SiC single crystal manufacturing method using alternating states of supersaturation

Patent metadata

Field	Value
Publication number	US-9624599-B2
Application number	US-201114350448-A
Country	US
Kind code	B2
Filing date	Dec 9, 2011
Priority date	Oct 31, 2011
Publication date	Apr 18, 2017
Grant date	Apr 18, 2017

Abstract

A SiC single crystal manufacturing method whereby growing speed improvement required to have high productivity can be achieved, while maintaining flat growth in which uniform single crystal growth can be continued at the time of growing a SiC single crystal using a solution method. In the method, a SiC single crystal is grown in a crucible from a Si solution containing C. The method includes alternately repeating: a high supersaturation degree growing period, in which the growth is promoted by maintaining the supersaturation degree of C in the Si solution higher than an upper limit critical value at which flat growth can be maintained, the supersaturation degree being at a growing interface between the Si solution and a SiC single crystal being grown; and a low supersaturation degree growing period, in which the growth is promoted by maintaining the supersaturation degree lower than the critical value.

First claim

What is claimed is:

1. A method for manufacturing a SiC single crystal in which a SiC single crystal is grown from a Si solution of C in a crucible, employing alternate repetition between a high supersaturation growth period in which growth is progressed while keeping a degree of supersaturation of C in the Si solution at a growth boundary between the growing SiC single crystal and the Si solution higher than a maximum critical value at which flat growth can be maintained, and a low supersaturation growth period in which growth is progressed while keeping the degree of supersaturation lower than the critical value,
wherein the ratio between a value Sa which is the difference between the high degree of supersaturation and the critical value integrated over a continuous time during the high supersaturation growth period, and a value Sb which is the difference between the low degree of supersaturation and the critical value integrated over a continuous time during the low supersaturation growth period, Sb/Sa, is greater than or equal to 1.25.

2. A method for manufacturing a SiC single crystal in which a SiC single crystal is grown from a Si solution of C in a crucible, employing alternate repetition between a high supersaturation growth period in which growth is progressed while keeping a degree of supersaturation of C in the Si solution at a growth boundary between the growing SiC single crystal and the Si solution higher than a maximum critical value at which flat growth can be maintained, and a low supersaturation growth period in which growth is progressed while keeping the degree of supersaturation lower than the critical value,
wherein the degree of supersaturation is varied by varying a height of a meniscus formed from the growth boundary up to a surface of the Si solution in the crucible.

3. The method for manufacturing a SiC single crystal according to claim 1 , wherein the degree of supersaturation is varied by varying a temperature gradient in the Si solution in the crucible.

4. The method for manufacturing a SiC single crystal according to claim 1 , wherein the degree of supersaturation is varied by varying a height of a meniscus formed from the growth boundary up to a surface of the Si solution in the crucible.

Assignees

• Kado Motohisa
• Daikoku Hironori
• Kusunoki Kazuhiko
• Toyota Motor Co Ltd
• Nippon Steel & Sumitomo Metal Corp

Inventors

• Kado Motohisa
• Daikoku Hironori
• Kusunoki Kazuhiko

Classifications

• C30B15/02

  adding crystallising materials or reactants forming it in situ to the melt · CPC title

• C30B29/36

  Carbides · CPC title

• C30B19/04 Primary

  the solvent being a component of the crystal composition · CPC title

• C30B15/22 Primary

  Stabilisation or shape controlling of the molten zone near the pulled crystal; Controlling the section of the crystal · CPC title