Microstructure of metal interconnect layer
US-2016133573-A1 · May 12, 2016 · US
US9761523B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9761523-B2 |
| Application number | US-201514832055-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 21, 2015 |
| Priority date | Aug 21, 2015 |
| Publication date | Sep 12, 2017 |
| Grant date | Sep 12, 2017 |
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A semiconductor device structure with twin-boundaries and method for forming the same are provided. The semiconductor device structure includes a substrate and a conductive structure formed over the substrate. The conductive structure includes twin boundaries, and a density of the twin boundaries is in a range from about 25 μm −1 to about 250 μm −1 .
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What is claimed is: 1. A semiconductor device structure, comprising: a substrate; and a conductive structure formed over the substrate, wherein the conductive structure comprises twin boundaries, and a density of the twin boundaries is in a range from about 25 μm −1 to about 250 μm −1 . 2. The semiconductor device structure as claimed in claim 1 , wherein the twin boundaries have an average twin-lamella width in a range from about 4 nm to about 40 nm. 3. The semiconductor device structure as claimed in claim 1 , wherein the conductive structure comprises: a diffusion barrier layer; and a conductive material formed over the diffusion barrier layer. 4. The semiconductor device structure as claimed in claim 1 , wherein a lattice mismatch ratio between a lattice constant of the diffusion barrier layer and a lattice constant of the conductive material is in a range from about 0.1% to about 6%. 5. The semiconductor device structure as claimed in claim 3 , further comprising: a glue layer formed between the diffusion barrier layer and the conductive material, wherein a lattice mismatch ratio between a lattice constant of the glue layer and a lattice constant of the conductive material is in a range from about 0.1% to about 6%. 6. The semiconductor device structure as claimed in claim 4 , wherein the diffusion barrier layer is made of ruthenium (Ru), nickel (Ni), ∝-cobalt (Co), β-cobalt (Co), cobalt nitride (Co4N) or combinations thereof. 7. The semiconductor device structure as claimed in claim 1 , further comprising: a via-trench structure formed over the conductive material, wherein the via-trench structure comprises twin boundaries, and a density of the twin boundaries is in a range from about 25 μm −1 to about 250 μm −1 . 8. The semiconductor device structure as claimed in claim 1 , further comprising: a device element formed in the substrate; and a dielectric layer formed over the device element, wherein the conductive structure is electrically connected to the device element. 9. A semiconductor device structure, comprising: a first dielectric layer formed over a substrate; a diffusion barrier layer formed in the first dielectric layer; and a conductive material formed over the diffusion barrier layer, wherein a lattice mismatch ratio between a lattice constant of the diffusion barrier layer and a lattice constant of the conductive material is in a range from about 0.1% to about 6%. 10. The semiconductor device structure as claimed in claim 9 , wherein the conductive structure comprises twin boundaries, and a density of the twin boundaries is a in a range from about 25 μm −1 to about 250 μm −1 . 11. The semiconductor device structure as claimed in claim 10 , wherein the twin boundaries have an average twin-lamella width in a range from about 4 nm to about 40 nm. 12. The semiconductor device structure as claimed in claim 9 , wherein the diffusion barrier layer is made of ruthenium (Ru), nickel (Ni), ∝-cobalt (Co), β-cobalt (Co), cobalt nitride (Co4N) or combinations thereof. 13. The semiconductor device structure as claimed in claim 9 , further comprising: a glue layer formed between the diffusion barrier layer and the conductive material, wherein a lattice mismatch ratio between a lattice constant of the glue layer and a lattice constant of the conductive material is in a range from about 0.1% to about 6%. 14. The semiconductor device structure as claimed in claim 9 , further comprising: a via-trench structure formed over the conductive material, wherein the via-trench structure comprises twin boundaries, and a density of the twin boundaries is in a range from about 25 μm −1 to about 250 μm −1 . 15. A semiconductor device structure, comprising: a first dielectric layer formed over a substrate; a first diffusion barrier layer formed in the first dielectric layer; a first conductive material formed over the first diffusion barrier layer; and a via-trench structure formed over the conductive material, wherein the via-trench structure comprises twin boundaries, and a density of the twin boundaries is in a range from about 25 μm −1 to about 250 μm −1 . 16. The semiconductor device structure as claimed in claim 15 , wherein the via-trench structure comprises a second diffusion barrier layer and a second conductive material formed over the second diffusion barrier layer, and a lattice mismatch ratio between a lattice constant of the second diffusion barrier layer and a lattice constant of the second conductive material is in a range from about 0.1% to about 6%. 17. The semiconductor device structure as claimed in claim 16 , wherein the via-trench structure further comprises a second glue layer between the second diffusion barrier layer and the second conductive material. 18. The semiconductor device structure as claimed in claim 15 , further comprising: an etch stop layer formed over the first dielectric layer; and a capping layer formed in the etch stop layer, wherein the via-trench structure is formed over the capping layer and in direct contact with the capping layer. 19. The semiconductor device structure as claimed in claim 15 , further comprising: a first glue layer formed between the first diffusion barrier layer and the first conductive material, wherein a lattice mismatch ratio between a lattice constant of the first glue layer and a lattice constant of the first conductive material is in a range from about 0.1% to about 6%. 20. The semiconductor device structure as claimed in claim 15 , wherein the twin boundaries have an average twin-lamella width in a range from about 4 nm to about 40 nm.
Electrolytic deposition, i.e. electroplating; Electroless plating · CPC title
on sidewalls or on top surfaces of conductors (H10W20/076 takes precedence) · CPC title
the barrier, adhesion or liner layers being on top of a main fill metal · CPC title
Barrier, adhesion or liner layers · CPC title
by forming openings in the dielectric parts · CPC title
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