Use of silane-modified polyolefins as adhesion promoters for the production flat laminates

Patent metadata

Field	Value
Publication number	US-9550344-B2
Application number	US-99279209-A
Country	US
Kind code	B2
Filing date	Jul 8, 2009
Priority date	Aug 15, 2008
Publication date	Jan 24, 2017
Grant date	Jan 24, 2017

Abstract

The invention relates to the use of polyolefins modified with one or more silanes as adhesion promoters for the production of flat glass/glass, glass/plastic, or plastic/plastic laminates, to corresponding laminates, and to displays containing the laminates according to the invention.

First claim

The invention claimed is:

1. A laminate comprising:
a flat glass body;
a body applied to at least one side of the flat glass body; and
an intermediate adhesion promoter layer between the flat glass body and the applied body;
wherein
the body applied to the flat glass body is glass, plastic or a mixture thereof, and
the intermediate adhesion promoter layer comprises at least one silane modified polyolefin, the polyolefin being a polyethylene-co-propylene-co-1-butene) comprising:
2 to 25% by weight ethene;
50 to 80% by weight propene; and
7 to 98% by weight of butene
wherein said polyolefin has a propylene fraction of from 50 to 80 ma % and a solubility in tetrahydrofuran at room temperature of at least 70 ma %.

2. The laminate as claimed in claim 1 , wherein a thickness of the flat glass body and applied body is each at most 8 mm.

3. The laminate as claimed in claim 1 , wherein a thickness of the intermediate adhesion promoter layer is at most 6.5 mm.

4. The laminate as claimed in claim 1 , wherein the laminate further comprises one or more layers, which are present on one or both sides of the laminate.

5. The laminate as claimed in claim 1 , wherein the laminate is flexible.

6. The laminate as claimed in claim 1 , wherein the polyolefin is partially crystalline.

7. The laminate as claimed in claim 1 , wherein said butene is 1-butene.

8. The laminate as claimed in claim 1 , wherein the silane modified polyolefin is modified with a silane which is at least one silane selected from the group consisting of vinyltrimethoxysilane, vinyltriethoxysilane, vinyl-tris(2-methoxy-ethoxy-)silane, 3-methacryloxypropyltrimethoxysilane, 3-methacryloxypropyltriethoxysilane, vinyldimethylethoxysilane and vinylmethyldibutoxysilane.

9. A method for the production of the laminate as claimed in claim 1 , comprising:
applying said at least one silane modified polyolefin to at least one side of the flat glass body to form the intermediate adhesion promoter layer; and then
applying the at least one body to the at least one intermediate adhesion promoter layer.

10. The method as claimed in claim 9 , wherein said at least one silane modified polyolefin is applied in the form of a solution or melt.

11. The method as claimed in claim 9 , wherein the application of said at least one silane modified polyolefin is performed by a technique selected from the group consisting of spray application, knife application, spincoating, roller application and pressure techniques.

12. The method as claimed in claim 9 , wherein the at least one silane modified polyolefin is a polymer film.

13. The method as claimed in claim 9 , further comprising applying one or more layers to one or both sides of the laminate.

14. A display comprising a laminate as claimed in claim 1 .

15. The display as claimed in claim 14 , wherein the display is a UFB display, a TFT display, a TFD display, a CSTN display, a STN display, a UBC display, an LCD display, an OLED display, a plasma display and/or a touchscreen.

16. A flexible electrical module comprising at least one laminate as claimed in claim 1 .

17. A solar cell comprising the flexible electrical module as claimed in claim 16 .

18. A laminate comprising:
at least one flat plastic body of a first plastic;
a body applied to at least one side of the flat plastic body; and
an intermediate adhesion promoter layer between the flat plastic body and said body;
wherein
said body is of the same plastic or a plastic different from the first plastic of said flat plastic body, and
the intermediate adhesion promoter layer comprises at least one silane modified polyolefin, the polyolefin being a poly(ethylene-co-propylene-co-1-butene) comprising:
2 to 25% by weight ethene;
50 to 80% by weight propene; and
7 to 98% by weight of butene
wherein said polyolefin has a propylene fraction of from 50 to 80 ma % and a solubility in tetrahydrofuran at room temperature of at least 70 ma %.

19. The laminate as claimed in claim 18 , wherein said butene is 1-butene.

20. A method for the production of the laminate as claimed in claim 18 , comprising:
applying said at least one silane modified polyolefin to at least one side of the flat plastic body of a first plastic to form the intermediate adhesion promoter layer; and
then applying said body to the intermediate adhesion promoter layer.

Assignees

• Becker Hinnerk Gordon
• Zagefka Hans-Dieter
• Wey Hans Guenther
• Schmidt Friedrich Georg
• Hoppe Dirk
• Kothe Martin
• Evonik Degussa Gmbh

Inventors

• Becker Hinnerk Gordon
• Zagefka Hans-Dieter
• Wey Hans Guenther
• Schmidt Friedrich Georg
• Hoppe Dirk
• Kothe Martin

Classifications

• Y10T428/269

  including synthetic resin or polymer layer or component · CPC title

• Y10T428/31612

  As silicone, silane or siloxane · CPC title

• B32B2255/10

  on synthetic resin layer or on natural or synthetic rubber layer · CPC title

• B32B2307/704

  Crystalline · CPC title

• B32B2255/26

  Polymeric coating · CPC title