Ferrite magnetic powder for bond magnet and manufacturing method of the same, and bond magnet

Patent metadata

Field	Value
Publication number	US-9460850-B2
Application number	US-201414255621-A
Country	US
Kind code	B2
Filing date	Apr 17, 2014
Priority date	Mar 31, 2006
Publication date	Oct 4, 2016
Grant date	Oct 4, 2016

Abstract

To provide ferrite magnetic powders for bond magnet capable of surely suppressing residual hexavalent chrome, being an environmental load substance, having no adverse influence on the magnetic characteristics, which is an obstacle in use, and without damaging productivity and at a low cost. The method includes the steps of obtaining sintered powders by sintering raw material powders; wet-pulverizing the sintered powders; wet-cleaning the sintered powders; and annealing the cleaned sintered powders, wherein in the step of the wet-pulverization and in the step of wet-cleaning, generation of the hexavalent chrome, being an environmental load substance, is suppressed by performing the pulverization and cleaning while maintaining pH of a dispersion solvent at 8.5 or less, at the time of pulverization and cleaning.

First claim

The invention claimed is:

1. A method of manufacturing ferrite magnetic powders, comprising steps of:
obtaining sintered powders by sintering raw material powders comprising iron, chromium, and an alkaline earth metal;
wet-pulverizing the sintered powders;
wet-cleaning the wet-pulverized powders;
annealing the wet-cleaned powders; and
reducing the annealed powders at a temperature range from 80° C. to 300° C. in a gas atmosphere containing at least one gas selected from the group consisting of H 2 gas, CO gas, NO gas, and HC (hydrocarbon) gas,
wherein the pH of a dispersion solvent used in the step of wet-pulverizing is maintained at 8.5 or less by adding an acid compound.

2. The method of manufacturing ferrite magnetic powders according to claim 1 , wherein, in the step of wet-cleaning, the wet-pulverized powders are wet-cleaned with water having a pH of between 5 and 8.

3. The method of manufacturing ferrite magnetic powders according to claim 1 , wherein carbon or a compound having a boiling point of 200° C. or more and comprising carbon and at least one element selected from the group consisting of H, O, N, and Cl, is added to the sintered powders after the step of obtaining the sintered powders and before the step of annealing.

4. The method of manufacturing ferrite magnetic powders according to claim 1 , wherein a compound containing bivalent Fe is added to the sintered powders, after the step of obtaining the sintered powders and before the step of annealing.

5. The method of manufacturing ferrite magnetic powders according to claim 1 , wherein the raw material powders contain 100 ppm or more and 3,000 ppm or less of chromium.

6. The method of manufacturing ferrite magnetic powders according to claim 1 , wherein the acid compound added in the step of wet-pulverizing is hydrochloric acid or carbon dioxide gas.

7. The method of manufacturing ferrite magnetic powders according to claim 2 , wherein decantation is performed with the water having pH of between 5 and 8 in the step of wet-cleaning.

Assignees

• Dowa F-Tec Co Ltd
• Dowa Electronics Materials Co Ltd

Inventors

• Kohayashi Shuichi
• Ikeda Hiroya
• Katayama Hideki
• Ayabe Keisuke

Classifications

• C01P2006/11

  Powder tap density · CPC title

• C01G49/0018

  Mixed oxides or hydroxides, (C01G49/0009 takes precedence) · CPC title

• C01G49/0036

  containing one alkaline earth metal, magnesium or lead · CPC title

• C01P2006/80

  Compositional purity · CPC title

• H01F41/0266 Primary

  Moulding; Pressing (H01F41/0273 takes precedence; hard magnetic particles H01F1/06, H01F1/11) · CPC title