Resin composition, prepreg, and laminate

Patent metadata

Field	Value
Publication number	US-9706651-B2
Application number	US-201214362200-A
Country	US
Kind code	B2
Filing date	Nov 30, 2012
Priority date	Dec 7, 2011
Publication date	Jul 11, 2017
Grant date	Jul 11, 2017

Abstract

To provide a prepreg resin composition which has good solubility in a solvent and with which moreover a cured product having excellent flame resistance and a low water absorption rate can be made simply and with good reproducibility, and a prepreg and a laminate and a printed wiring board and the like using the same. The prepreg resin composition of the present invention including at least a cyanate compound (A) obtained by cyanation of a phenol-modified xylene formaldehyde resin, an epoxy resin (B), and an inorganic filler.

First claim

The invention claimed is:

1. A prepreg resin composition comprising at least a cyanate compound (A) obtained by cyanation of a phenol-modified xylene formaldehyde resin, an epoxy resin (B), and an inorganic filler (C), and
wherein 30 to 70 parts by mass of the cyanate compound (A) is contained based on 100 parts by mass of a total of the (A) component and the (B) component,
wherein 30 to 70 parts by mass of the epoxy resin (B) is contained based on 100 parts by mass of the total of the (A) component and the (B) component,
wherein the weight average molecular weight Mw of the cyanate compound (A) is 250 to 10,000,
wherein the cyanate compound (A) is at least one selected from the group consisting of the cyanate compound having a structure represented by the following general formula (Ia) and the cyanate compound having a structure represented by the following general formula (Ib),

wherein, in the formula (la), R 1 each independently represents a methylene group, a methyleneoxy group, a methyleneoxymethylene group, or an oxymethylene group, T 1 represents a hydrogen atom, a hydroxyl group, or a hydroxymethylene group, w represents an integer of 0 or 1, m represents an integer of 0 or more, and n 1 and n 2 each independently represent an integer of 1 or more,

wherein, in the formula (Ib), R 1 each independently represents a methylene group, a methyleneoxy group, a methyleneoxymethylene group, or an oxymethylene group, T 1 represents a hydrogen atom, a hydroxyl group, or a hydroxymethylene group, w represents an integer of 0 or 1, m represents an integer of 0 or more, and n 1 and n 2 each independently represent an integer of 1 or more,
wherein the epoxy resin (B) is a biphenyl aralkyl-based epoxy resin represented by the following general formula (10),

wherein R 6 each independently represents a hydrogen atom or a methyl group, and o represents an integer of 1 to 50.

2. The prepreg resin composition according to claim 1 , wherein the inorganic filler (C) is silica.

3. The prepreg resin composition according to claim 1 , wherein 10 to 300 parts by mass of the inorganic filler (C) is contained based on 100 parts by mass of the total of the (A) component and the (B) component.

4. A prepreg obtained by impregnating or coating a substrate with the prepreg resin composition according to claim 1 .

5. A laminate comprising a plurality of the prepregs according to claim 4 that are laminated.

6. A metal foil-clad laminate comprising the prepreg according to claim 4 and metal foil laminated on the prepreg.

7. A printed wiring board comprising the laminate according to claim 6 .

8. A printed wiring board comprising an insulating layer and a conductor layer formed on a surface of the insulating layer, wherein the insulating layer comprises the prepreg resin composition according to claim 1 .

Assignees

• Mitsubishi Gas Chemical Co

Inventors

• Saito Chisato
• Sogame Masanobu
• Mabuchi Yoshinori
• Kato Yoshihiro

Classifications

• Y10T428/31522

  Next to metal · CPC title

• C08L63/00

  Compositions of epoxy resins; Compositions of derivatives of epoxy resins · CPC title

• Y10T428/24917

  including metal layer · CPC title

• Y10T428/24802

  Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] · CPC title

• Y10T428/31515

  As intermediate layer · CPC title