Method of making textured ceramics

Patent metadata

Field	Value
Publication number	US-9708224-B2
Application number	US-201514821817-A
Country	US
Kind code	B2
Filing date	Aug 10, 2015
Priority date	Jul 15, 2015
Publication date	Jul 18, 2017
Grant date	Jul 18, 2017

Abstract

The invention proposed a novel hot pressing flowing sintering method to fabricate textured ceramics. The perfectly 2-dimensional textured Si3N4 ceramics (Lotgering orientation factor fL 0.9975) were fabricated by this method. During the initial sintering stage, the specimen flowed along the plane which is perpendicular to the hot pressing direction under pressure, through the controlling of the graphite die movement. The rod-like β-Si3N4 nuclei was easily to texture during the flowing process, due to the small size of the β-Si3N4 nuclei and the high porosity of the flowing specimen. After aligned, the β-Si3N4 grains grew along the materials flowing direction with little constraint. textured Si3N4 ceramics fabricated by this invention also showed high aspect ratio. Compared to the conventional hot-forging technique which contained the sintering and forging processes, hot pressing flowing sintering proposed is simpler and lower cost to fabricate textured Si3N4.

First claim

What is claimed is:

1. A method of making textured ceramics, comprising:
step a, preparing a powder, wherein the step a comprises milling mixed powders containing a Si 3 N 4 powder and sintering aids as a slurry in a ball mill using the Si 3 N 4 powder and drying the slurry to obtain the prepared powder with α-Si 3 N 4 particles;
step b, forming a green part, wherein the step b comprises dry pressing the prepared powder through a steel die and then performing a cold isostatic pressing on the dry pressed powder to obtain the green part with a shaped body;
step c, performing a texturing process by a hot pressing flowing sintering, wherein the step c comprises loading the green part in a graphite die, and then gradually increasing an applied pressure on the green part until a target pressure in a sintering temperature range and keeping the applied pressure at the target pressure for a certain period of time such that the α-Si 3 N 4 particles are changed into rod-like β-Si 3 N 4 nuclei and then flow in a one-dimensional or two-dimensional directions perpendicular to a direction of the applied pressure to align and anisotropically grow along the flow direction(s) under the applied pressure and thereby achieve textured Si 3 N 4 ceramics with one-dimensional or two-dimensional texture.

2. The method of making textured ceramics according to claim 1 , wherein the sintering aids are selected from the group consisting of alkali metal oxides and rare earth metal oxides.

3. The method of making textured ceramics according to claim 1 , wherein a cold isostatic pressure used for the cold isostatic pressing is 50-300 MPa.

4. The method of making textured ceramics according to claim 1 , wherein the texturing process is performed in the graphite die, and using flowing inert gas atmosphere for protection.

Assignees

• Dongguan South China Design And Innovation Inst
• Univ Guangdong Technology
• Dongguan South China Design And Innovation Inst

Inventors

• Wu Shanghua
• Jiang Qiangguo
• Guo Weiming
• Gu Shangxian
• Zhou Maopeng
• Liu Wei
• Cheng Lixia
• Wang Bo
• Wang Chengyong
• Wang Qimin

Classifications

• C04B35/593 Primary

  obtained by pressure sintering · CPC title

• C04B2235/605

  Making or treating the green body or pre-form in a magnetic field · CPC title

• C04B35/65

  Reaction sintering of free metal- or free silicon-containing compositions {(C04B35/573, C04B35/591 take precedence)} · CPC title

• C04B2235/787

  Oriented grains · CPC title

• C04B2235/6025

  Tape casting, e.g. with a doctor blade · CPC title