Method for forming metal fluoride material

Patent metadata

Field	Value
Publication number	US-9446966-B2
Application number	US-201414221957-A
Country	US
Kind code	B2
Filing date	Mar 21, 2014
Priority date	Mar 21, 2013
Publication date	Sep 20, 2016
Grant date	Sep 20, 2016

Abstract

The present invention is directed to processing techniques and systems of metal fluoride based material, including but not limited to nickel difluoride, copper difluoride, manganese fluoride, chromium fluoride, bismuth fluoride, iron trifluoride, iron difluoride, iron oxyfluoride, metal doped iron fluorides, e.g., Fe x M 1-x F y (M=metals, which can be Co, Ni, Cu, Cr, Mn, Bi and Ti) materials. An exemplary implementation involves mixing a first compound comprising a metal material, nitrogen, and oxygen to a second compound comprising hydrogen fluoride. The mixed compound is milled to form metal fluoride precursor and a certain byproduct. The byproduct is removed, and the metal fluoride precursor is treated to form iron trifluoride product. There are other embodiments as well.

First claim

What is claimed is:

1. A method for processing a metal fluoride based material comprising:
providing a first compound comprising metal, nitrogen, and oxygen elements at a first quantity;
a second compound comprising ammonium hydrogen fluoride at a second quantity;
mixing the first compound and the second compound in a first container;
providing a milling agent within the first container;
causing movements of the containers at a first frequency for a first duration to form a milled compound;
removing the first container from the milling apparatus;
processing the milled compound to obtain a seperated compound;
removing a supernatant portion from the separated compound from the first container to obtain a mixed compound, the mixed compound comprising a portion of metal fluoride material, a portion of nitrate material, and a portion of ammonium material;
removing a portion of the nitrate material and a portion of the ammonium material by repeatedly adding a solvent to the mixed compound and removing the portion of nitrate material and the portion of the ammonium material dissolved in the solvent;
drying the portion of the metal fluoride material at a temperature of between least 20 to 200 degrees Celsius to form metal fluoride powders;
subjecting the metal fluoride powders to the temperature of at least 350 degrees Celsius for a third duration of at least 2 hours; and
cooling the metal fluoride powders.

2. The method of claim 1 further comprising disengageably coupling the first container to a milling apparatus.

3. The method of claim 1 further comprising performing centrifugation on the milled compound at a second frequency for a second duration to obtain a centrifuged compound.

4. The method of claim 3 wherein the second frequency is at least 2000 RPM.

5. The method of claim 1 wherein drying the portion of the metal fluoride material is at a temperature of between least 60 to 100 degrees Celsius to form metal fluoride powders.

6. The method of claim 5 wherein the metal comprises iron or copper.

7. The method of claim 1 wherein the solvent comprises ethanol and/or water.

8. The method of claim 1 wherein the metal comprises iron, copper, cobalt, manganese, nickel, and/or bismuth.

9. The method of claim 1 wherein the metal fluoride powders have a median particle size of about 20 nm to about 100 nm.

10. The method of claim 1 further comprising mixing a coating material with the first compound and the second compound.

11. The method of claim 1 wherein the substantially oxygen-free environment comprises, helium, argon, and/or nitrogen gas.

12. The method of claim 1 wherein the solvent is added to mixed compound at least three times.

13. The method of claim 1 wherein the first compound is solid.

14. The method of claim 1 further comprising:
providing a polymer material;
forming an electrode using the iron fluoride material.

15. The method of claim 1 further comprising:
providing a carbon material;
mixing the carbon material with the metal fluoride material.

16. The method of claim 1 wherein the first compound further comprises hydrogen material.

17. The method of claim 1 wherein the first compound further comprises iron nitrate material.

18. The method of claim 1 wherein the ratio in weight between the first quantity and the second quantity is about 2:1 to 5:1.

19. The method of claim 1 wherein the milling agent comprises stainless steel or ZrO 2 balls.

20. The method of claim 1 wherein the first duration is between about 10 to 45 minutes.

21. The method of claim 1 wherein the second container comprises a centrifuge tube.

22. The method of claim 1 wherein the first frequency is at least 1400 RPM.

23. The method of claim 1 further comprising forming a positive electrode using the dried powder.

Assignees

• Quantumscape Corp

Inventors

• Shan Jon

Classifications

• C01G3/04

  Halides · CPC title

• C01P2002/72

  by d-values or two theta-values, e.g. as X-ray diagram · CPC title

• C01P2002/54

  one element only · CPC title

• C01G49/10 Primary

  Halides {(C01G49/0018 takes precedence)} · CPC title

• C01G29/00

  Compounds of bismuth · CPC title