Zirconia covering element with selective coloring

Patent metadata

Field	Value
Publication number	US-11144012-B2
Application number	US-201616062733-A
Country	US
Kind code	B2
Filing date	Nov 17, 2016
Priority date	Dec 18, 2015
Publication date	Oct 12, 2021
Grant date	Oct 12, 2021

Abstract

The present invention relates to a covering element for a portable object made of a first material, the first material being a ceramic material having a first color, characterized in that the surface of said covering element is at least partially treated so as to exhibit at least one conversion having a different color from the first color.

First claim

The invention claimed is:

1. A process for treating a covering element for a portable object, the covering element comprising zirconia, said process comprising:
making available the covering element and placing the covering element in a hermetically sealed chamber (E) comprising an atmosphere that is atomically loaded with a chemical element:
selectively carburizing or nitriding the covering element by activating and locally heating, via a first focused heat source (S), the surface of the covering element such that the atoms from the atmosphere of the chamber combine locally with a portion of the zirconia surface to form a pattern of zirconium carbide or of zirconium nitride.

2. The treatment process as claimed in claim 1 , wherein the atmosphere is created by dissociation of a gas via a second heat source.

3. The treatment process as claimed in claim 1 , wherein the atmosphere is created by dissociation of a gas via a second heat source, the covering element being heated at a lower temperature than the activation temperature for combining the atoms from the atmosphere with the zirconia surface via a third heat source.

4. The treatment process as claimed in claim 1 , wherein the surface of the covering element is locally heated at a temperature of between 700 and 1100° C. for a duration of 30 to 180 minutes.

5. The treatment process as claimed in claim 1 , wherein a surface layer which has the structure of zirconium carbide or of zirconium nitride is obtained, and extends from the surface to a depth of between 10 and 500 nm.

6. A process for treating a covering element for a portable Object made of zirconia, said process comprising:
making available the covering element;
locally depositing a metal layer on the surface of said covering element;
placing said covering element in a hermetically sealed chamber (E) comprising an atmosphere that is atomically loaded with a chemical element and selective carburizing or nitriding the covering element by activating and locally heating the surface of the covering element such that the atoms from the atmosphere of the chamber combine with the surface of a first material not covered with the metal deposit, to form a pattern of zirconium carbide or of zirconium nitride.

7. The treatment process as claimed in claim 6 , further comprising selectively and chemically attacking the surface of said covering element in order to remove the metal deposit.

8. The treatment process as claimed in claim 6 , wherein a selective metal deposit is produced by deposition through a mask previously laid on the covering element.

9. The treatment process as claimed in claim 6 , wherein the depositing of the metal layer consists in:
depositing a sacrificial layer over the whole of the surface of said covering element;
selectively etching the sacrificial layer according to a desired shape; and then
depositing the metal layer over the whole of the surface of said covering element, the remaining sacrificial layer then being removed by chemical attack, thereby leaving the metal layer in the locations in which the sacrificial layer was previously etched.

10. The treatment process as claimed in claim 6 , wherein a selective metal deposit is produced by deposition followed by laser structuring of the surface of said covering element.

11. The treatment process as claimed in claim 10 , wherein the metal deposit comprises at least one selected from the group consisting of chromium, tantalum, molybdenum, tungsten, niobium, titanium, silicon and boron.

12. The treatment process as claimed in claim 6 , wherein a selective metal deposit is produced by deposition followed by photolithography of the surface of said covering element.

13. A process for treating a covering element for a portable object comprising zirconia, said process comprising:
making available the covering element;
treating said covering element by placing the covering element in a hermetically sealed chamber comprising an atmosphere that is atomically loaded with a chemical element and selectively carburizing or nitriding the covering element by activating and locally heating the surface thereof such that the atoms from the atmosphere of the chamber combine with the surface of the first material,
wherein the process further comprises, prior or subsequent to the treating of said covering element, structuring the covering element, making it possible to create a relief on the surface thereof and to reveal the color of the zirconia contrasting with a carburized or nitrided surface color, in order to form a pattern of zirconium carbide or of zirconium nitride.

14. The treatment process as claimed in claim 13 , further comprising, when the structuring of the covering element is carried out prior to the treating of said covering element:
polishing in order to remove the carburized/nitrided surface layer on the portions protruding from the surface in relief of the covering element.

15. A process for treating a covering element for a portable Object comprising zirconia, said process comprising:
making available the covering element;
locally depositing ink or enamel pigments on the surface of the covering element; and
placing the covering element in a hermetically sealed chamber comprising an atmosphere that is loaded with carbon or nitrogen atoms, and selectively carburizing or nitriding the covering element by activating and locally heating the surface thereof, so as to form a pattern of zirconium carbide or of zirconium nitride around an ink or enamel pattern.

Assignees

• Swatch Group Res & Dev Ltd

Inventors

• Curchod Loic
• Faure Cedric
• Willemin Michel
• Springer Simon

Classifications

• G04B45/0076 Primary

  Decoration of the case and of parts thereof, e.g. as a method of manufacture thereof (specially shaped G04B45/0061, G04B45/0069; decoration with inscriptions and pictures G04B45/0084; construction of the hands G04B19/042; decoration by adding extra pieces to the clockwork G04B47/04; colouring by treatment of the surface, e.g. by oxidation C25D) · CPC title

• C23C14/5873

  Removal of material · CPC title

• C23C8/04

  Treatment of selected surface areas, e.g. using masks · CPC title

• C23C8/20

  Carburising · CPC title

• A44C27/006

  Metallic coatings · CPC title