Primary Carbide Refinement In Hypereutectic High Chromium Cast Irons
US-2024052462-A1 · Feb 15, 2024 · US
US9573176B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9573176-B2 |
| Application number | US-201314427759-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 6, 2013 |
| Priority date | Sep 13, 2012 |
| Publication date | Feb 21, 2017 |
| Grant date | Feb 21, 2017 |
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A surface layer material of a hot rolling mill roll is provided. The surface layer has a chemical composition containing, by mass %, C: 2.4% or more and 3.5% or less, Si: 1.2% or more and 2.4% or less, Mn: 0.2% or more and 2.0% or less, Cr: 0.8% or more and 2.1% or less, Mo: 0.3% or more and 1.1% or less, Ni: 3.0% or more and 6.0% or less, V: 1.0% or more and 2.2% or less, Nb: 0.1% or more and 0.5% or less, REM: 0.0005%) or more and 0.1% or less, Al: 0.003% or more and 0.05% or less, and the balance being Fe and inevitable impurities. The contents of C, Cr, V, Nb, REM, and Al satisfy the relationships Cr+0.2≦C−(0.24×V+0.13×Nb)≦3.0 and 0.01≦REM/Al≦3.2.
Opening claim text (preview).
The invention claimed is: 1. A surface layer material of a hot rolling mill roll which is adapted to be used for a surface layer of a hot rolling mill composite roll, the material having a chemical composition containing, by mass%, C: 2.4% or more and 3.5% or less, Si: 1.2% or more and 2.4% or less, Mn: 0.2% or more and 2.0% or less, Cr: 0.8% or more and 2.1% or less, Mo: 0.3% or more and 1.1% or less, Ni: 3.0% or more and 7.0% or less, V: 1.2% or more and 2.2% or less, Nb: 0.1% or more and 0.8% or less, REM: 0.0005% or more and 0.1% or less, Al: 0.003% or more and 0.05% or less, and the balance being Fe and inevitable impurities, wherein the contents of C, Cr, V, Nb, REM, and Al satisfy relational expressions (1) and (2) below: Cr+0.2≦C−(0.24×V+0.13×Nb)≦3.0 (1) 0.01≦REM/Al≦3.2 (2), where C, Cr, V, Nb, REM, and Al respectively represent the mass% contents of the corresponding chemical elements. 2. The surface layer material of the hot rolling mill roll according to claim 1 , wherein the chemical composition of the material further contains, by mass %, B: 0.001% or more and 0.05% or less. 3. The surface layer material of the hot rolling mill roll according to claim 1 , wherein the chemical composition of the material further contains, by mass % at least one of the following element: Ca: 0.04% or less and Ti: 0.03% or less. 4. The surface layer material of the hot rolling mill roll according to claim 1 , wherein the chemical composition of the material further contains, by mass %, at least one of the following elements: Co: 2.0% or less and W: 2.0% or less. 5. A hot rolling mill composite roll comprising: an inner layer, and a surface layer welded and, integrated with the inner layer, the surface layer having a chemical composition containing, by mass%, C: 2.4% or more and 3.5% or less, Si: 1.2% or more and 2.4% or less, Mn: 0.2% or more and 2.0% or less, Cr: 0.8% or more and 2.1% or less, Mo: 0.3% or more and 1.1% or less, Ni: 3.0% or more and 7.0% or less, V: 1.2% or more and 2.2% or less, Nb: 0.1% or more and 0.8% or less, REM: 0.0005% or more and 0.1% or less, Al: 0.003% or more and 0.05% or less, and the balance being Fe and inevitable impurities, wherein the contents of C, Cr, V, Nb, REM, and Al satisfy relational expressions (1) and (2) below: Cr+0.2 ≦C−(0.24×V+0.13×Nb)≦3.0 (1) 0.01 ≦REM/Al≦3.2 (2), where C, Cr, V, Nb, REM, and Al respectively represent the mass% contents of corresponding chemical elements. 6. The hot rolling mill composite roll according to claim 5 , wherein the chemical composition of the surface layer further contains, by mass %, B: 0.001% or more and 0.05% or less. 7. The hot rolling mill composite roll according to claim 5 , wherein the chemical composition of the surface layer further contains, by mass %, at least one of the following elements: Ca: 0.04% or less and Ti: 0.03% or less. 8. The hot rolling mill composite roll according to claim 5 , wherein the chemical composition of the surface layer further contains, by mass %, at least one of following elements: Co: 2.0% or less and W: 2.0% or less. 9. The surface layer material of the hot rolling mill roll according to claim 2 , wherein the chemical composition of the material further contains, by mass%, at least one of the following elements: Ca: 0.04% or less and Ti: 0.03% or less. 10. The surface layer material of the hot rolling mill roll according to claim 2 , wherein the chemical composition of the material further contains, by mass%, at least one of the following elements: Co: 2.0% or less and W: 2.0% or less. 11. The surface layer material of the hot rolling mill roll according to claim 3 , wherein the chemical composition of the material further contains, by mass%, at least one of the following elements: Co: 2.0% or less and W: 2.0% or less. 12. The surface layer material of the hot rolling mill roll according to claim 9 , wherein the chemical composition of the material further contains, by mass%, at least one of the following elements: Co: 2.0% or less and W: 2.0% or less. 13. The hot rolling mill composite roll according to claim 6 , wherein the chemical composition of the surface layer further contains, by mass%, at least one of the following elements: Ca: 0.04% or less and Ti: 0.03% or less. 14. The hot rolling mill composite roll according to claim 6 , wherein the chemical composition of the surface layer further contains, by mass%, at least one of the following elements: Co: 2.0% or less and W: 2.0% or less. 15. The hot rolling mill composite roll according to claim 7 , wherein the chemical composition of the surface layer further contains, by mass%, at least one of the following elements: Co: 2.0% or less and W: 2.0% or less. 16. The hot rolling mill composite roll according to claim 13 , wherein the chemical composition of the surface layer further contains, by mass%, at least one of the following elements: Co: 2.0% or less and W: 2.0% or less.
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