Method for producing unsaturated nitrile

Patent metadata

Field	Value
Publication number	US-9464039-B2
Application number	US-201113994230-A
Country	US
Kind code	B2
Filing date	Oct 13, 2011
Priority date	Mar 2, 2011
Publication date	Oct 11, 2016
Grant date	Oct 11, 2016

Abstract

A method for producing an unsaturated nitrile by subjecting propane to a vapor-phase catalytic ammoxidation reaction using a fluidized bed reactor in the presence of a composite oxide catalyst containing Mo, V, and Nb, the method comprising the step of: adding a tungsten compound into the fluidized bed reactor to adjust a molar ratio (W/Mo ratio) of tungsten contained in a tungsten compound to molybdenum contained in the composite oxide catalyst that exist within the fluidized bed reactor so that the molar ratio is in the range of 0.0001 to 0.1.

First claim

What is claimed is:

1. A method for producing an unsaturated nitrile, comprising:
subjecting propane to a vapor-phase catalytic ammoxidation reaction using a fluidized bed reactor in the presence of a composite oxide catalyst, to produce the unsaturated nitrile,
wherein a tungsten compound is added into the fluidized bed reactor during the vapor-phase catalytic ammoxidation reaction, to adjust a molar ratio (W/Mo ratio) of a tungsten contained in the tungsten compound to a molybdenum contained in the composite oxide catalyst that exist within the fluidized bed reactor so that the molar ratio is in a range of 0.0001 to 0.1, and
the composite oxide catalyst comprises a composite oxide represented by the following composition formula (1):
Mo 1 V a Nb b A c X d Z e O n   (1)

wherein component A represents at least one or more elements selected from Te and Sb; component X represents at least one or more elements selected from W, Bi, and Mn; component Z represents at least one or more elements selected from La, Ce, Pr, Yb, Y, Sc, Sr, and Ba; a, b, c, d, e, and n each represent an atomic ratio of the corresponding element per Mo atom; a is in a range of 0.01≦a≦1; b is in a range of 0.01≦b≦1; c is in a range of 0.01≦c≦1; d is in a range of 0≦d≦1; e is in a range of 0≦e≦1; and n represents a number determined by valences of the component elements; and
said method further comprising
(1) extracting a mixture of the composite oxide catalyst and the tungsten compound from the fluidized bed reactor during the vapor-phase catalytic ammoxidation reaction; (2) measuring a temporary value of the W/Mo ratio from the mixture obtained by (1); and (3) controlling the W/Mo ratio to fall within the range of 0.0001 to 0.1 based on the temporary value measured in (2).

2. The method for producing the unsaturated nitrile according to claim 1 , comprising a step of adding a molybdenum compound into the fluidized bed reactor.

3. The method for producing the unsaturated nitrile according to claim 1 or 2 , wherein the composite oxide is carried on 20 to 70% by mass of silica based on a whole amount of the catalyst in terms of SiO 2 .

Assignees

• Tamura Sho
• Shoji Sadao
• Asahi Kasei Chemicals Corp

Inventors

• Tamura Sho
• Shoji Sadao

Classifications

• B01J23/30

  Tungsten · CPC title

• B01J27/0576

  Tellurium; Compounds thereof · CPC title

• B01J2523/00

  Constitutive chemical elements of heterogeneous catalysts · CPC title

• C07C253/24 Primary

  by ammoxidation of hydrocarbons or substituted hydrocarbons · CPC title

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title