 Mo 1.2 In 0.8 O 3.5 , Cu 2 Cr 0.5 Al 1.5 O 3 , Cu 2 Mo 0.5 Al 1.5 O 3 , Cu 2 Cr 0.8 Ga 1.2 O 3.9 , Cu 2 Cr 1.1 Al 0.9 O 3.5 , Cu 2 Fe 0.5 In 1.5 O 3 , Cu 2 Cr 0.5 Ga 1.5 O 2.8 , Cu 2 Cr 0.3 Mo 0.3 Al 1.4 O 3.3 and Cu 2 Cr 0.6 Ga 0.7 Al 0.7 O 3.3 .

11. A polymer article comprising:
a polymer matrix, and
particles dispersed in the polymer matrix, the particles comprising a metal compound having a formula (I)
Cu 2 A α B 2-α O 4-β   (I),

wherein
A comprises at least one element selected from the groups 6 and 8 of the periodic table,
B comprises Al and/or In,
0<α<2,
0<β<1.5, and
if A is Fe, B is not Al.

12. The polymer article according to claim 11 , wherein A comprises Cr and/or Mo.

13. The polymer article according to claim 11 , wherein B comprises In.

14. The polymer article according to claim 11 , wherein the metal compound further comprises CuO, and based on the total weight of the metal compound, the content of the CuO is less than about 0.01 mol %.

15. The polymer article according to claim 11 , wherein the particles have an average particle diameter of about 0.01 μm to about 5 μm.

16. A polymer article comprising:
a polymer matrix, and
particles dispersed in the polymer matrix, the particles comprising a metal compound having a formula (I)
Cu 2 A α B 2-α O 4-β   (I),

wherein
A comprises Cr and/or Mo,
B comprises at least one element selected from the group 13 of the periodic table,
0<α<2, and
0<β<1.5.

17. The polymer article according to claim 16 , wherein B comprises Al and/or In.

18. The polymer article according to claim 16 , wherein B comprises In.

19. The polymer article according to claim 16 , wherein the metal compound further comprises CuO, and based on the total weight of the metal compound, the content of the CuO is less than about 0.01 mol %.

20. The polymer article according to claim 16 , wherein the particles have an average particle diameter of about 0.01 μm to about 5 μm.

Assignees

• Shenzhen Byd Auto R&D Co Ltd
• Byd Co Ltd

Inventors

• Gong Qing
• Zhou Wei
• Mao Bifeng
• Miao Weifeng

Classifications

• B01J37/04

  Mixing {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• C23C18/1608

  from pretreatment step, i.e. selective pre-treatment · CPC title

• B01J31/06

  containing polymers {(organometallic polymers B01J31/123; polymer-bound organometallic complexes B01J31/165; coordination polymers B01J31/1691)} · CPC title

• C01G15/006

  Compounds containing gallium, indium or thallium, with or without oxygen or hydrogen, and containing two or more other elements · CPC title

• C23C18/1651

  Two or more layers only obtained by electroless plating · CPC title