Coloured technical ceramic bodies and method for obtaining the same

Patent metadata

Field	Value
Publication number	US-9458064-B2
Application number	US-201314647641-A
Country	US
Kind code	B2
Filing date	Dec 20, 2013
Priority date	Dec 21, 2012
Publication date	Oct 4, 2016
Grant date	Oct 4, 2016

Abstract

The invention relates to coloured ceramic bodies and a method for obtaining these coloured ceramic bodies. The method of the invention comprising the following steps: providing a composition comprising a technical ceramic material, a first pigment component and optionally binder materials, preparing a green body from this composition, optionally debinding the green body, thereafter subjecting the green body to a treatment with a metal-containing preparation as a further pigment component, and sintering the treated green body. The coloured technical ceramic body of the present invention consists of a technical ceramic material, the technical ceramic body comprising a first coloured area and a second coloured area of a different colour, whereby the first coloured area contains a first pigment component, and the second coloured area contains a second pigment component which is formed from the first pigment component and the further pigment component.

First claim

The invention claimed is:

1. Method for the production of a coloured technical ceramic body, comprising the following steps:
providing a composition comprising a technical ceramic material, a first pigment
component and optionally binder materials,
preparing a green body from this composition,
debinding the green body, wherein treatment with heat for debinding the green body is conducted at a temperature in the range of 700 to 1200° C.,
thereafter subjecting the green body to a treatment with a metal-containing preparation as a further pigment component, and
sintering the treated green body.

2. The method of claim 1 , wherein the composition comprises binder materials and wherein a step of pre-debinding is conducted before the debinding step, wherein the pre-debinding step consists in treating the green body with an aqueous solution and subsequently drying the treated green body, or in treating the green body by heat.

3. The method of claim 1 , wherein the technical ceramic material is zirconia, which is stabilized with yttria, calcia, ceria, or magnesia.

4. The method of any of claim 1 , wherein the first pigment component is selected from the group consisting of the compounds Al 2 O 3 , CoO, Co 2 O 3 , Co 3 O 4 , Cr 2 O 3 , Cu 2 O, CuO, Fe 2 O 3 , Fe 3 O 4 , MnO, Mn 2 O 3 , Mn 0 2 , MoO 2 , MoO 3 , NbO, NbO 2 , Nb 2 O 5 , NiO, PbO, Pb 0 2 , SnO, SnO 2 , TiO, Ti 2 O 3 , TiO 2 , VO 2 , V 2 O 5 , WO 2 , W 2 O 5 and WO 3 .

5. The method of claim 4 , wherein the first pigment component is selected from Al 2 O 3 and Fe 2 O 3 .

6. The method of any of claim 1 , wherein the first pigment component is a complex inorganic pigment compound showing a spinel crystal structure of space group Fd-3m.

7. The method of claim 6 , wherein the first pigment component has the formula AB 2 O 4 ,
wherein A is selected from the group consisting of Fe, Co, Ni, Zn, and Mn, and
wherein B is selected from the group consisting of Al, Cr, and Fe.

8. The method of claim 1 , whereby the green body is subjected partly to a treatment with the metal-containing preparation.

9. The method of claim 1 , wherein the treatment with the metal-containing preparation is an impregnation with a solution of a metal-containing further pigment component which is followed by drying of the impregnated body.

10. The method of claim 9 , wherein the impregnating solution is a solution of at least one salt of Al, Co, Cu, Cr, Fe, Mg, Mn, Mo, Ni, Ti and Zn in water and/or if appropriate at least one organic solvent.

11. The method of claim 9 , wherein the drying step after the impregnation is conducted at ambient temperature during 12 to 24 hours, or at 60-100° C. during 1 to 60 minutes.

12. The method of claim 1 , wherein the body which has been treated with a metal-containing preparation as a further pigment component and has been optionally dried is sintered at a temperature of between 1300 and 1550° C.

13. The method of claim 1 , wherein the coloured technical ceramic body is a watch case or a watch bezel.

14. A coloured technical ceramic body, consisting of a technical ceramic material,
the technical ceramic body comprising a first coloured area and a second coloured area of a different colour,
wherein the first coloured area contains a first pigment component, wherein the first pigment component is selected from the group consisting of Al 2 O 3 , CoO, Co 2 O 3 , Co 3 O 4 , Cr 2 O 3 ,Cu 2 O, CuO, Fe 2 O 3 , Fe 3 O 4 MnO, Mn 2 O 3 , Mn 0 2 , MoO 2 , MoO 3 , NbO, Nb 0 2 , Nb 2 O 5 ,NiO, PbO, PbO 2 , SnO, SnO 2 , TiO, Ti 2 O 3 , TiO 2 , VO 2 , V 2 O 5 , WO 2 , W 2 O 5 and WO 3 , and
wherein the second coloured area contains a second pigment component, wherein the second pigment component is formed from the first pigment component in combination with one or more metal ions selected from the group consisting of Co, Cu, Cr, Fe, Mg, Mn, Mo, Ni, Ti, and Zn.

15. The coloured technical ceramic body according to claim 14 , in which the first coloured area contains a pigment component corresponding to a cubic phase of space group Fd-3m.

16. The coloured technical ceramic body according to claim 14 , wherein the first coloured area has a blue, brown or white colour and the second coloured area has a blue, brown or black colour.

17. The coloured technical ceramic body of claim 14 which is a watch case bezel.

18. The coloured technical ceramic body according to claim 15 , wherein the pigment component is a CoAl 2 O 4 pigment.

Assignees

• Rolex Sa

Inventors

• Huguet Pierre
• Bienvenu Carine

Classifications

• C04B35/48

  based on zirconium or hafnium oxides, zirconates, {zircon} or hafnates · CPC title

• C04B41/85

  with inorganic materials · CPC title

• G04B37/226 Primary

  coated with a metallic layer · CPC title

• C04B2235/9661

  Colour · CPC title

• C04B41/5007

  with salts or salty compositions, e.g. for salt glazing (C04B41/5006 takes precedence) · CPC title