Electrode active material precursor, method for preparing the same, electrode active material, and battery
US-2024079551-A1 · Mar 7, 2024 · US
US9466831B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9466831-B2 |
| Application number | US-201414310355-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 20, 2014 |
| Priority date | Aug 14, 2009 |
| Publication date | Oct 11, 2016 |
| Grant date | Oct 11, 2016 |
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A method of: dissolving salts of a first metal ion and a second metal ion in water to form a solution; heating the solution to a temperature of about 80-90° C.; and adding a base to the solution to precipitate nanoparticles of an oxide of the first metal ion and the second metal ion.
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What is claimed is: 1. A method comprising: dissolving salts of a first metal ion and a second metal ion in water to form a solution; heating the solution to a temperature of about 80-90° C.; and adding a base to the solution to precipitate nanoparticles of an oxide of the first metal ion and the second metal ion; wherein the second metal ions have a higher oxidation state than the first metal ions; and wherein the presence of the second metal ion increases the number of metal cation vacancies relative to an absence of the second metal ion. 2. The method of claim 1 ; wherein the first metal ion is Fe 3+ ; and wherein the second metal ion is Mo 6+ or V 5+ . 3. The method of claim 1 , wherein the oxide comprises γ-Fe 2 O 3 and at least one of Mo 6+ and v 5+ . 4. The method of claim 1 , wherein the metal salts include FeCl 3 .6H 2 O, FeCl 2 .4H 2 O, and MoCl 5 . 5. The method of claim 1 , wherein the base is triethylamine.
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