Metal oxide particle production method and production device

Patent metadata

Field	Value
Publication number	US-9617166-B2
Application number	US-201013389989-A
Country	US
Kind code	B2
Filing date	Aug 3, 2010
Priority date	Aug 24, 2009
Publication date	Apr 11, 2017
Grant date	Apr 11, 2017

Abstract

An object of the present invention is to provide a method for producing metal oxide particles, in which metal oxide particles with high photocatalytic activity is produced, and a production apparatus therefor. The above object can be achieved by using a method for producing metal oxide particles, which includes subjecting a reaction gas containing metal chloride and an oxidizing gas containing no metal chloride in a reaction tube ( 11 ) to preheating, and then subjecting a combined gas composed of the reaction gas and the oxidizing gas to main heating in a main heating region (A) apart from the downstream side of the junction ( 5 b ), wherein the time until the combined gas from the junction ( 5 b ) arrives at the upstream end (A 1 ) of the main heating region (A) is adjusted to be less than 25 milliseconds.

First claim

The invention claimed is:

1. A method for producing metal oxide particles, which comprises subjecting a reaction gas containing metal chloride and an oxidizing gas containing no metal chloride in a reaction tube to preheating, and then subjecting a combined gas composed of the reaction gas and the oxidizing gas to main heating in a main heating region apart from the downstream side of the junction, wherein
the time until the combined gas from the junction arrives at the upstream end of the main heating region through a middle region, at which no heating device is provided, is adjusted to be 8 milliseconds to less than 25 milliseconds, wherein at least one of a light shield plate and a heat shield plate is provided outside the reaction tube at the middle region.

2. The method for producing metal oxide particles according to claim 1 , wherein the reaction tube includes a double-tube structure portion composed of a hollow outer cylinder and a hollow inner cylinder inserted into the upstream side of the hollow outer cylinder, and
the reaction gas is allowed to flow into the hollow inner cylinder and also the oxidizing gas is allowed to flow into a site between the hollow inner cylinder and the hollow outer cylinder, thereby allowing the downstream end portion of the hollow inner cylinder to serve as the junction of the reaction gas and the oxidizing gas.

3. The method for producing metal oxide particles according to claim 1 , wherein the metal chloride is titanium tetrachloride, and the metal oxide particles are titanium oxide particles.

4. The method for producing metal oxide particles according to claim 3 , wherein the titanium oxide particles are decahedral titanium oxide particles.

5. The method for producing metal oxide particles according to claim 1 , wherein the preheating temperature is 136° C. or higher and 750° C. or lower.

6. The method for producing metal oxide particles according to claim 1 , wherein the main heating temperature is 800° C. or higher and 1,500° C. or lower.

7. The method for producing metal oxide particles according to claim 1 , wherein the reaction gas contains an oxygen gas and/or a nitrogen gas.

8. The method for producing metal oxide particles according to claim 1 , wherein the oxidizing gas contains an oxygen gas, a nitrogen gas, argon, water vapor, or at least two kinds thereof.

9. The method for producing metal oxide particles according to claim 1 , wherein a linear velocity of the oxidizing gas is adjusted to be within a range of from 0.1 to 10 based on a linear velocity of the reaction gas on the upstream side of the downstream end portion of the hollow inner cylinder.

10. The method for producing metal oxide particles according to claim 3 , wherein the concentration of titanium tetrachloride contained in the combined gas is adjusted to be from 0.1 to 20% by volume on the downstream side of the downstream end portion of the hollow inner cylinder.

11. The method for producing metal oxide particles according to claim 1 , wherein the time during which the combined gas remains in the main heating region is adjusted to be from 2 to 500 milliseconds.

12. The method for producing metal oxide particles according to claim 1 , wherein the Reynolds number of the combined gas is adjusted to be from 10 to 10,000.

13. The method for producing metal oxide particles according to claim 1 , wherein the middle region is a non-heating region.

Assignees

• Ohtani Bunsho
• Sugishita Noriyuki
• Kuroda Yasushi
• Nat Univ Corp Hokkaido Univ
• Showa Denko Kk

Inventors

• Ohtani Bunsho
• Sugishita Noriyuki
• Kuroda Yasushi

Classifications

• C01P2004/30

  extending in three dimensions · CPC title

• B01J19/0006

  Controlling or regulating processes (controlling or regulating in general G05) · CPC title

• B01J12/005

  carried out at high temperatures, e.g. by pyrolysis · CPC title

• B01J37/08

  Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• B01J35/70

  characterised by their crystalline properties, e.g. semi-crystalline (catalysts comprising carbon B01J21/18; molecular sieves B01J29/00) · CPC title