Halogen-free thermosetting resin composition, prepreg and laminate for printed circuit prepared from the same

Patent metadata

Field	Value
Publication number	US-9752028-B2
Application number	US-201514679387-A
Country	US
Kind code	B2
Filing date	Apr 6, 2015
Priority date	Dec 29, 2014
Publication date	Sep 5, 2017
Grant date	Sep 5, 2017

Abstract

The present invention relates to a halogen-free thermosetting resin composition, and also a prepreg and a laminate for printed circuit prepared from the halogen-free thermosetting resin composition. The halogen-free thermosetting resin composition comprises, based on 100 parts by weight of organic solids, (A) from 30 to 60 parts by weight of a halogen-free epoxy resin, (B) from 5 to 30 parts by weight of a first curing agent of phosphorus-containing bisphenol, (C) from 5 to 30 parts by weight of a second curing agent of alkylphenol novolac, and (D) a phosphorus-containing flame retardant. The prepreg and laminate for printed circuit prepared from the halogen-free thermosetting resin composition according to the present invention have high glass transition temperature, excellent dielectric properties, low water absorption, high thermal resistance and better process workability, and can fulfill halogen-free flame retardance and achieve the grade of UL94 V-0.

First claim

The invention claimed is:

1. A halogen-free thermosetting resin composition, consisting of, based on 100 parts by weight of organic solids,
(A) from 30 to 60 parts by weight of a halogen-free epoxy resin,
(B) from 5 to 30 parts by weight of a first curing agent of phosphorus-containing bisphenol;
(C) from 5 to 30 parts by weight of a second curing agent of alkylphenol novolac;
(D) a phosphorus-containing flame retardant; and
(E) optionally one or more liquid solvents;
the phosphorus-containing bisphenol has the following structure

wherein n 2 is an integer of 2 to 20; and
the alkylphenol novolac has the following structure

wherein R 3 , R 4 and R 5 are all independently selected from substituted or unsubstituted linear or branched alkyl groups having 4-8 carbon atoms; and n 3 is an integer from 2 to 20.

2. The halogen-free thermosetting resin composition according to claim 1 , characterized in that the halogen-free epoxy resin is one selected from or a mixture of at least two selected from bisphenol-A epoxy resin, bisphenol-F epoxy resin, o-cresol novolac epoxy resin, bisphenol-A novolac epoxy resin, trisphenol novolac epoxy resin, dicyclopentadiene novolac epoxy resin, biphenyl novolac epoxy resin, alkylbenzene novolac epoxy resin and naphthol novolac epoxy resin.

3. The halogen-free thermosetting resin composition according to claim 2 , characterized in that the halogen-free epoxy resin is selected from the epoxy resin having the following structure,

wherein, X 1 , X 2 and X 3 are each independently selected from

R 1 is selected from hydrogen atom, substituted or unsubstituted C1-C5 linear alkyl, and substituted or unsubstituted C1-C5 branched alkyl;
Y 1 and Y 2 are each independently selected from single bonds, —CH2—,

wherein n 1 is an integer from 1 to 10; R 2 is selected from hydrogen atom, substituted or unsubstituted C1-C5 linear alkyl, and substituted or unsubstituted C1-C5 branched alkyl.

4. A prepreg comprising a reinforcing material and a halogen-free thermosetting resin composition according to claim 2 which is attached thereon after impregnation and drying.

5. A laminate comprising at least one prepreg according to claim 4 .

6. The halogen-free thermosetting resin composition according to claim 1 , characterized in that the phosphorus-containing bisphenol has a weight average molecular weight of from 1000 to 6500.

7. The halogen-free thermosetting resin composition according to claim 1 , characterized in that, based on 100 parts of weight of the addition amount of the sum of components (A), (B) and (C), the component (D) is added in an amount of from 5 to 50 parts by weight.

8. A prepreg comprising a reinforcing material and a halogen-free thermosetting resin composition according to claim 1 which is attached thereon after impregnation and drying.

9. A laminate comprising at least one prepreg according to claim 8 .

10. The halogen-free thermosetting resin composition according to claim 1 , characterized in that the phosphorus-containing flame retardant is one selected from or a mixture of at least two selected from tri-(2,6-dimethylphenyl)-phosphine, 10-(2,5-dihydroxylphenyl)-9,10-dihydro-9-oxa-10- phosphaphenanthrene-10-oxide, 2,6-di-(2,6-dimethylphenyl) phosphine benzene, 10-phenyl -9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, phenoxyphosphazene compound, phosphate, polyphosphate, polyphosphonate and phosphonate-carbonate copolymers.

Assignees

• Shengyi Technology Co Ltd

Inventors

• You Jiang
• Huang Tianhui
• Yang Zhongqiang

Classifications

• C08G59/4071 Primary

  phosphorus containing compounds · CPC title

• C08G59/621

  Phenols · CPC title

• C08L63/00

  Compositions of epoxy resins; Compositions of derivatives of epoxy resins · CPC title

• C08K5/0066

  Flame-proofing or flame-retarding additives · CPC title

• C08L63/04 Primary

  Epoxynovolacs · CPC title