Apparatus for producing mixed solution and method for preparing mixed solution

Patent metadata

Field	Value
Publication number	US-9827538-B2
Application number	US-201615225626-A
Country	US
Kind code	B2
Filing date	Aug 1, 2016
Priority date	Jan 31, 2011
Publication date	Nov 28, 2017
Grant date	Nov 28, 2017

Abstract

An apparatus for producing a mixed solution, comprising a mixing vessel for preparing an aqueous mixed solution containing a dicarboxylic acid and an Nb compound and a filter for the aqueous mixed solution connected to the mixing vessel via a pipe, the mixing vessel being anticorrosive and equipped with a stirring unit, a heating unit and a cooling unit for the aqueous mixed solution, wherein the aqueous mixed solution prepared in the mixing vessel is fed to the filter via the pipe and filtered in the filter under increased pressure.

First claim

The invention claimed is:

1. A method for preparing a mixed solution, comprising the steps of:
heating and stirring a dicarboxylic acid, a niobium compound and water in an anticorrosive mixing vessel so as to obtain an aqueous mixed solution;
cooling and stirring the aqueous mixed solution; and
feeding the aqueous mixed solution into a filter to filter under an increased pressure.

2. The method for preparing the mixed solution according to claim 1 , wherein a temperature of the aqueous mixed solution is adjusted in the step of feeding the aqueous mixed solution into a filter.

3. The method for preparing the mixed solution according to claim 1 , wherein in the step of heating and stirring the dicarboxylic acid, the niobium compound and the water in an anticorrosive mixing vessel to obtain the aqueous mixed solution, a niobium and a dicarboxylic acid are dissolved in the aqueous mixed solution.

4. The method for preparing the mixed solution according to claim 1 , wherein in the step of cooling and stirring the aqueous mixed solution, the dicarboxylic acid is deposited from the aqueous mixed solution.

5. The method for preparing the mixed solution according to claim 1 , further comprising the steps of:
measuring a concentration of an obtained filtrate after the step of feeding the aqueous mixed solution into a filter and
adding a dicarboxylic acid and/or water to the filtrate when a dicarboxylic acid/niobium molar ratio is not within a predetermined range.

6. The method for preparing the mixed solution according to claim 5 , wherein a molar ratio of the dicarboxylic acid to the niobium of the filtrate is adjusted to more than 1 and less than 4.

7. The method for preparing the mixed solution according to claim 1 , wherein the dicarboxylic acid is an oxalic acid.

8. A method for preparing a molybdenum, vanadium, antimony and niobium-containing catalyst comprising:
preparing a mixed solution according to claim 1 and;
mixing together the mixed solution and a solution comprising molybdenum, vanadium and antimony.

9. A method for producing an unsaturated nitrile, comprising:
preparing a catalyst by the method according to claim 8 ; and
contacting the catalyst with i) propane, ammonia and oxygen or ii) isobutane, ammonia and oxygen, so as to produce the unsaturated nitrile.

Assignees

• Asahi Kasei Chemicals Corp

Inventors

• Ishii Yusuke
• Kato Takaaki

Classifications

• B01J2531/57

  Niobium · CPC title

• B01F1/0016

  Operations & Transport · mapped topic

• B01J2523/53

  Antimony · CPC title

• B01J2219/0209

  of glass · CPC title

• B01F15/0022

  Operations & Transport · mapped topic